学科分类
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1 个结果
  • 简介:Inthisworktypicalmechanicalpropertiesforacatalystsupportmaterial,ZSM5(aspray-driedgranularzeolite),havebeenmeasuredinordertorelatethebulkbehaviourofthepowdermaterialtothesingleparticlemechanicalproperties.Particleshapeandsizedistributionofthepowders,determinedbylaserdiffractionandscanningelectronmicroscopy(SEM),confirmedthesphericalshapeofthespray-driedparticles.TheexcellentflowabilityofthematerialwasassessedbytypicalmethodssuchastheHausnerratioandtheCarrindex.Thiswasconfirmedbybulkmeasurementsoftheparticle-particleinternalfrictionparameterandflowfunctionusingaSchulzeshearcell,whichalsoillustratedthelowcompressibilityofthematerial.SingleparticlecompressionwasusedtocharacterizesingleparticlemechanicalpropertiessuchasreducedelasticmodulusandstrengthfromHertzcontactmechanicstheory.Comparisonwithsurfacepropertiesobtainedfromnanoindentationsuggestsheterogeneity,thesurfacebeingharderthanthecore.Inordertoevaluatetherelationshipbetweensingleparticlemechanicalpropertiesandbulkcompressionbehaviour,uniaxialconfinedcompressionwascarriedout.ItwasdeterminedthattheAdamsmodelwassuitablefordescribingthebulkcompressionandfurthermorethattheAdamsmodelparameter,apparentstrengthofsingleparticles,wasingoodagreementwiththesingleparticlestrengthdeterminedfromsingleparticlecompressiontest.

  • 标签: ZSM-5沸石 机械性能 颗粒形状 喷雾干燥 催化剂载体材料 扫描电子显微镜