简介:Thefullpotentiallinearizedaugmentedplanewave(FLAPW)methodisusedtostudythecrystalstructureandelectronicstructurepropertiesofPbFeo.5Nbo.5O3(PFN).Theoptimizedcrystalstructure,densityofstates,bandstructureandelectrondensitydistributionhavebeenobtainedtounderstandtheferroelectricbehaviourofPFN.TheanalysisresultofthedensityofstatesshowsthereisanobviouschangeofNbdstatesintheparaelectric-to-ferroelectricphasetransition.ThepolarizationresultshowsthatthecontributiontoferroelectricityofNbatomsislargerthanthatofFeatoms.InferroelectricphasethereisahybridizationofFed-OpandNbd-OpinferroelectricPFN.Thisisconsistentwiththeresultoftheelectronicbandstructure.Thishybridizationisresponsibleforthetendencytoitsferroelectricity.
简介:Synthesis,structureandmagneticpropertiesofRudopedperovskitestructuredmanganiteLa0.5Sr0.5MnO3wereinvestigatedexperimentally.Ahydrothermalmethodwasusedforthepreparationofthesamples.Ahigh-temperatureannealingprocesswasalsoemployedtomakeacomparison.AslightlyenhancementoftheunitcellvolumewasobservedwiththeincreaseofRuconcentration.Scanningelectronmicroscopyshowsthatthematerialsaremadeupofcube-shapedparticleswithdimensionofseveralmicrometers.Importantly,itisfoundthatboththeCurietemperatureTCandsaturationmomentcanbereducedbyRudoping.ThevalueofcoercivefieldisnotaffectedbytheintroductionofRu.
简介:Effectofvelocityjumpandtemperaturejumpontheheatandmomentumtransferinmicro-domainsisdiscussedindetail.Asimulationaidedbylocallyfullydevelopedassumptionisdevelopedtoexplaintheexperimentalresultsdifferentfromthosepredictedbyconventionaltheory.Heattransferinmicro-channelsundertheuniformheatfluxisalsoanalyzed.Itisfoundthatvelocity-jumpandtemperature-jumphaveanoppositeinfluenceandNusseltnumberhasagreatervaluewhentheKnudsennumberisverysmall,WiththeincreasingofKnudsenNumber,Nussqltnumberbecamesmallerthan8.24.
简介:首次制备出粉末微晶BaCl0.5Br0.5F:Sm2+红色发光材料,并测量了其低温光谱。发现其谱线宽度与BaClF:Sm2+的相比较有了约十倍左右的非均匀增宽,而且相应于5D0,1,2→7F0,1的谱线由两个峰间距分别为15cm-1,65cm-1的谱线构成,峰间距只与基态7F0和7F1有关。W.Lenth&W.E.Morener[1]讨论了光子门光谱烧孔作为频率微区光学记录的理论和应用的可能性。对于长存的光谱烧孔,可以进行二进制的数据存储与改写。该技术为实现大容量、高速度的光学计算机的应用提供了新的前景。在这方面已经有了不少的研究工作[2~6]。为提高存储容量,需使光谱线非均匀增宽,以提供更多的光谱烧孔可能性。为此目的,首次制备出粉末微晶BaCl0.5Br0.5F:Sm2+红色发光材料,并测量了其低温光谱,并将其与BaClF:Sm2+的低温光谱进行了比较分析。
简介:Inthiswork,weinvestigatethemethodstoimprovetheperformanceofthesweptsourceat1.0μmbasedonapolygonscanner,includingin-cavityparametersandboosterstructuresoutofthecavity.Thethreein-cavityparametersarethecavitylength,therotatingspeedofthepolygonscanner,andthein-cavityenergy.Withthedecreaseofcavitylength,thespectrumbandwidthbecomeswiderandthedutycyclebecomeshigher.Withtheincreaseoftherotatingspeedofthepolygon,thespectrumbandwidthbecomesnarrower,andthedutycyclebecomeslowerbuttherepetitionratebecomeshigher.Withmoreenergyin-cavity,thespectrumbandwidthbecomeswiderandthedutycyclebecomeshigher.Theboosterstructuresincludethebufferedstructure,secondaryamplifier,anddual-semiconductoropticalamplifierconfiguration,whichareusedtoincreasethesweepfrequencyto86kHz,theoutputpowerto18mW,andthetuningbandwidthto131nm,respectively.
简介:Weinvestigatethedynamiccrystallizationprocessesofcolloidalphotoniccrystals,whicharepotentiallyinvaluableforsolvinganumberofexistingandemergingtechnicalproblemsinregardstocontrolledfabricationofcrystals,suchassizenormalization,stabilityimprovement,andaccelerationofsynthesis.Inthispaper,wereportsystematichigh-resolutionopticalobservationofthespontaneouscrystallizationofmonodispersepolystyrene(PS)micro-spheresinaqueoussolutionintoclose-packedarraysinastaticlineopticaltweezers.Theexperimentsdemonstratethatthecrystalstructureismainlyaffectedbytheminimumpotentialenergyofthesystem;however,thecrystallizationdynamicscouldbeaffectedbyvariousmechanical,physical,andgeometricfactors.Thecomplicateddynamictransformationprocessfrom1Dcrystallizationto2Dcrystallizationandthecreationandannihilationofdislocationsanddefectsviacrystalrelaxationareclearlyillustrated.Twomajorcrystalgrowthmodes,theepitaxygrowthpatternandtheinsertedgrowthpattern,havebeenidentifiedtoplayakeyroleinshapingthedynamicsofthe1Dand2Dcrystallizationprocess.Theseobservationsofferinvaluableinsightsforin-depthresearchaboutcolloidalcrystalcrystallization.
简介:PalladiumcatalystsaresupportedonTiO2,ZrO2,Al2O3,Zr0.5Al0.5O1.75andTiO2-Zr0.5Al0.5O1.75preparedbyco-precipitationmethod,respectively.CatalyticactivitiesformethaneandCOoxidationareevaluatedinagasmixturethatsimulatedtheexhaustfromlean-burnnaturalgasvehicles(NGVs).Pd/TiO2-Zr0.5Al0.5O1.75performsthebestcatalyticactivityamongthetestedfivecatalysts.ForCH4,thelight-offtemperature(T50)is254℃,andthecompleteconversiontemperature(T90)is280℃;forCO,T50is84℃,andT90was96℃.Varioustechniques,includingN2adsorption-desorption,X-raydiffraction(XRD),H2-temperature-programmedreduction(H2-TPR),X-rayphotoelectronspectroscopy(XPS),andscanningelectronmicroscopy(SEM)areemployedtocharacterizetheeffectofsupportsonthephysicochemicalpropertiesofpreparedcatalysts.N2adsorption-desorptionandSEMshowthatTiO2-Zr0.5Al0.5O1.75expressesuniformnano-particlesandlargemeso-porediametersof26nm.H2-TPRandXRDindicatethatPdOiswelldispersedonthesupportsandstronglyinteractedwitheachother.TheresultsofXPSshowthattheelectrondensityaroundPdOandtheproportionofactiveoxygenonTiO2-Zr0.5Al0.5O1.75aremaximaamongthefivesupports.
简介:ThispaperresentsanewX-rayimagingmethodswingLaminography(SL)thatissuitalbletoperformnon-destructivetestingontheslender-shapedmulti-layersamples.ComputersimulationsaremadetocomparethelimitedprojectionsinSLandtheprincipleofchoosingOptimalProjectionAngularRegion(OPAR)isdiscussed.Theexperimentonatwo-layerPrintedCircuitsBoardshowsthatSLwith120°swinganglesdistributedinOPARcangettheseparatedimagesofeachlayer.
简介:Na0.5CoO2的费密表面拓扑学用混合密度被学习功能的理论。我们首先学习一个单身者(CoO2)(0.5-)有从0%~20%变化的非局部的Hartree-Fock交换的百分比的层模型。结果看那混合非局部的Hartree-Fock交换是否仅仅在1%和5%之间,费密表面拓扑学类似于试验性的。与在混合密度的3%HF交换功能就在Na-0.5CoO2系统的效果ofNa离子而言,我们结束费密表面被切开加倍洞,小差距在在Brillouin地区和费密表面之间的交叉附近开。我们两个都,非局部的Hartree-Fock的数量在功能的混合密度交换的结果表演然后一离子在费密表面拓扑学上有许多影响。