简介:ThestrongadaptabilityofBroussonetiapapyrifera(L.)Vent.tolowphosphorus(P)conditionscanbeattributedtothelargeamountofroot-exudedorganicacidsandthehighef?ciencyofPextraction.However,microelementcontentsarein?uencedbylow-Pstress,andtheireffectsonthephotosyntheticcapabilityofB.papyriferaremainunknown.Inthisstudy,weinvestigatedtheeffectsoflow-Ptreatmentonnetphotosyntheticrate(P_N);chlorophylla?uorescence(ChlF)characteristics;andFe,Mn,Cu,andZncontentsofB.papyriferaandMorusalbaL.seedlings.ResultsshowthatB.papyriferaexhibitedbetterphotosyntheticcapabilityundermoderatePde?-ciency(0.125,0.063,and0.031mmol/LPtreatments),whereasthephotosyntheticcapabilityofM.albadecreasedundermoderateandseverePde?ciency(0.016and0mmol/LPtreatments).UndermoderatePde?ciency,thedecreaseinCuandZncontentsinB.papyriferawaslowerthanthatinM.alba.UnderseverePde?ciency,aconsiderabledecreaseofphotosyntheticcapabilityinB.papyriferaandM.albawasassociatedwithlowCuandZncontents.ThePNofthetwoMoraceaespeciesexhibitedabettercorrelationwithCuandZncontentsthanwithFeorMncontent.Pde?ciencycouldnotonlydecreasecyclicphotophorylationandphotosyntheticef?ciency,butcouldalsoaffectthestabilityofthylakoidmembranestructureandelectrontransportef?ciencybyin?uencingthecontentsofCuorZn,therebyaffectingphotosynthesis.
简介:Metalgrainsinstonymeteoritesarerelativelymovableduringthermalnetamorphism(Wood,1967;XieandWang,1979;Xie,1986).InviewofthefactthattheJilinmeteoriteisthelargestintheworldknownuptonow,itsmainbodyweighing1770kganditstotalvolumeamountingto117×93×84cm^3,ade-tailedinvestigationintosuchahugemeteoritebodywouldundoubtedlyprovideuswithalotofcluesandinformationvaluableinthestudyofthebehaviorofFe-Nimetalduringthermalmetamorphismofmeteorites.OurrecentinvestigationhasrevealedthatduringthermalmetamorphismoftheJilinchondirtefineFe-Nimetalparticlesmigratedeasilybydiffusioninsolidstate,andsubsequentlyaggregatedintometalnodulesabout5-10mminlength,andthelargestnodulewefoundis30mminsize(Photo1).Inthispaperwepresentsomenewresultsofourstudyconcerningthemigra-tionandconcentrationofFe-NimetalintheJilinchondriteonthebasisofop-tical,SEMobservationsandhigh-temperature-highpressureaswellasshockloadingexperiments.
简介:这篇论文在Guiyang的地表的土壤描述象Cu和Zn那样的重金属污染物质的环境联盟者geochemical特征,GuizhouProvince的首都的城市。在土壤和geochemical标准的重金属的基线集中被建立了在环境上区分自然或人工的影响。用统计上分析方法,我们在Guiyang(18.8mg/kg)建立了Cu的基线,土壤(超过68.4mg/kg)可以承受Cu污染。Zn的数据是46。3mg/kg并且112。0mg/kg。Geoaccumulation指数分析显示有sufferednon污染到的地表的土壤为38%,38%,和22%的Cu帐户为中间污染中间污染,并且仅仅对严重污染中间污染的2%between。承受了Zn的非污染tomid污染的地表的土壤占41%,50%,和7%为中间污染,并且仅仅2%betweenmid污染到严重污染。Cu污染的最大的度在Guiyang的surficials油是5.09。没为53承受Cu污染报道的地表的土壤。2%。Cu的全部的污染度是稍微超过零。Guiyang的地表的土壤因此承受了slightCu污染。Zn污染度的最大的价值是2。85在地表的土壤ofGuiyang。77。8%地表的土壤还没承受了任何Zn污染。Zn的全部的污染度是不到零。在Guiyang的地表的土壤因此从Zn的污染是免费的。
简介:Understandingtheeffectsoforganicacids(OA)onthetransformationofFeandMntosurfacewaterfromtheweatheringcoalgangueisofgreatbene?ttoriskassessmentandremediationstrategiesforcontaminatedwaterandsoil.BasedontheinvestigationonsurfacewaterinthecentralcoaldistrictsoftheGuizhouProvince,18watersampleswerecollectedforheavymetalanalysis.TheresultsindicatedthatthepHvalueofsurfacewaterislow(3.11–4.92),andFeconcentration(1.31–5.55mgL-1)andMnconcentration(1.90–5.71mgL-1)were,onaverage,10.86and34.33timesthelimitofSurfaceWaterQualityStandards,respectively.InordertoevaluatetheeffectsoftheOAonthedissolutionofFeandMnfromtheweatheringcoalgangue,columnelutionandbatchleachingexperimentswereconducted.Theresultsshowthatthelowmolecularweightoforganicacids(LMWOAs,i.e.,oxalic,tartaric,malicandcitricacids)andfulvicacidssigni?-cantlyacceleratedthedissolutionofFeandMn;inaddition,whentheconcentrationofOAreached25mmolL-1,theconcentrationsofFe,andMnwere1.14–67.08and1.11–2.32timesashighasthosein0.5mmolL-1OA,respectively.Furthermore,themigrationofFeandMnwassigni?cantlyin?uencedbythepHandEh,especiallyforFe;theionMnwasdissolvedfromtheganguemoreeasilythantheionFeinthecolumnleaching,whichwascontrarytotheresultsofbatchleaching.
简介:岩浆Cu-Ni-PGE硫化物矿床形成的重要过程是硫化物熔体的熔离,而关键在于成矿岩浆中硫的过饱和。判断岩浆Cu-Ni-PGE硫化物矿床中硫来源最直接有效的方法就是研究其硫同位素特征。当矿床的硫同位素值超出了地幔硫同位素的组成范围,揭示了壳源硫的混入。如果矿床硫同位素值δ^34S落入地幔值的范围内,则需要结合围岩硫同位素组成、并考虑岩浆房中是否发生了硫同位素交换反应来进一步判断是否有围岩硫的加入。异常的Δ^33S值主要出现在太古宙沉积硫化物中,利用δ^34S与Δ^33S相结合可识别样品中是否存在太古宙岩石中来源的硫;然而,一些太古宙岩石中硫化物Δ^33S值也可以在0‰附近;在一些后太古宙岩石的硫化物中也发现了异常的Δ^33S值;因此在根据Δ33S值来判断S是否来源于太古宙岩石时应谨慎。仔细测定围岩和潜在的混染源的硫同位素组成对于准确评价岩浆Cu-Ni-PGE硫化物矿床中S的来源是非常关键的。硫同位素和其他同位素如镍同位素、铜同位素、铁同位素相结合也许对于认识岩浆Cu-Ni-PGE硫化物矿床中成矿物质来源及成矿岩浆演化过程能够提供新的思路。
简介:Icecoreδ18OrecordefromtheNo.aglacierattheheadoftheUrumqiRiverwereusedocharacterizetherelationshipbetweenδ18Oandcontemporaneoussurfaceairtemperature(Ta)nearbytheDaxigouMeteorologicalStation(3539mabovesealevel,-2kmawayfromtheicecoredrillingsite),Althoughtheicecorerecordsofannuallyaveragedδ18Oarepositivelycorrelatedwithconemporaneoussurfaceairtemperature,especiallysummerairtemperature,thecorrelationislesssignificantthanthatfortheprecipitationsamplesduetodepositionalandpost-depositionalmodificationprocesses,However,theClimatologicalsignificanceoftheicecorδ18Orecordscanbestillpreservedtoacertaindegree,whichmoghtextendtheapplicationofhighaltitudeandsub-tropicalicecoreδ18Orecordstopaleoclimatereconstruction.
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简介:TheDachangtin-polymetallicdistrict,Guangxi,China,isoneofthelargesttinorefieldsintheworld.Bothcassiterite-sulfideandZn-CuskarnmineralizationarehostedintheMid-UpperDevoniancarbonate-richsedi-mentsadjacenttotheunderlyingCretaceousLongxianggaigranite(91-97Ma).TheLamoZn-CudepositisatypicalskarndepositinthedistrictandoccursatthecontactzonebetweentheUpperDevonianlimestoneandthegranite.Theoremineralsmainlyconsistofsphalerite,arsenopyrite,pyrrhotite,galena,chalcopyrite,andminormolybdenite.However,theageofmineralizationandsourceofthemetalsarenotwellconstrained.Inthisstudy,weusethemolybdeniteRe-Osdatingmethodandin-situPbisotopesofsulfidesfromtheLamodepositforthefirsttimeinordertodirectlydeterminetheageofmineralizationandthetracingsourceofmetals.SixmolybdenitesamplesyieldedamoreaccurateRe-Osisochronageof90.04-1.1Ma(MSWD--0.72),whichismuchyoungerthanthereportedgarnetSm-Ndisochronageof95±11MaandquartzfluidinclusionsRb-Srisochronageof99±6Ma.ThisageisalsointerpretedastheageofZn-Cuskarnminer-alizationintheDachangdistrict.Further,inthisstudywefoundthatin-situPbisotopesofsulfidesfromtheLamodepositandfeldsparsinthedistrict'sbiotitegraniteandgraniticporphyrydikeshaveanarrowrangeandanoverlapofPbisotopiccompositions(206pb/204pb18.417-18.594,207pb/204pb=15.641-15.746,and208pb/204pb=38.791-39.073),suggestingthatthemetalsweremainlysourcedfromCretaceousgraniticmagma.