简介:Recentinvestigationsindicatedthatmetalscanbeeffectivelystrengthenedbynumeroustwinboundaries(TBs)withtwin/matrixlamellarthicknessesinthenanometerregime.Superiorstrength-ductilitysynergieshavebeenachievedwiththenano-twinstrengtheningmechanism.Inthistalk,thenovelnano-twinstrengtheningwillbeappliedtoaustenitesteelsincluding316LstainlesssteelandaFe-Mnsteelinordertooptimizetheirstrength-ductilitycombinations.Thesteelsareprocessedbymeansofdynamicplasticdeformation(DPD,i.e.,plasticdeformationathighstrainrates).Single-phased(austenite)bulknanostructuredsteelspecimenswereprepared,consistingofnano-sizedgrainsembeddedwithnano-scaletwinbundles.Theas-preparednanostructuredsampleswereannealedatvariousconditions,resultinginpartialrecrystallizationofthenanostructuresandformingamixturestructureofcoarse-grainsembeddedwithnano-twinbundles.Strengthandductilityoftheaustenitesteelswithdifferentamountofnano-twinbundlesareanalyzed.Measurementsshowedthenano-twinstrengthenaustenitesteelscanbesuperstrong(withyieldstrengthabove1GPa)togetherwithaconsiderableductility(elongation-to-failure>20%).
简介:BasedonthepracticeofBaosteel's60000m3/hairseparationunit(ASU),whichisthefirstdomestically-integratedunitofsuchascale,thispaperstudiestheprinciplesoftypeselectionofthedistributioncontrolsystem(DCS).Itdiscussesthedesignoftheunit'scontrolsystem,whichinvolvesacompressorsystem,apurificationsystem(molecularsieving),aturboexpansionsystemandanairseparationsystem.ThefinalpartofthepaperdiscussesthemaintenanceandfuturedevelopmentoftheASUcontrolsystematBaosteel.
简介:ThisstudymainlyintroducesthetechnicalpropertiesofakindofleancoalminedfromLu'an,aprefectureofShanxiProvinceanditsapplicationtocoalinjectioninlarge-scaleblastfurnaces(BFs)inBaosteel.Chinaisrichinleancoalresources.Thetechnicalpropertiesofleancoal,includingashcontent,sulfurcontentandcaloricity,etc.,aresimilartothoseofanthracitecoalusedinBaosteel,exceptthefactthatthevolatileofleancoalishigher.Besides,theexplosivepropertyandthecokingpropertyofleancoalaresuitablefortheBFcoalinjection.Inthisstudy,leancoalwastestedinthepulverizedcoalinjection(PCI)ofaBF.Inthetest,theblendingproportionofleancoalinthecoalblendwasincreasedgradually,andtheconsequentialproductionindexesweretraced.AlltheoperationalindexesshowthattheresultsoftheBFcoalinjectionaregood,demonstratingthatleancoalcanbesubstitutedforanthracitecoalinthePCIinBFs.Withanabundantamountandspecificutilization,leancoalisfoundtobeofahigheconomicvalue.
简介:Theformationofsolidsolutioncombinedwithtricalciumphosphateanddicalciumsilicatecouldpromoteaconsiderableremovalofphosphorusfromliquidslagtosolidduringhotmetaldephosphorization,andthusthedephosphorizationbyusingmultiphasefluxescouldsignificantlydecreasetheconsumptionoflime.However,thereactionmechanismofmultiphasefluxeshasnotbeenunderstoodclearly.Inthepresentstudy,thephasediagramfortheCaO-SiO2-FeO-P2O5systemhasbeenmeasuredwithcertainoxygenpartialpressureathotmetalpretreatmenttemperature.ComparingwiththeCaO-SiO2-FeOsystem,shrinkageofliquidphaseareaathigherFeOcontentswasobservedat1673Kwithoxygenpartialpressureof9.2×10-11atm.
简介:InordertosuppressthesurfacecrackinginducedbyCuduringreheatingandhotrollingprocess,Cuenrichmentanditsmigrationatthesteel-scaleinterfacewasinvestigatedduringheatingofsteelcastattemperaturesbetween1000℃and1200℃inN2-O2andN7-H2Oatmospheres.ForoxidationofCucontainingsteel,CuenrichedphasewasformedbythepreferentialoxidationofFeandtheenrichmentandmigrationbehaviorofCudependsontheoxidationtemperature,steelchemistryandatmospherecondition.NiinsteelinducedtheformationofsolidCuandNienrichedphaseatsteel/scaleinterfaceandinscalelayerandtheformationofunevensteel/scaleinterface,whichsuppressestheCuenrichmentbecauseofextrusionofCuenrichedregionbeforetheformationofliquidphase.Ontheotherhand,SnadditionpromotestheliquidCuformationatsteel/scaleinterfaceandpenetrationintograinboundaryofCuenrichedphasebydecreasingsolidustemperatureandsolubilitylimit.Inaddition,foroxidationat1200℃,thebehaviorofCuatandaroundthesteel-scaleinterfacewasfounddependenttoalargeextentonmorphologyoftheoxidescaleformedduringoxidation.Attheearlystageofoxidation,Cu-richphaseformedandaccumulatedatthesteelscaleinterfaceunderbothO2-N2andH2O-N2atmospheres.Astheoxidationproceeded,however,Cuenrichmentatanditsmigrationfromthesteel-scaleinterfacewerevastlydifferentfordifferentoxidizingatmospheres.InthecaseofO2-N2oxidation,anoxidelayerformedinitiallyatthesteelsurface,butsoonafteragapwasdevelopedatthesteel-scaleinterfaceandgrewinitssize,whichpracticallyseparatedthescalefromthesteelsubstrate.Thescalelayerformedunderthisconditionwasporous.TheCu-richphaseinitiallyformedattheinterfacewasfoundmigratingtothescalelayer,leavingnoCu-richphaseattheinterface.InthecaseofH2O-N2oxidation,however,thescalelayerformedwasdenseandtightlyattachedtothesteelsurface,andtheCurich-phasecontinuedto
简介:Thefirstdomestically-integratedlarge-scaleairseparationunit(ASU)withacapacityof60000m3/hwassuccessfullybuiltandputintooperationatBaosteel.Comparedwiththeelectricaldesignoftheimportedequipmentofthesametype,thisASUhasanelectricalprotectioninterlinkthatisindependentfromthedistributioncontrolsystem(DCS).Withthedesignideaofsimplicity,theASUfeaturesasimplifiedconfigurationandanaudioalarmsystemforelectricalfailures.Ithelpsreducethefailurerateoftheelectricalequipmentanddetectfailuresquicklyandaccurately.Itwilleffectivelyenhancesafeandstabilizedproduction.TheASUcannotonlyreducethecostofinvestment,butalsoensureasmoothandstablerunningofthewholeelectricalequipment.Thisstudyfocusesontheexperienceandunderstandingoftheunitdesignandcommissioning.
简介:Amulti-objectiveoptimizationapproachfortherollshiftingstrategyincrossrollingcampaignsofhotstripmillsispresented.Theeffectofdifferentrollshiftingstrategiesonrollwearcontourisstudiedbynumericalsimulation,andtwoevaluationindexes,namelybodysmoothnessandedgesmoothness,areproposed.Theaveragebodysmoothnessandaveragerollingedgesmoothnessofallstripsinarollingcampaignaretakenastheobjectivefunctions,theshiftingpositionsofallwidestripsasthedecisionvariables,andthemulti-objectivemethodofNSGA-Ⅱastheoptimizer.Thusamulti-objectiveoptimizationmodelfortherollshiftingstrategyisbuilt.Thesimulationresultsshowthatworkrollshiftingcanmakewearcontoursmooth,andadish-shapedwearcontourwithoutseverelocalwearcanbeachievedbytherollshiftingstrategywithvaryingstroke.OptimizationexperimentationshowsthatbymeansofNSGA-Ⅱ,agoodPareto-optimalfrontcanbeobtained,whichsuggestsaseriesofalternativesolutionsforrollshiftingstrategyoptimization.Theexperimentationalsoshowsthatthereisaconflictbetweenthetwoobjectives.Finally,applicationcasesconfirmthefeasibilityofthemulti-objectiveapproach,whichcanimprovethestripprofile,reduceedgewavesandextendtherollingmilesofarollingcampaign.
简介:做铕的borosilicate眼镜被融化熄灭过程在空中准备。Eu2+和Eu3+的混合原子价被相片光光谱和电子识别顺磁的回声(EPR)。混合原子价的存在由于unequivalent替换和同样准备的borosilicate眼镜的de聚合网络被观察。在B2O3/BaO比率的玻璃作文的变化清楚地改变了Eu3+离子的稳定性。特别地,同样准备的borosilicate眼镜展出了易兴奋的系列在397,466和534nm集中了在约592和617nm给拓宽的橘子红排放的一盏tri波长灯,由于Eu3+离子的敏感过度的转变。这同时的tri波长刺激碰巧从钇铝柘榴石从近紫外的、蓝AlInGaN薄片和那与射出的波长相应:Ce3+。在466nm刺激下面的做Eu的眼镜的全部的量收益(QY)被评估是10%,潜在地向万用的联合提供做铕的borosilicate眼镜让红部件增加改进白光的质量。
简介:Tobreakthroughthebottle-neckofquantumyieldinupconversion(UC)core-shellsystem,weelucidatedthattheenergytransferefficiencyincore-shellsystemhadanevidentcontributionfromthechargetransferofinterfacewithrelatedtotwofactors:(1)bandoffsetsand(2)bindingenergyareadensity.Thesetwovariablesweredeterminedbymaterialintrinsicpropertiesandcore-shellthicknessratio.Wefurtherunraveledthemechanismofnon-radiativeenergytransferbychargetransferinduceddipoleattheinterface,basedonaquasi-classicalderivationfromF?rstertyperesonantenergytransfer(FRET)model.Withstablebondingacrosstheinterface,thecontributionsonenergytransferinbothradiativeandnon-radiativeenergytransfershouldalsobeaccountedtogetherinAuzel'senergytransfer(ETU)modelincore-shellsystem.Basedonthediscussionaboutinterfacebonding,bandoffsets,andformationenergies,wefiguredoutthesignificanceofinterfacebondinginducedgapstates(IBIGS)thatplayedasignificantroleforinfluencingthechargetransferandradiativetypeenergytransfer.Theinterfacebandoffsetswereakeyfactorindominatingthenon-radiativeenergytransfer,whichwasalsocorrelatedtocore-shellthicknessratio.Wefoundthattheenergyareadensitywithrelatedtocore/shellthicknessratiofollowedthetrendofBoltzmansigmoidalgrowthfunction.Bythephysicaltrend,thisworkcontributedareferencehowthemulti-layeredcore-shellstructurewasformedstartingfromtheverybeginningwithinminimumsize.Aroutewaspavedtowardsasystematicstudyoftheinterfacetounveiltheenergytransfermechanismincore-shellsystems.