简介:Thepotentialenergycurves(PECs)ofBOmolecule,includingΣ+andΠsymmetrieswithdoubletspinmultiplicities,areobtainedemployingmulti-referenceconfigurationinteraction(MRCI)methodandDunning'scorrelationconsistentbasissets.Theanalyticalpotentialenergyfunctions(APEFs)arefittedusingtheMurrell-Sorbie(MS)functionandtheleastsquaremethod.BasedonthePECs,thespectroscopicconstantsofthestateshavebeendeterminedandcomparedwiththetheoreticalandexperimentalresultsavailabletoaffirmtheaccuracyandliabilityofthecalculations.Theroot-mean-square(RMS)errorsbetweenthefittedresultsandtheabinitiovaluesaretoolittleincomparisonwiththechemicalaccuracy(349.755cm-1).ItisshownthatthepresentAPEFsareaccurateandcandisplaytheinteractionbetweentheatomswell.ThepresentAPEFscanbeusedtoconstructmorecomplicatedAPEFordosomedynamicinvestigations.
简介:Atemperaturesensorbasedonpolarizationnon-reciprocity(PNR)infiber-opticSagnacinterferometer(FSI)wasproposed.Theexperimentalstudywasmadeprimarilyandtheresultsagreewiththeorywell.Discussionshowsthatthiskindoftemperaturesensorcanachievehighprecisionandhavegreatapplicationpotential.
简介:Thetime-of-flightmassspectrum(TOFMS)relativetotheresonanttwo-photonionizationofgasphasep-dichlorobenzenewasobtainedinthewavelengthrangeof240-250nmbyahome-madesystem.Aspecialdesignwasmadetoreducetheeffectofmemoryontheinnerwallofthesampleinletsystemsuitablefortheinvestigationofsemi-volatileorganiccompound.Inthiswavelengthrange,p-dichlorobenzenemoleculesfirstlyabsorbedonephotontobeexcitedfromthegToundstate~1A_g(S_0)tothefirstexcitedstate1B2u($1),thenabsorbedanotherphotontobeionized.Therelationshipbetweenthesignalintensityofp-dichlorobenzenemolecularionC_6H_4~(35)Cl_2~+at248-nmwavelengthandthelaserpowerwasgiven.The1.52powerindexofC_6H_4~(35)Cl_2~+wasatypicalidentificationofthe3/2powerlaw.TherelationshipbetweentheionsignalintensityofC_6H_4~(35)Cl_2~+andthesampleconcentrationwasclosetoalinearoneintheppm(V/V)range,whichledtoadetectionlimitof125ppb(V/V)forp-dichlorobenzene.
简介:Theeffectofλ/2SiO2overcoatonthelaserdamagecharacteristicsofHfO2/SiO2high-reflector(HR)coatingsisinvestigatedwith1-on-1andN-on-1laserdamagetestmethods.Thelaserdamagesurfaceof1-on-1isanalyzedbyastepanalyzer.ThesurfacemorphologiesshowthatlaserdamagemakesthecoatingdamagedareaprotrudentandroughforHRcoatingwithoutλ/2silicaovercoat,butconcaveandsmoothforHRcoatingwithλ/2silicaovercoat.Theresultof10-on-1multi-pulseirradiationonthesamepointofthecoatingshowsthatthereisanenergydensitystageonthedamagecurve.Ifthelaserenergydensityiswithintherangeofthestage,HfO2/SiO2HRcoatingswithλ/2silicaovercoatwillnotbedamagedmorethan2timesformulti-shots,andthesurfacedamagesareveryslightsothatthereisnoimpactonthecoatingperformance.Anotherinterestingresultisthattheenergydensitystageextendsfromthedamagethresholdtothepointofabout3timesofthreshold,whichissimilartotheeffectofthelaserconditiononcoating.
简介:Thenonlinearswitchingcharacteristicsoffusedfiberdirectionalcouplerswerestudiedexperimentally.Byusingfemtosecondlaserpulseswithpulsewidthof100fsandwavelengthofabout1550nmfromasystemofTi:sapphirelaserandopticalparametricamplifier(OPA),thenonlinearswitchingpropertiesofanullcoupleranda100%couplerweremeasured.Theexperimentalresultswerecoincidentwiththesimulationsbasedonnonlinearpropagationequationsinfiberbyusingsuper-modetheory.Nonlinearlossinfiberwasalsomeasuredtogettheinjectedpoweratthecoupler.Afterdeductingthenonlinearlossandinputefficiency,thenonlinearswitchingcriticalpeakpowersfora100%andanullfusedcouplerswerecalculatedtobe9410and9440W,respectively.ThenonlinearlossparameterPNinanexpressionofαNL=αP/PNwasobtainedtobePN=0.23W.
简介:报道了一种基于空气孔型光子晶体自准直环形谐振腔1×4光分束器。其结构由4个改变空气孔半径的分光镜组成。首先运用多光束干涉原理分析光分束器各个端口的透射谱,通过分光镜的合适组合,自准直光就可以按照设定的比例从各出口出射。再利用编写的二维时域有限差分程序进行数值模拟计算,其结果和理论值很好地吻合。该结构具有尺寸小、自由光谱范围大、硅基等优点,有望应用于未来的高密度集成光路中。
简介:通过分析F-P扫描干涉仪的工作原理,基于STC89C52RC单片机,采用PA93功率放大器驱动压电陶瓷,设计了1064nm平平腔结构的F-P扫描干涉仪。腔镜反射率为98%,精细度156,腔长0.1~100mm连续可调,对应自由光谱区1.5~1500GHz和分辨率9.65~9650MHz。压电陶瓷驱动电压和频率通过4×4矩阵键盘,可以在0~200V和1~30Hz连续可调,显示在1602液晶屏上。同时可以通过RS232串口与计算机通讯,在上位机使用LabVIEW软件界面方便地设置压电陶瓷驱动电压和频率。最后使用该F-P扫描干涉仪,对激光二极管泵浦Nd:YVO4激光器纵模进行了测量,验证了整个系统的工作性能。
简介:Byusingagraded-indexmultimodefiber(GI-MMF)witharelativelyflatindexprofileandhighrefractiveindexofthefibercore,amicroextrinsicfiber-opticFabryProtinterferometric(MEFPI)strainsensorisfabricatedthroughchemicaletchingandfusionsplicing.Higherreflectanceofthemicrocavityisobtainedduetotheless-curvedinnerwallinthecenterofthefibercoreafteretchingandhigherindexcontrastbetweentheGI-MMFcoreandair.Themaximumreflectionofthesensorisenhanced12dBthanthatobtainedbyetchingoftheEr-orB-dopedfibers.Highfringecontrastof22dBisobtained.ThestrainandtemperatureresponsesoftheMEFPIsensorsareinvestigatedinthisexperiment.Goodlinearityandhighsensitivityareachieved,withwavelength-strainandwavelength-temperaturesensitivitiesof7.82pm/μεand5.01pm/°C,respectively.
简介:Usingamicrowavegenerator,chlorinedilutedbyheliumwasdissociatedtochlorineatomsthatsubse-quentlyreactedwithhydrogenazidetoproducetheexcitedstatesofNCl(a1△).Meanwhile,moleculariodinewithcarriergasofheliumreactedwithatomicchlorinetoproduceatomiciodinewhichthenwaspumpedtoexcitedstateofI(2P1/2)byanenergytransferreactionfromNCl(a1△).Inthispaper,thechangesofNCl(a1△)andNCl(bi∑)emissionintensityispresentedwhenI2/HeisintroducedintothestreamofCl/Cl2/He/HN3/NCl(a1△)/NCl(b1∑).ThedependencesofatomiciodineI(2P1/2)onflowratesofgaseswerealsoinvestigated.TheoptimumparametersforI(2P1/2)productionaregiven.
简介:Ablationdynamicsoftungstenirradiatedwitha70fslaserpulseisinvestigatedwithX-rayinterferometryandX-rayimagingusinga13.9nmsoftX-raylaserof7pspulseduration.Theevolutionofhigh-densityablationfrontoftungsten(i.e.,W)ispresented.Theablationfrontexpandsto~120nmabovetheoriginaltargetsurfaceat160psafterfemtosecond-laserirradiationwithanexpansionspeedofapproximately750m∕s.TheseresultswillprovideimportantdataforunderstandingablationpropertiesofW,whichisacandidatematerialofthefirstwallofmagneticconfinementfusionreactors.