Synthesis of δ-meso-formylvinylchlorin and Benzoisobacterichlorin by Vilsmeier Reaction with Methyl Pyropheophorbide-a-中国期刊网

摘要 Frommethylpyropheophorbide-a(MPPa,1),thevinylgroupofmethylpyropheophorbide-awasconvertedintoalkylcarbonylgroupbyGrignardreactionandoxidizationtogivechlorins2,3and5.TheVilsmeierreactionofnickel3-substituent-3-devinylpyropheophorbide-a(6),whichwaspreparedbythemetallationwithnickelacetate,with3-dimethylamino-acrolein/phosphorylchloride(3-DMA/POCl3)wascarriedouttogiveδ-meso-formylvinylpyropheophorbide-a(7)ingoodyield.Thebenzoisobacterichlorin(8)wasobtainedbythetreatmentof7bwithconcentratedsulfuricacid.

1Lingyun Rong;Zhongning Xu;Jing Sun;Guocong Guo. New methyl formate synthesis method： Coal to methyl formate.物理,2018-01.
2朱士正;许国林;钦朝岳;许勇;储千里. Preparation and reaction of bis (perfluoroalkanesulfonyl) methyl halides.化学,1998-03.
3R.Haywood J.R.Edbon 等. SYNTHESIS AND REACTION OF TELECHELIC OLIGOMERS.高分子化学,2000-12.
4ZHANG Bo;LI Aimin;TAO Weihua;YANG Weiben. STUDY ON SIDE REACTION IN THE SYNTHESIS OF HYPERCROSSLINKED POLYMERS.高分子化学,2008-01.
5Yi Luo Ping Zhong Xiao Hong Zhang Qiu Lian Lin Ye Na Chen. Formylation of N-arylpyrazole containing active amino group using Vilsmeier-Haack reaction.化学,2008-04.
6陈柳生;王国昌;Mitchell A.Winnik. SYNTHESIS AND CHARACTERIZATION OF 1-NAPHTHYLMETHYL METHACRYLATE-METHYL METHACRYLATE COPOLYMERS.高分子化学,1986-03.
7LIU Rui;LU Anhuai;QIN Shan. Synthesis of Pb-Feldspar by Ion Exchange Reaction and Its Implications.地质学,2006-02.
8Rui Tao;Xue-Jiao Yin;Ke-Hu Wang;Yu-Zhuo Niu;Ya-Lin Wang;Dan-Feng Huang;Ying-Peng Su;Jin-Xian Wang;Yu-Lai Hu;Ying Fu;Zheng-Yin Du. Solvent free synthesis of trifluoromethyl tertiary alcohols by cross Aldol reaction.化学,2015-08.
9Jingcheng Zhang;Jun Nan;Zhangyong Liu;Haibin Yu;Shan Geng;Yulin Shi;Xiaolong Qu;Chenguang Liu;Hongguang Liu. Synthesis of Special Morphology ZnO Materials and the Performance for Reaction Adsorption Desulfurization of Thiophene.物理,2013-01.
10ShanminGao;LiPang;HongweiChe;XiaopingZhou. SYNTHESIS OF SnO2 NANOCRYSTALS BY SOLID STATE REACTION FOLLOWED BY CALCINATION.力学,2004-04.

Synthesis of δ-meso-formylvinylchlorin and Benzoisobacterichlorin by Vilsmeier Reaction with Methyl Pyropheophorbide-a

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Synthesis of δ-meso-formylvinylchlorin and Benzoisobacterichlorin by Vilsmeier Reaction with Methyl Pyropheophorbide-a

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