学科分类
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219 个结果
  • 简介:经过槽下系统的设备改造,实现了槽下过筛,入炉粉率降低,为一系列的技术进步提供了基础保障,阐述了各项生产技术进步与生产实践.

  • 标签: 高炉 槽下改造 入炉粉率 生产实践 炼铁
  • 简介:本文在0.0016%亚硝基R盐-0.75摩尔/升氯化铵,pH=9条件下,镍于-0.42伏(VS.S.C.E.)产生吸附催化波,波形好,镍浓度在0.01~0.6微克/毫升范围内有线性关系。常见的共存离子有一定的允许量,对一些镍矿石样品的分析结果与标准值无明显偏差。

  • 标签: 催化极谱 亚硝基R盐 氯化铵
  • 简介:从离子型稀土矿床的地质特征与原地浸析采矿的工艺特点及其应用条件出发,首次时我国南方的离子型稀土矿进行具体分类.阐述了分类的原则、各类别特征及在原地浸析采矿工艺特点,最终提出了分类总表。

  • 标签: 分类 离子型稀土矿 原地浸析
  • 简介:在pH=4.7的六次甲基四胺缓冲介质钒(Ⅳ)与依来铬青R、CPB形成蓝紫色的三元配合物,其组成为1:3:3,λmax=590nm,表观摩尔吸光系数为4.0×104L/mol·cm,钒在0~25μg/25mL范围内遵守比耳定律,用于钢钒的测定,结果准确可靠.

  • 标签: 钒(Ⅳ) 依来铬青R 吸光光度法 测定
  • 简介:Inthiswork,boththethermalexpansionandelectricalconductivityofnanocrystallineLa2Mo2O9werestudied.ThenanocrystallinepowderofLa2Mo2O9wasobtainedbysol-gelmethod,andwiththehelpofSHP(superhighpressure)upto4.5×104atmat700℃forashorttime,andthenanocrystallinepowderwasdensifiedwithoutobviousparticlesizegrowth.TheelectricalconductivityofnanocrystallineLa2Mo2O9wasoneorderofmagnitudelowerthanthatofthemicrocrystallinesampleatthesametemperature.Owingtothephasetransition,themicrocrystallineLa2Mo2O9hasanabruptincreaseofthermalexpansionwithapeakvalueof48×10-6K-1at556℃.Forthenanocrystallinematerial,thepeakvalueincreasesto112×10-6K-1at520℃.Ontheotherhand,above600℃thesignificantgrowthofparticlesizeofthenanocrystallineLa2Mo2O9wasobserved,accompanyingbyatremendousincreaseofthermalexpansionwithapeakvalueofthirdhigherthanthatofLa2Mo2O9.

  • 标签: NANOCRYSTALLINE electrical CONDUCTIVITY LANTHANUM MOLYBDATE superhigh
  • 简介:Basedonthethermodynamicallyself-consistentanalysisandoptimizationofthreesub-binarysystemsoftheternarysystemPrCl3-CaCl2-MgCl2,thethermodynamicsofthisternarysystemhasbeenstudied.UsingHillertmodelandtakingMgCl2asanasymmetriccomponent,thePrCl3-CaCl2-MgCl2phasediagramhasbeencalculated.Theagreementbetweencalculatedandmeasuredcompositionsandtemperaturesatdeflectingpointsonliquidusisgood.Thesystemisasimpleeutecticonewithaeutecticpointat26.0mol%PrCl3,41.5mol%CaCl2,32.5mol%MgCl2;560℃(calculated)and26.0mol%PrCl3,39.4mol%CaCl2,34.6mol%MgCl2;546℃(measured),respectively.

  • 标签: TERNARY system Phase DIAGRAM Rare earth
  • 简介:TheZrO2-Al2O3ceramiccompositeswerepreparedbyappropriatetechniqueswithcommercialZrO2andAl2O3powdersasrawmaterialsandY2O3asstabilizer.TheresultsindicatethatwiththeintroductionofAl2O3intotheZrO2matrixwherethequantityofadditiveY2O3is3.5%(molefraction),thegrowthofZrO2grainsisefficientlyinhibited,whichhelpstheZrO2grainsexistinametastabletetragonalmanner;thushigherstrengthandtoughnessareacquired.Whenthecontentofaluminais20%(massfraction),thebendingstrengthandfracturetoughnessofthecompositesare676.7MPaand10MPa·m1/2respectively,themechanicalbehaviorsareclosetothosepreparedwithZrO2andAl2O3powderssynthesizedthroughwetchemicalapproach.Themechanicalbehaviorsofthecompositesarewellimprovedowingtothedispersiontougheningofaluminagrainsandphasetransformationtougheningofzirconiagrains.

  • 标签: 无机非金属材料 陶瓷 稳定设备 稀土
  • 简介:FluorescencespectraofSm2+andEu2+→Sm2+energytransferwerestudiedinSrB4O7.Thereappearsonlyfluorescencefrom5D0transitionofSm2+at77K.Thevibroniclinesassociatedwith5D0→7F0transitionwereobserved.Thethermalpopulationtoupperstatesof5D1and4f5dlevelsfrom5D0givesriseto5D1→7FJand5d→4fradiativetransitionsofSin2+athighertemperature.

  • 标签: Strontium-samarium BORATE Energy transfer ELECTRON-PHONON interaction
  • 简介:Reactionof(MeC5H4)3LnwithHOCH2CH2NMe2intetrahydrofuran(THF)givesthenewcomplexes[(MeC5H4)2Ln(μ-OCH2CH2NMe2)]2(Ln=Sm,Y,Nd)withnitrogenfunctionalizedμ-alkoxideligand.ThecomplexeswerecharacterizedbyelementalanalysisandIR,and[(MeC5H4)2Sm(μ-OCH2CH2NMe2)]2wasstructurallycharacterizedbytheX-raydiffractiontobeadimerformedbytwounsymmetricoxygenbridges.ThecomplexhasatricyclicskeletonwiththeadditionaltwoSm-NbondsviaintramolecularcoordinationofOCH2CH2NMe2.ThecoordinationnumberofthecentralmetalSmisnine.Thetitlecomplexesshowgoodcatalyticactivityforring-openingpolymerizationofε-caprolactone.

  • 标签: 2 晶体结构 合成 镧系元素 ε-已内酯 聚合
  • 简介:Inthispaper,varioustechniquesincludingBET,XRD,SEMandXPSwereusedtostudythesinteringofpureandLa2O3-dopedtitania.Theexperimentalresultsshowthatsinteringoftitaniaproceedsviavolumediffu-sion.Addingoflanthanumoxidedecreasestherateofsinteringandhindersthephasetransitionfromanatasetorutilecrystalbystrongsurfaceinteractionbetweenthemixedcrystals(La4Ti9O24,La0.66TiO2.99)andTiO2.

  • 标签: La2O3 TiO2 SINTERING kinetics Thermal stability
  • 简介:铝山西分公司氧化铝3因转窑窑前鼓风机因轴承失效、机壳移位等原因造成风机振动大,虽更换了轴承恢复了机壳位置,但振动未消除:后采用因素排除的方法,在检修过程实行过程工序确认制度,最终找出了风机振动大的原因,和对缺陷处理的方法.

  • 标签: 氧化铝 回转窑 鼓风机 振动 动平衡 裂缝
  • 简介:Ca8Mg(SiO4)4Cl2:Eu2+phosphordopedwithSr2+cationforCa2+partially,wassynthesizedbysolid-statereactionathightemperatureunderreducingatmosphere,anditsluminescentpropertieswereinvestigated.TheexperimentalresultsindicatethattheemissionintensityofthephosphorincreasesafterbeingdopedwithafewamountofSr2+ion.Theemissionpeakofthephosphorblueshifttoabout464nmwhenthephosphorisdopedwithlargequantityofSr2+ions.TheexcitationspectrumindicatesthatthephosphorcanbewellexcitedbyUVandbluelightfrom300to460nm,andthephosphorwasfittedwellfortheexcitationbyUVorblue-LED.

  • 标签: CALCIUM MAGNESIUM chlorosilicate Eu2+ emission SPECTRUM
  • 简介:近日,铝河南分公司2005年重点建设项目——碳素厂3焙烧炉已破土动工。碳素厂3焙烧炉项目总投资1.35亿元。该工程是分公司适应市场新形势、提升碳素产品国际竞争力的一个重点建设项目,工程设计采用了国际先进的碳素焙烧技术,不仅具有先进的节能降耗功能,而且投资节约,运行经济。该项目的建设可为分公司新增6万t的高品质出口碳阳极焙烧能力,及优化河南分公司产业链条,做优碳素板块,提升竞争实力。

  • 标签: 中铝河南分公司 焙烧炉 碳素厂 重点建设项目 2005年 项目总投资
  • 简介:山西铝厂热电分厂4汽轮机在事故动静部分严重磨擦,造成转子报废.对这一事故的原因进行了分析探讨,并提出了改进和保护的措施.

  • 标签: 热电厂 汽轮机 转子损坏 事故分折 摩擦
  • 简介:黄磷(Bi1-xSmx)2ZnB2O7(x=0.01,0.03,0.05,0.07,和0.09)被常规稳固的州的反应综合。所有样品的纯净被X光检查粉末衍射(XRD)检查。XRD分析证明所有这些混合物具有Bi2ZnB2O7的一个单个阶段,显示在Bi2ZnB2O7的双性人(3+)能被没有晶体结构的变化的Sm(3+)部分代替。在房间温度的刺激和排放系列显示出Sm(3+)的典型4f-4f转变。主导的刺激线在404nm附近由于(6)H5/2→(4)K11/2和排放光谱在563,599,646,和704nm由一系列线组成由于(4)G5/2→(6)H5/2,(6)H7/2,(6)H9/2,并且(6)H11/2分别地。在Bi2ZnB2O7的Sm(3+)的最佳的集中关于3mol%(相对1mol双性人(3+))并且批评距离Rc作为2.1nm被计算。Bi1.94Sm0.06ZnB2O7的排放紧张的温度依赖在在100和450K之间的温度范围被检验。紧张下降了到起始的紧张的一半的熄灭的温度是280K。为在Bi1.94Sm0.06ZnB2O7的Sm(3+)的一生作为0.29和1.03ms的价值被适合。

  • 标签: Bi2ZnB2O7 稀土 发光性能 荧光材料 浓缩猝灭 热猝灭
  • 简介:LongafterglowphotoluminescentmaterialsSr2MgSi2O7dopedwithEu2+,Dy3+werepreparedbysol-gelmethod.ThesynthesizedsampleswerecharacterizedbyX-raydiffraction.Theexcitationspectrum,emissionspectrumandlongdecaycurveweremeasuredandanalyzed.XRDpatternindicatesthatphosphoriswithSr2MgSi2O7crystalstructure.Thewiderangeofexcitationwavelengthindicatesthatluminescentmaterialcanbeexcitedbylightfromultravioletraytovisiblelight.Themainpeakofemissionspectrumislocatedat466nm.Sampleexcitedbyvisiblelightcanemitbrightbluelight,andtheafterglowtimelastsmorethan8h.

  • 标签: 发光材料 无机非金属材料 稀土