摘要
4newmodel,phaseequilibrium-kineticsmodel(PEKM),forestimationofdiffusioncoefficientwasproposedinthispaper.KineticexperimentsofphenoldesorptiononNKAIIresininthepresenceandtheabsenceofultrasoundwereseparatelyconducted,anddiffusioncoefficientsofphenolwithinanadsorbentparticlewereestimatedbymeansofproposedPEKMandclassicsimplifiedmodel.ResultsshowthattheuseofultrasoundnotonlychangesthephaseequilibriumstateofNKAllresin/phenol/watersystemwhichhadbeenequilibriumatnormalcondition,butalsoenhancesdiffusionofphenolwithintheresin.ThediffusioncoefficientofphenolintheresininthefieldofultrasoundincreasesinanorderofmagnitudeincomparisonwiththediffusioncoefficientdeterminedundernoultrasoundExperimentalresultsalsoindicatedthatthediffusioncoefficientsestimatedbyPEKMweremoreaccuratethanthatestimatedbytheclassicsimplifiedmodel.
出版日期
2002年01月11日(中国期刊网平台首次上网日期,不代表论文的发表时间)