简介:LowcarbonsteelswithBandPadditionswereremeltedbyelectromagneticlevitationandsolidifiedinavacuumdroptube.Thedropletvolumesweresettobe2mm×2mm×2mm(TM)and5mm×5mm×5mm(FM),respectively.Themicrostructureofrapidlysolidifiedsteeldroplets(cooledinsiliconoil)withPandbothBandPadditionwasobserved.ThemicrostructuresofB-bearingdropletsamplesweremoreuniformthanthoseofB-freeones,forbothTMandFMsamples.Thedistributionof℃andPalongthediameterofeachsamplewasdetected.Thewell-distributionof℃andPwasdetectedinB-bearingdropletsamples.SoitcouldbededucedthatBwasalsowelldistributedinthesteels.ItwasBatomsthatpromotedthewell-distributionof℃andP,whichfurtherimprovedtheuniformityofmicrostructureundertheconditionofrapidsolidification.Themicro-hardnessofBbearingsampleswashigherthanthatofB-freesamples,andthehardeningmechanismwasdiscussedindetail.
简介:PositronannihilationbehaviorshavebeenstudiedinthesinglephaseNd2Fe14BmagnetandthenanocompositeNd2Fe14B/α-Femagnet,preparedbymeltspinning.Theresultsshowedthatthenumberofvacancy-clusteratgrainboundariesincreaseswithincreasingannealingtemperatureforthebothtypesofmagnets.Theincreaseofthiskindofdefectcanimprovethecoercivityof
简介:使用Stober法水热反应制备球状SiO2@ZnO核壳结构,通过样品对罗丹明B水溶液的降解研究其光催化活性,使用X-射线衍射(XRD)、扫描电子显微镜(SEM)、X-射线能量色散谱(EDS)、光致发光谱(PL)及紫外-可见分光光度计(UV—vis)等测试手段对材料物性进行表征,结果表明,SiO2表面包覆的ZnO层结晶良好,且不与SiO2核发生反应,表面致密、厚度均匀,保持了SiO2微球体的形貌特征;球状SiO2@ZnO核壳结构的吸收边和紫外发光峰位置相比于ZnO均发生红移,禁带宽度减小;通过光催化实验分析可知,球状SiO2@ZnO核壳结构光催化剂对罗丹明B水溶液的降解率有所提高,光照3h其降解率高达11%。
简介:MoleculardynamicssimulationusingauniversalforcefieldhasbeenemployedtodeterminethediffusioncoefficientsofO2andNa2SO4vaporintoB2O3andSiCfrom700Kto1273K,respectively.Einsteindiffusionwasobservedina250~300pssimulation.ThediffusioncoefficientfortheO2rangefromabout9.279×10-9cm2/sforB2O3to2.275×10-10cm2/sforSiCataloadingof32moleculespersimulationbox,thatfortheNa2SO4vaporrangefromabout9.888×10-7cm2/sforB2O3to1.837×10-10cm2/sforSiCataloadingof8moleculespersimulationbox.EnvironmentpropertiesofC/SiCcompositewillbeincreasedviatheB2O3preventingthediffusionofO2andNa2SO4vaporintothepyrolyticinterphaseandcarbonfibers.
简介:有alloying原子X=C,B,N,O和空缺的镁和它的合金的概括叠的差错(GSF)精力和表面精力用第一原则的方法被调查了。叠的差错精力上的alloying原子和空缺的占优势的减少效果在slip飞机附近在第一层从他们的位置被结果,这被发现。叠的差错精力是将近与纯镁一样当alloying原子和空缺被放在时第二,第三,第4,第5和第6层。O强烈减少Mg的GSF精力,这被显示出。alloying原子C,B和N增加表面精力,但是O和空缺减少Mg的表面精力。Mg和Mg合金的韧性被使用在表面精力和不稳定的叠差错精力之间的比率基于瑞斯标准讨论了。
简介:ExperimentswerecarriedouttostudytheinfluenceofsurfaceconditiononexpulsionduringthespotweldingofAZ31BMgalloy.AgeneralelectricalcontactresistancetheoryforconductiveroughsurfacesandtherelationbetweenmaximumtemperatureTminthecontactandvoltage-dropVacrossinterfaceoftwosurfaceswereemployedtounderstandthereasonofexpulsioninMgalloyspotwelding.Themainreasonofexpulsionisthatthehighelectricalcontactresistanceinducedbylargeroughnessofthesurfaceandoxidefilmcoveredonthesurfaceleadstolocalmeltingofmetalintheinterfaceoftwosurfaces,andliquidmetalofthelocalareaejectedfromthespecimenunderelectrodeforceformsexpulsion.