THE EXTRACTION OF GOLD FROM CYANIDE SOLUTION BY α—ALKYL SUBSTITUTED PYRIDINE RESIN

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摘要 Inthispaper,wehavestudiedtheadsorptionpropertiesofgoldbyα-alkylsubstitutedpyridineresin(BPR)inalkalinesolution.ThesingleanddualcomponentkineticmasstransferprocessofAu(I),Ag(I)andothermetalcyanideionswerealsoinvestigated.Theresultsobtainedshowthatthemasstransferratesofthecyanideionsintheresinphasearecloselyrelatedtothemolarratioandtheconfigurationofmetalcyanideions.TheelutionkineticsofAu(I)andothercyanideionsbyNH4SCNhasbeeninvestigatedsystematically.TheintraparticlediffusioncoefficientandactivationenergyofAu(I),Ag(I),Ni(I)Fe(Ⅲ)cyanideanionsweredeterminedinCI,NO3,OH-typeBPRresinatdifferenttemperatures.ItisfoundfromtheexperimentalresultsthatthemechanismforextractingAu(I),Ag(I)andothermetalcyanideanionsbyBPRresinbelongstoionexchangeprocess.Thedifferenceofactivationentropyofsomemetalcyanideanions(ΔS-ΔS^-)wasevaluated.
机构地区 不详
出版日期 1992年02月12日(中国期刊网平台首次上网日期,不代表论文的发表时间)
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