简介：Amodelstudyleadingtothepreparationoftheuniquetricyclo[6.2.1.0]undecaneBCDringsystemsofaconitineisdescribed.Thesynthesisfeaturesanunprecedenteddiastereoselectiveoxidativedearomatization/dimerization/retro-DA/IMDAcascadereactionandahighlyefficientWagner-Meerweinrearrangement.
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![Rapid construction of the unique BCD ring system of tricyclo[6.2.1.0] undecane in the C_（<b style='color:red'>19</b>）-diterpenoid alkaloid aconitine](/image/thesis0 "Rapid construction of the unique BCD ring system of tricyclo[6.2.1.0] undecane in the C_（<b style='color:red'>19</b>）-diterpenoid alkaloid aconitine")