学科分类
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5 个结果
  • 简介:COandformaldehyde(HCHO)oxidationreactionswereinvestigatedovermesoporousAg/Co3O4catalystspreparedbyone-pot(OP)andimpregnation(IM)methods.Itwasfoundthattheone-potmethodwassuperiortotheimpregnationmethodforsynthesizingAg/Co3O4catalystswithhighactivityforbothreactions.ItwasalsofoundthatthecatalyticbehaviorofmesoporousCo3O4andAg/Co3O4catalystsforthebothreactionswasdifferent.AndtheadditionofsilveronmesoporousCo3O4didnotalwaysenhancethecatalyticactivityoffinalcatalystforCOoxidationatroomtemperature(20C),butcouldsignificantlyimprovethecatalyticactivityoffinalcatalystforHCHOoxidationatlowtemperature(90C).Thehighsurfacearea,uniformporestructureandtheprettygooddispersiondegreeofthesilverparticleshouldberesponsiblefortheexcellentlow-temperatureCOoxidationactivity.However,forHCHOoxidation,theadditionofsilverplayedanimportantroleintheactivityenhancement.AndthesilverparticlesizeandthereducibilityofCo3O4shouldbeindispensableforthehighactivityofHCHOoxidationatlowtemperature.

  • 标签: MESOPOROUS materials Co3O4 AG CO OXIDATION
  • 简介:利用质谱法定量分析了^6Li(n,α)T反应中伴随产生的^4He核,得到了产氚量。采用自膨胀密封方法在常温下定量制备了密封锂铅合金靶。靶件在西安脉冲堆的跑兔辐照通道内辐照了2h,冷却15d后进行测量。建立了去除氢同位素干扰的气体样品处理平台,并以含氢的模拟标准气进行了验证。研究并建立了测量。He的在线同位素稀释法,并用空气进行了验证。靶件在700℃被熔融后释放^4He,首次熔融的^4He释放率达到99.9%,产氚量测量结果的不确定度小于6%。

  • 标签: ^6LI ^4He 质谱
  • 简介:Inordertoinvestigatethefiresuppressioneffectivenessofwatermistwithmetalchlorideadditives,ultrafinewatermistsofthesesaltswithdiametersabout10μmwereintroducedintoCH4/airnon-premixedflameinthecupburner.Resultsshowedthatthesedropletshardtomakeitselftotheflamefrontunderthecupburnerflowconditionsfunctionedasacarrierofthevaporizedsolidparticlesoritsdecomposedmaterials.Themetalchlorideimprovedfiresuppressionefficacyofwatermistwhichwereaffectedbythetypeandconcentrationofmetalchloride.Onamassbasis,thereisafiresuppressioneffectivenessrelationshipofMgCl2

  • 标签: additive water MIST FIRE suppression CH4
  • 简介:MesoporousLiFePO4/Ccompositescontaining80wt%ofhighlydispersedLiFePO4nanoparticles(4-6nm)werefabricatedusingbimodalmesoporouscarbon(BMC)ascontinuousconductivenetworks.TheuniqueporestructureofBMCnotonlypromisesgoodparticleconnectivityforLiFePO4,butalsoactsasarigidnano-confinementsupportthatcontrolstheparticlesize.Furthermore,thecapacitieswereinvestigatedrespectivelybasedontheweightofLiFePO4andthewholecomposite.Whencalculatedbasedontheweightofthewholecomposite,itis120mAh·g-1at0.1Cofthehighloadingelectrodeand42mAh·g-1at10Cofthelowloadingelectrode.TheelectrochemicalperformanceshowsthathighLiFePO4loadingbenefitslargetapdensityandcontributestotheenergystorageatlowrates,whiletheelectrodewithlowcontentofLiFePO4displayssuperiorhighrateperformance,whichcanmainlybeduetothesmallparticlesize,gooddispersionandhighutilizationoftheactivematerial,thusleadingtoafastionandelectrondiffusion.

  • 标签: LiFePO4 HIGH loading fast ion diffusion