Recycled Nd-Fe-B sintered magnets prepared from sludges by calcium reduction-diffusion process

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摘要 EnvironmentalfriendlyrecyclingprocessforNd-Fe-Bsinteredmagnetsludgesgeneratedinthemanufacturingprocess,whichcontainlargeamountofrareearth,includingNd,PrandDy,isbadlyneededsofar.Inpresentstudy,wehavedevelopedaneffectiveroutetoobtainrecycledsinteredmagnetsfromNd-Fe-Bsinteredmagnetsludgesbycalciumreduction-diffusion(RD)process.Comparedtoconventionalrecyclingprocess,ourresearchisfocusedonrecoveringmostoftheusefulelements,includingNd,Pr,Dy,Co,andFetogetherinsteadofjustrareearthelements.Toimprovetherecyclingefficiencyandreducepollution,theco-precipitatingparametersweresimulatedandcalculatedusingMATLABsoftware.Mostofusefulelementswererecoveredbyaco-precipitationmethod,andtheobtainedcompositepowderswerethendirectlyfabricatedasrecycledNd-Fe-Bpowdersbyacalciumreduction-diffusion(RD)method.Therecoveryratesare98%,99%,99%,93%,and99%,forNd,Pr,Dy,Co,andFe,respectively.Theamountofusefulelementscontainedintherecoveredcompositepowdersisgreaterthan99.71wt%.TheprocessofRDforsynthesizingNd2Fe14BandsubsequentlyremovingCaOwasthoroughlyinvestigated.Furthermore,therecycledNd-Fe-Bmagnetexhibitsaremanenceof1.1T,acoercivityof1053kA/m,andanenergyproductof235.6kJ/m3,respectively,indicatingthatrecycledNd-Fe-Bsinteredmagnetwassuccessfullyrecoveredfromtheseverelycontaminatedsludgesviaaneffectiverecyclingroute.
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出版日期 2018年12月22日(中国期刊网平台首次上网日期,不代表论文的发表时间)
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