Salen-Cu（Ⅱ）@MIL-101（Cr） as an efficient heterogeneous catalyst for cycloaddition of CO2 to epoxides under mild conditions-中国期刊网

摘要 Adoubleactivecentersystem,namelySalen-Cu（Ⅱ）@MIL-101（Cr）,wassuccessfullysynthesizedviathe“shipinabottle”approach,whichactedasabifunctionalmaterialforbothcaptureandconversionofCO2inasingleprocess.Forthefirsttime,Salen-Cu（Ⅱ）@MIL-101（Cr）catalystwasdevelopedforthesynthesisofpropylenecarbonatefromCO2andpropyleneoxideunderroomtemperatureandambientpressurewithayieldof87.8%over60h.Furthermore,thereactionmechanismwasalsodiscussed.

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Salen-Cu（Ⅱ）@MIL-101（Cr） as an efficient heterogeneous catalyst for cycloaddition of CO2 to epoxides under mild conditions

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Salen-Cu（Ⅱ）@MIL-101（Cr） as an efficient heterogeneous catalyst for cycloaddition of CO2 to epoxides under mild conditions

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