摘要
Pt-freecounterelectrode（CE）composedofLa2MoO6（La2O3-MoO3）wassuccessfullysynthesizedbysimplepyrolysisoflanthanumacetate（C6H9O6La·xH2O）andhexaammoniumheptamolybdatetetrahydrate(（NH4）6Mo7O24·4H2O).Furthermore,threeproportionscompositescatalystsofLa2MoO6@MWCNTsbasedonLa2MoO6andmultiwallcarbonnanotubes（MWCNTs）werepreparedandcharacterizedasPtfreecatalystforCEindye-sensitizedsolarcells（DSSCs）.ThemorphologyandstructureofLa2MoO6@MWCNTscompositesweredeterminedbyscanningelectronmicroscopy,transmissionelectronmicroscopeandX-raydiffraction.TheelectrochemicalperformanceofLa2MoO6@MWCNTscompositecatalystsforCEswasdeterminedbyphotocurrent-voltagemeasurements,cyclicvoltammetry,electrochemicalimpedancespectroscopy,andTafelpolarization.Thepowerconversionefficienciesof4.68%,4.87%and5.06%areobtainedforLa2MoO6:MWCNTswiththemassratiosof5:1,3:1and1:1towardsthereductionofI3-toI-underthesameconditions,respectively,whicharesuperiortothoseofMWCNTs（3,94%）andLa2MoO6（1.71%）electrodes.TheexperimentalresultsrevealthatthepresenceofMWCNTsresultsinanaugmentedactivecatalyticsurfaceareaandenhancedchargetransferfromCEtotheelectrolyte.
出版日期
2018年12月22日（中国期刊网平台首次上网日期，不代表论文的发表时间）
