简介:Ananomalousisotopeeffectexistsinmanyheavyelementisotopesystems(e.g.,Sr,Gd,Zn,U).Thiseffectusedtobecalledthe‘‘odd–evenisotopeeffect’’becausetheoddmassnumberisotopesbehavedifferentlyfromtheevenmassnumberisotopes.Thismass-independentisotopefractionationdrivingforce,whichoriginatesfromthedifferenceintheground-stateelectronicenergiescausedbydifferencesinnuclearsizeandshape,iscurrentlydenotedasthenuclearfieldshifteffect(NFSE).ItisfoundthattheNFSEcandriveisotopefractionationofsomeheavyelements(e.g.,Hg,Tl,U)toanastonishingdegree,farmorethanthemagnitudecausedbytheconventionalmass-dependenteffect(MDE).Forlightelements,theMDEisthedominantfactorinisotopefractionation,whiletheNFSEisneglectable.Furthermore,theMDEandtheNFSEbothdecreaseastemperaturesincrease,thoughatdifferentrates.TheMDEdecreasesrapidlywithafactorof1/T2,whiletheNFSEdecreasesslowlywithafactorof1/T.Asaresult,evenathightemperatures,theNFSEisstillsignificantformanyheavyelementisotopesystems.Inthisreviewpaper,webeginwithanintroductionofthebasicconceptoftheNSFE,includingitshistoryandrecentprogress,andfollowwiththepotentialimplicationsoftheinclusionoftheNFSEintothekineticisotopefractionationeffect(KIE)andheavyisotopegeochronology.
简介:Recently,alarge-scaleOrdovicianoilandgaspoolhasbeendiscoveredinXinken,northoftheTarimBasin,andithasstronglyheterogeneousreservoirsandcomplicatedfluiddistribution.Throughanalyzingoil,gasandwatersamplescollectedfromthisarea,incombinationoffieldproductionandtestingdata,thisstudyrevealsthattheXinkenoilpoolcontainsdominantlynormaloilcharacterizedbylowviscosity,lowsulphur,andhighwax.Ithasalowcontentofnaturalgas,whichpresentstypicalcharacteristicsofwetgasandisoil-associatedgas.Oil-gascorrelationshowsthattheoilwasfromtheMiddle-UpperOrdoviciansourcerocksandthechargeandaccumulationofoilandgastookplaceintheLateHercynianPeriod.Controlledbypaleogeomorphology,sedimentaryfacies,ancientkarstification,faults,andotherfactorsintheCaledonianPeriod,theOrdoviciancarbonatereservoirsaredominatedbydissolvedpores,cavitiesandfractures.Thereservoirbodyoffracturesandcavitiesisdistributedintheshapeofstripandlaminatealongfaultsandexcellentreservoirsaremostlyintherangeof70–100mbelowthetopoftheYijianfangFormation.Asawhole,theXinkenoilpoolisafracture-cavitypoolcontrolledbyinterbeddedkarstreservoirsandisacomplexcomposedofstackedkarstfracturesandcavitiesofvarioussizes.Itcontainsoilinlargeareashorizontally,whichisquasi-laminatedindistribution,andtheaccumulationofoilandgasiscontrolledbythedistributionanddevelopmentdegreeoftheOrdoviciancarbonatereservoirs.Thestudyshowsthatthisareahasabundantresourcesandagreatexplorationpotentialforoilandgas.
简介:Sn-polymetallicoresatDachang,GuangxiAutonomousRegion,China,arehostedinMiddle-UpperDevonianreeflimestones,siliceousrocks,bandedandlenticularlimestones,etc.Twotypesoforebodiescanbedistinguishedaccordingtotheirtelationstothebedding:oneisdistributedalongthebeddingandthe.othercutsacrossthebedding.SnandsulfideorebodiesassociatedwithK-feldsparearemostlycharacterizedbylaminatedorestructure.MicroscopicexaminationsofK-feldspar-bearingrocks,inconjunctionwithX-raydiffraction,chemicalcomposiionandcathodoluminescencedataforK-feldspars,aswellastheirtelationstomineralization,theauthorsconsiderthattheK-feldspareareofauthigenicorigin,subordinatetotheepigeneticstageofdiagenesis,Theyresultedfromthereactionofmixed,deep-seated,circulatingundergroundhotwatersrichinK,AlandSiwithargillaceouscarbonatesduringtheIndonesianorogenicmovement.ItissuggestedmoreattentionshouldbepaidtotheeffectofauthigenicK-feldsparsonSnmineralization.Inthemeantimetheeventrelatedtocirculatingundergroundhotwatersshouldalsobetakenintoaccountsoastoprovidenewcluestoblindoreprospecting.
简介:Fromthepetrologicalstudyofore-hostingfockswhichcontainlargeanorthitscrystalsandtheoccurrenceandchemicalcompositionofanorthitesandrelatedminerals,theauthorsconsiderthatthelargeanorthitecrystalsareofauthigenicorigin.Thedistributioncharacteristicsofanorthites,i.e.,theyaredistributedalongthebeddingandstructurallyweakzonesbutnotrestrictedtosynsedimentaryslumpstructures,andtherelationshipforsomeelementsbetweenanorthitesandothermineralsindicatethatanorthiteshaveresultedfromreactionofcirculatingalkalinesolutionsrichinAlandSiwithcarbonatedduringtheIndosinianorogeny.TheresultsofthisworksuggestthattheassociationofauthigenicanorthiteswithbeddedorebodiesintheDachangorefieldmaybetheevidencethatthemineralizationisrelatedtocirculatingundergroundhotwaters.
简介:TheBaobangoldfield,locatedintheareaofHainanIsland,SouthChina,bearsthreegoldde-posits:Tuwaishan,Baoban,andErjia,whichbelongtothewall-rockalterationtype.Intermsofthepetrographydata,fouralterationzonescanberecognizedfromtheore-veinoutwards(1)thesilicificationzone;(2)thesericitizationzone;(3)thechloritizationzone;and(4)thecalcitizationzone.Thegeochemicalkineticsimulationwascarriedoutonsericitizationandchloritization.Resultsofthestudyshowedthattheformationofthealterationzonesisconnectedwiththepropertiesofhydrothermalfluids:theinitialconcentrationofAl(OH)3,thediffusioncoefficientandthevelocityoffluidflow.Thealterationzonesinthisfieldaretheresultofmultipleinteractionbetweenhydrothermalfluidsandwallrocks.
简介:WithwellsPuguang2and6inthePuguanggasfieldastheresearchobjectsbychoosingorganiccarbonascharacterizationreservoircarbon(indirectlyreflectingthebitumencontents),thispaperdiscussestherelationshipbetweenbitumencontentsandlithologiccharacteristics,reservoircharacteristics,andcalculatesthevolumeofpaleo-oilandoilcrackedgas.Thestudyshowsthattheorganiccarboncontentsofthereservoirsarerelatedtolithologiccharacteristics.Duetovariationsintheparticlesizeorstructureofrocks,theporosityofthereservoirsvaries,furthermore,itwillinfluencethecontentsoforganiccarbon.Andtherelationshipbetweenthesetwoparametersispositive.Basedontheanalysis,therelationshipbetweentotalorganiccarbon(TOC)andthecontentsofreservoirbitumenalsoappearstobepositive.Thevolumeofpaleo-oilandcrackedgasoftheChangxing-Feixian’guanFormationarerespectively495milliontonsand360.4billionm3throughthecalculationofreservoir’sorganiccarbon.Therefore,therelationshipbetweencarbon-bearingrateandcharacteristicsofthereservoirscanbeusedtoindirectlyevaluatereservoirtypes.Besides,thecarbon-bearingrateofthereservoirsalsoreflectsthecontentsofreservoirbitumen,paleo-oilaswellasnaturalgas.Itmakesanewapproachforthestudyofthetypesofreservoirsandtheamountsofpaleo-oilandoilcrackedgasinnortheasternSichuanBasin.
简介:中央煤气的地是在中国的Ordos盆的一块著名的大尺寸的煤气的地。然而,在这气体的奥陶纪水库的主要煤气的来源的鉴定回答遗体思索。根据天然气上的很多geo化学的数据和地质的研究,从奥陶纪的天然气的特征和来源在Ordos盆在中央煤气的领域里捱过外壳水库被学习。结果显示从在中央气体的捱过的外壳水库在Ordos盆回答的奥陶纪的天然气有类似的化学药品和同位素组成到高度成熟、在成熟上的干燥气体。导出煤的气体和油类型气体在Ordos盆在中央煤气的领域里共存。前者从更低的古生代的海洋的碳酸盐主要从含碳二叠的煤措施和后者被导出。当油类型气体可以在Ordos盆主要在中央煤气的领域的北、西方、南部的部分被生产时,导出煤的气体发生在中央煤气的领域的东方部分,这被建议。
简介:基于确定的数学模型和图形的解释,一个新方法,被用来在一由紫外线光谱技术生产混合很好计算单个地区的生产的贡献,被建立了。标准板用作为X轴作为Y轴和波长人工地提出的样品油的消光系数E被拉。从样品油的紫外分析导致混合的井的曲线被插入到标准板并且比较。在生产混合很好的每个单个地区的比例与接近人工地提出的样品油的曲线的曲线的比例是相同的。在井QHD32-6-3地里,例如并且用这个方法拿A22很好,一个单个地区的生产贡献被计算。Theresult证明Nm4地区是一个主要“贡献者”,Nm4地区的比例是70%,并且Nm1地区的是30%。紫外线光谱技术提供了监视生产贡献的一种新reservoirgeochemical技术,特别为简历降级的重油,而是它有某限制,就取决于GC指纹技术。
简介:在云南省的巨大的HuizeZn-Pb矿石地,西南的中国,包括Qilinchang和Kuangshanchang存款。存款在等级在规模(Zn和Pb的超过5山)和高度大(全部的Zn和Pb的平均等级是30%)。在这报导纸是Rb-Sr的结果从这块矿石地的闪锌矿的同位素的标明日期。二精确年龄(223.5±3.9妈和226±6.4妈)从二isochrons被获得了。这二年龄在这个区域接近与Emeishan洪水暗岩有关的本国的铜矿化作用的报导年龄,它是到228妈的226妈。以前的研究证明大小高举从Emeishan洪水暗岩结果比1000m大,显示Kuangshanchang和Qilinchang扔在一样的地质的事件期间被形成并且在高举期间由液体移植发源从Emeishan洪水暗岩结果。
简介:在这糊REE集中和Sr和从Furong矿石的Bailashui锡矿床的荧石的Nd同位素组成回答的在场的作者,南部的湖南省。结果证明在荧石的REE的全部的数量通常是低的,从有在学习区域的Qitianling花岗石的类似于那些的使球粒状陨石正常化的REE分发模式的0.705~8.785μg/g,与显著否定Eu异例由LREE丰富模式描绘了。荧石在范围以内在Sr同位素组成变化0.70830.7091,价值比在这个区域的主人碳酸盐岩石的那些是比花岗石并且高的那些低的。ɛ荧石的Nd(t)价值在−9.4和+10.3之间变化,两个都揭示那外壳--并且披风来源材料涉及形成矿石的热水的液体。在这张矿床上与以前的研究结合了,Bailashui锡矿床是速度集合并且仔细空间地在这个区域与花岗石的岩浆酌联系。热水的荧石是在热水的液体和海洋的碳酸盐摇的花岗石的magmatic之间的液体/岩石相互作用的产品。而在形成矿石的液体的Sr主要来自热水的液体和海洋的碳酸盐摇的花岗石的magmatic,在形成矿石的液体的REE和F从花岗石被导出,尽管在Sr同位素组成的变化不能被这二结束成员的简单混合物解释。证据证明形成矿石的液体具有外壳披风的混合起源,但是液体可能是,这不完全地一致,这可以被不同来源的液体的不同类的混合引起。
简介:TheDachangtin-polymetallicdistrict,Guangxi,China,isoneofthelargesttinorefieldsintheworld.Bothcassiterite-sulfideandZn-CuskarnmineralizationarehostedintheMid-UpperDevoniancarbonate-richsedi-mentsadjacenttotheunderlyingCretaceousLongxianggaigranite(91-97Ma).TheLamoZn-CudepositisatypicalskarndepositinthedistrictandoccursatthecontactzonebetweentheUpperDevonianlimestoneandthegranite.Theoremineralsmainlyconsistofsphalerite,arsenopyrite,pyrrhotite,galena,chalcopyrite,andminormolybdenite.However,theageofmineralizationandsourceofthemetalsarenotwellconstrained.Inthisstudy,weusethemolybdeniteRe-Osdatingmethodandin-situPbisotopesofsulfidesfromtheLamodepositforthefirsttimeinordertodirectlydeterminetheageofmineralizationandthetracingsourceofmetals.SixmolybdenitesamplesyieldedamoreaccurateRe-Osisochronageof90.04-1.1Ma(MSWD--0.72),whichismuchyoungerthanthereportedgarnetSm-Ndisochronageof95±11MaandquartzfluidinclusionsRb-Srisochronageof99±6Ma.ThisageisalsointerpretedastheageofZn-Cuskarnminer-alizationintheDachangdistrict.Further,inthisstudywefoundthatin-situPbisotopesofsulfidesfromtheLamodepositandfeldsparsinthedistrict'sbiotitegraniteandgraniticporphyrydikeshaveanarrowrangeandanoverlapofPbisotopiccompositions(206pb/204pb18.417-18.594,207pb/204pb=15.641-15.746,and208pb/204pb=38.791-39.073),suggestingthatthemetalsweremainlysourcedfromCretaceousgraniticmagma.