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  • 简介:RamanpeaksofvarioushydratesintheH2O-NaCl-CaCl2systemhavebeenpreviouslyidentified,butaquantitativerelationshipbetweentheRamanpeaksandXNaCl(i.e.,NaCl/(NaCl+CaCl2))hasnotbeenestablished,mainlyduetothedifficultytofreezethesolutions.Thisproblemwassolvedbyaddingaluminapowdertothesolutionstofacilitatenucleationofcrystals.Cryogenic(-185oC)Ramanspectroscopicstudiesofalumina-spicedsolutionsindicatethatXNaClislinearlycorrelatedwiththetotalpeakareafractionofhydrohalite.Capsulesofsolutionsmadefromsilicacapillarywerepreparedtosimulatefluidinclusions.Mostoftheseartificialfluidinclusionscouldnotbetotallyfrozenevenattemperaturesaslowas-185oC,andthetotalpeakareafractionofhydrohaliteisnotcorrelatedlinearlywithXNaCl.However,thedegreeofdeviation(?XNaCl)fromthelinearcorrelationestablishedearlierisrelatedtotheamountofresidualsolution,whichisreflectedbytheratio(r)ofthebaseline"bump"area,resultingfromtheinterstitialunfrozenbrinenear3435cm-1,andthetotalhydratepeakareabetween3350and3600cm-1.Alinearcorrelationbetween?XNaClandrisestablishedtoestimateXNaClfromcryogenicRamanspectroscopicanalysisforfluidinclusions.

  • 标签: 拉曼光谱仪 氯化钠 氯化钙 低温 系统 流体包裹体
  • 简介:本文首先简述了苏北褶皱构造区的地质概况、地热地质条件,确定该区域系统属于中-低温对流型地热系统。基于井温测量、热导率测试数据,综合以往研究成果建立了数学模型,利用Tough2软件分别对洪泽复式背斜、黄滕沟背斜及圩中背斜3条剖面进行了地温场模拟,并分析了其影响因素。结果表明:深部热储的预测温度在73℃-120℃,往深部钻进有望获得温度更高的地热水。较薄的地壳厚度和较浅的居里等温面埋深构成了研究区地温偏高的深部地质背景,构造断裂带及其交汇带的热水深部循环也是造成该中-低温对流型地热系统局部热异常的主控因素之一。

  • 标签: 地温场 地热资源 地热田 温度模拟 地温梯度 影响因素