Liquid phase synthesis of dendritic nickel carbide alloy with high conductivity for advanced energy storage

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摘要 Alloymaterialshaveattractedincreasingattentionsbecausetheypossesssuperiorelectricalconductivitywhichcancontributetoexcellentelectrochemicalperformance.HereinadendriticNi3Calloymaterialhasbeenpreparedbythepyrolysisofnickelacetylacetonateemployingoleylamineasareductantand1-octadeceneoroctadecaneasthesolvent.Thecurrent–voltagecurvesindicatingthattheelectricalconductivityofNi3Cishigherthanthatofnickeloxide.Electrochemicaltestingindicatesthatahighspecificcapacityof390C/gisfoundinalkalineelectrolyteat0.5A/g,anddeliverexcellentratecharacteristicaswellascyclelife.Theexcellentelectrochemicalperformancemaybeattributedtoitshighelectricalconductivityanddendriticnanostructurethatcanpromotediffusionofelectrolyteions.Inaddition,theAC//Ni3Casymmetricsupercapacitorhasbeenassembledatacellvoltagesbetween0and1.6V,achievingamaximumenergydensityof37Wh/kg(atapowerdensityof0.3995kW/kg),andthismanifeststhattheNi3Calloyisapromisingelectrodematerialforelectrochemicalenergystorage.
机构地区 不详
出处 《能源化学:英文版》 2017年4期
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出版日期 2017年04月14日(中国期刊网平台首次上网日期,不代表论文的发表时间)
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