SYNTHESIS OF THE COPOLYMERS OF p-DIETHYNYLBENZENE WITH OTHER ACETYLENIC DERIVATIVE S INITIATED BY （Ph3P）2 PdCl2-中国期刊网

摘要 Thecopolymerizationofp-diethynylbenzene（PDEB）withphenylacetylene（PhA）,4,4’-diethynylbiphenyl（DEBP）orm-diethynylbenzene（MDEB）arestudiedbyvaryingmoleratiosofmonomers.WhenthemoleratiosofPDEB/PhAarelessorequalto1/5,thecopolymersaresolubleandfusible,buttheothercopolymersareinsolubleandinfusible.Theresultsshowthatthegoodsolventofcross-linkedcopolymersisbenzeneandtheirsolubilityparameteris9.15cal0.5.cm（-1.5）.Andtheirswellability（θp）,Hugginsparameter（χ）,density(d425)andtheaveragemolecularweightsbetweencrosslinks（c）aremeasured.Itisfoundthatθpandcofcopolymersaregreaterbutd425islessthanthatofrespectivehomopolymers.IRspectrashowthatthecopolymershavetransoidconfigurationandsmallnumberofunreactedethynylgroupsexistinthecopolymers.Themechanismaboutthepolymerizationoracetylenicderivativesinitiatedby（Ph3P）2PdCl2isdiscussed.

1何晓康;刘建鹏;张祥;沈咏;邹宏新. Forbidden transition properties of fine-structure 2p3 4S3/2-2p3 2Da/2,s/2 for nitrogen-like ions.物理,2018-08.
2Jiang, H;Xu, Y;Liao, SJ;Yu, DR;Chen, H;Li, XJ. Carbonylation　of　Allyl　Chloride　Catalyzed　by　PdCl2（TPPTS）2　in　Two－phase　Medium.化学,1996-09.
3童叶翔;康北笙;苏成勇;余小岚;陈小明. Synthesis and crystal structure of [Co（mpt）2{P（OCH3）3}2]BF4 （Hmpt = 2-mercaptothiazoline）.化学,1999-01.
4廖广睿;平荣刚;杨永栩. Helicity Amplitude Analysis of e^＋e^- ψ（2S） → γχcJ→γ∧∧^-→γpπ^-p^-π^＋＊.物理,2009-05.
5Rongxin Zeng. LEGAL REGULATIONS IN P2P FINANCING IN THE U.S. AND EUROPE.法学理论,2013-03.
6FuqingZHANG;YulinHUA;等. SYNTHESIS OF POLY{（p—PHENYLENEVINYLENE）—alt—p,m—[2—PHENYL—5—（p—PHENYLENEVINYLENE）—1,3,4—OXADIAZOLYL]} WITH DEFINED CONJUGATION LENGTH AND IMPROMVED SOLUBILITY.高分子化学,2000-03.
7彭飞;陈磊. 基于S-P2P的教育资源整合平台.教育学,2010-03.
8叶文龙. P2P技术探索.计算机软件与理论,2014-12.
9Wei Wei;Gao Shou-Bao;Sun Zhao-Peng;Song Yu-Zhi;Meng Qing-Tian. A typical slow reaction H（2S）＋ S2（X3∑g） → SH（X2П）＋S（3P） ona new surface： Quantum dynamics calculations.物理,2014-07.
10程黎艳. P2P网络模型研究.教育学,2008-03.

SYNTHESIS OF THE COPOLYMERS OF p-DIETHYNYLBENZENE WITH OTHER ACETYLENIC DERIVATIVE S INITIATED BY （Ph3P）2 PdCl2

来源期刊

相关推荐

同分类资源更多

相关关键词

SYNTHESIS OF THE COPOLYMERS OF p-DIETHYNYLBENZENE WITH OTHER ACETYLENIC DERIVATIVE S INITIATED BY （Ph3P）2 PdCl2

来源期刊

相关推荐

同分类资源 更多

相关关键词

同分类资源更多