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500 个结果
  • 简介:ThesplittingofpotentialenergylevelsforgroundstateX2ΠgofOx2(x=+1,1)underspin–orbitcoupling(SOC)hasbeencalculatedbyusingthespin–orbit(SO)multi-configurationquasi-degenerateperturbationtheory(SO-MCQDPT).TheirMurrell–Sorbie(M–S)potentialfunctionsaregained,andthenthespectroscopicconstantsforelectronicstates2Π1/2and2Π3/2arederivedfromtheM–Sfunction.TheverticalexcitationenergiesforOx2(x=+1,1)areν[O+12(2Π3/2X2Π1/2)]=195.652cm1,andν[O12(2Π1/2X2Π3/2)]=182.568cm1,respectively.Allthespectroscopicdataforelectronicstates2Π1/2and2Π3/2aregivenforthefirsttime.

  • 标签: 分子结构 势能函数 自旋轨道耦合 电子态
  • 简介:QuantumdynamicscalculationsforthetitlereactionH(2S)+S2(X3-Σg)→SH(X2Π)+S(3P)areperformedbyusingagloballyaccuratedoublemany-bodyexpansionpotentialenergysurface[J.Phys.Chem.A1155274(2011)].TheChebyshevrealwavepacketpropagationmethodisemployedtoobtainthedynamicalinformation,suchasreactionprobability,initialstate-specifiedintegralcrosssection,andthermalrateconstant.Itisfoundnotonlythatthereisareactionthresholdnear0.7eVinbothreactionprobabilitiesandintegralcrosssectioncurves,butalsothatboththeprobabilityandcrosssectionincreasefirstlyandthendecreaseasthecollisionenergyincreases.Theexistenceoftheresonancestructureinboththeprobabilityandcrosssectioncurvesisascribedtothedeeppotentialwell.Thecalculationoftherateconstantrevealsthatthereactionoccurringonthepotentialenergysurfaceoftheground-stateHS2isslowtotakeplace.

  • 标签: 反应概率 动力学计算 上海 量子 表面 截面曲线
  • 简介:Multimediastreamingservedthroughpeer-to-peer(P2P)networksisboomingnowadays.However,theend-to-endstreamingqualityisgenerallyunstableduetothevariabilityofthestateofserve-peers.Ontheotherhand,proxycachingisabandwidth-efficientschemeforstreamingovertheInternet,whereasitisasubstantiallyexpensivemethodneedingdedicatedpowerfulproxyservers.Inthispaper,wepresentaP2PcooperativestreamingarchitecturecombinedwiththeadvantagesofbothP2Pnetworksandmultimediaproxycachingtechniquestoimprovethestreamingqualityofparticipatingclients.Inthisframe-work,aclientwillsimultaneouslyretrievecontentsfromtheserverandotherpeersthathaveviewedandcachedthesametitlebefore.Inthemeantime,theclientwillalsoselectivelycachetheaggregatedvideocontentsoastoservestillfutureclients.Theassociateprotocoltofacilitatethemulti-pathstreamingandadistributedutility-basedpartialcachingschemearedetailedlydis-cussed.Wedemonstratetheeffectivenessofthisproposedarchitecturethroughextensivesimulationexperimentsonlarge,Inter-net-liketopologies.

  • 标签: 分布式高速缓存 P2P网络 流媒体服务 体系结构
  • 简介:P2Psystemsarecategorizedintotree-basedandmesh-basedsystemsaccordingtotheirtopologies.Mesh-basedsystemsareconsideredmoresuitableforlarge-scaleInternetapplications,butrequireoptimizationonlatencyissue.Thispaperproposesacontentsubscribingmechanism(CSM)toeliminateunnecessarytimedelaysduringdatarelaying.Anodecansendcontentdatatoitsneighborsassoonasitreceivesthedatasegment.Noadditionaltimeistakenduringtheinteractivestagespriortodatasegmenttransmissionofstreamingcontent.CSMconsistsofthreesteps.First,everynoderecordsitshistoricalsegmentslatency,andadoptsgammadistribution,whichpossessespowerfulexpressionability,toexpresslatencystatistics.Second,anodepredictssubscribingsuccessratioofeveryneighborbycomparingthegammadistributionparametersofthenodeanditsneighborsbeforeselectinganeighbornodetosubscribeadatasegment.Theabovestepswouldnotincreaselatencyastheyareexecutedbeforethedatasegmentsarereadyattheneighbornodes.Finally,thenode,whichwassubscribedto,sendsthesubscribeddatasegmenttothesubscriberimmediatelywhenithasthedatasegment.ExperimentsshowthatCSMsignificantlyreducesthecontentdatatransmissionlatency.

  • 标签: 国际互联网 分布特点 流动特点 P2P技术
  • 简介:ThespectrumoftheΣ(1193)excitedstates,Σ,withisospinI=1andstrangenessS=??1isoneofthemostimportantissuesinhadronicphysics.TheΣresonancesaremostlyproducedandstudiedinK-inducedreactions.ManyΣresonancesarenowcatalogedbytheParticleDataGroup[1].However,ourknowledgeoftheseresonancesisstillverypoor.Intheenergyregionbelow2GeV,onlyafewofthemarewellestablished,suchastheΣ(1385)ofspin-parityJP=3=2+,Σ(1670)ofJp=3=2??andΣ(1775)ofJp=5=2??.Theothersarenotwellestablishedandsomeofthemareevenoflargeuncertaintiesontheirexistence.Thus,thestudyoftheΣresonancewiththeavailableexperimentaldataisnecessary.

  • 标签: EXPERIMENTAL Π now OUR is
  • 简介:强力旋压是机械加工中的常用方法,它依靠旋轮从工件的表面给材料施加巨大的成型力,使材料整体发生强烈塑性变形而形成所需要的最终形状,在旋轮-工件接触区域,由于旋轮的被动自转,还存在着复杂的多方向的摩擦力,这对工件表面和表层组织形貌有着重要的影响。

  • 标签: 旋压法 表面纳米化 塑性变形 低碳钢
  • 简介:WehavesynthesizedandinvestigatedphysicalpropertiesoftwonewquaternarycompoundsGd2CoAl4T2(T=Si,Ge)singlecrystals,whichareisostructuraltoTb2NiAl4Ge2andEr2CoAl4Ge2.Themostimportantstructuralfeatureofthesematerialsistheanti-CaF2-typeCoAl4T2slabs.Thesematerialsshowmetallicbehaviorbelow300Kandthereisalong-rangeantiferromagnetic(AFM)transitionappearingat20and27KforGdCoAl4Ge2andGd2CoAl4Si2,respectively.ResistivityandheatcapacitymeasurementsalsoconfirmthesebulkAFMtransitions.Furtheranalysisindicatesthatthislong-rangeantiferromagnetismshouldresultfromthemagneticinteractionbetweenlocalmomentsofGd^3+ions.

  • 标签: magnetic MAT erials RARE earth COMPOUNDS
  • 简介:ThegrowinginterestintheuseofGalliumArsenidssemiconductormaterialshaspresentedmanyopportunitiesfordeviceoperationalspeedimprovementsbuthasalsopresentedmanyproblemsforthedevicemaker,Anoveldeep-submicronx-raylithographyprocessforT-shapedgatepatternsusefulforhigh-electron-mobilitytransistors(HEMT)isintroducedinthiswork.InthefabricationofT-shapedgateatherrlayerresistsmethodisused.Thex-rayexposureexperimentswerefinishedbyBeijingSynchrotronRadiationFacility(BSRF)3B1Abeamline,andgoodresulthasbeenobtained.

  • 标签: X射线平板印刷术 半导体二极管器件 T-型门图样
  • 简介:研究目的:研究新型磁性回热填料Gd2O2S对液氦温区高频脉管制冷机多级回热器损失特性的影响。创新要点:确定了不同回热填料以及运行参数(频率、平均压力)下液氦温区多级脉管制冷机的制冷温度和各级预冷量,进一步明确了4K高频回热损失机理。研究方法:采用理论研究与实验验证相结合的方法,基于一台两级G-M型低频脉管制冷机预冷的单极斯特林型高频脉管制冷机,研究多级回热器在高频以及4K温区下的损失特性。选取新型回热填料Gd2O2S替代部分回热填料HoCu2比较回热器采用两种填料时在不吲运行频率及平均压力下的冷端制冷温度(图10)、各级预冷量和预冷温度(图1112)。重要结论:采用孔隙率较小的新型磁性回热填料Gd2O2S可显著改善第一级回热器内压力波与质量流的相位关系,从而减小该级回热损失。减小平均压力可以降低制冷机无负荷制冷温度并减小第二级预冷量,但制冷工质氦的体积比热容会急剧增大,从而使低温级回热器的换热对频率非常敏感。此外,频率对高温级回热器的回热特性影响不明显。该方法可以为三级斯特林型4K多级脉管制冷机提供设计依据。

  • 标签: 斯特林型脉管制冷机 回热填料 4K 高频 预冷 低温惯性管