简介:Differentialpulsestrippingvoltammetrymethod(DPSV)wasappliedtothedeterminationofthreeherbicides,ametryn,cyanatryn,anddimethametryn.Itwasfoundthattheirvoltammogramsoverlappedstrongly,anditisdifficulttodeterminethesecompoundsindividuallyfromtheirmixtures.Withtheaidofchemometrics,classicalleastsquares(CLS),principalcomponentregression(PCR)andpartialleastsquares(PLS),voltammogramresolutionandquantitativeanalysisofthesyntheticmixturesofthethreecompoundsweresuccessfullyperformed.Theproposedmethodwasalsoappliedtotheanalysisofsomerealsampleswithsatisfactoryresults.