简介:Thepotentialenergycurves(PECs)ofBOmolecule,includingΣ+andΠsymmetrieswithdoubletspinmultiplicities,areobtainedemployingmulti-referenceconfigurationinteraction(MRCI)methodandDunning'scorrelationconsistentbasissets.Theanalyticalpotentialenergyfunctions(APEFs)arefittedusingtheMurrell-Sorbie(MS)functionandtheleastsquaremethod.BasedonthePECs,thespectroscopicconstantsofthestateshavebeendeterminedandcomparedwiththetheoreticalandexperimentalresultsavailabletoaffirmtheaccuracyandliabilityofthecalculations.Theroot-mean-square(RMS)errorsbetweenthefittedresultsandtheabinitiovaluesaretoolittleincomparisonwiththechemicalaccuracy(349.755cm-1).ItisshownthatthepresentAPEFsareaccurateandcandisplaytheinteractionbetweentheatomswell.ThepresentAPEFscanbeusedtoconstructmorecomplicatedAPEFordosomedynamicinvestigations.
简介:Atemperaturesensorbasedonpolarizationnon-reciprocity(PNR)infiber-opticSagnacinterferometer(FSI)wasproposed.Theexperimentalstudywasmadeprimarilyandtheresultsagreewiththeorywell.Discussionshowsthatthiskindoftemperaturesensorcanachievehighprecisionandhavegreatapplicationpotential.
简介:Thetime-of-flightmassspectrum(TOFMS)relativetotheresonanttwo-photonionizationofgasphasep-dichlorobenzenewasobtainedinthewavelengthrangeof240-250nmbyahome-madesystem.Aspecialdesignwasmadetoreducetheeffectofmemoryontheinnerwallofthesampleinletsystemsuitablefortheinvestigationofsemi-volatileorganiccompound.Inthiswavelengthrange,p-dichlorobenzenemoleculesfirstlyabsorbedonephotontobeexcitedfromthegToundstate~1A_g(S_0)tothefirstexcitedstate1B2u($1),thenabsorbedanotherphotontobeionized.Therelationshipbetweenthesignalintensityofp-dichlorobenzenemolecularionC_6H_4~(35)Cl_2~+at248-nmwavelengthandthelaserpowerwasgiven.The1.52powerindexofC_6H_4~(35)Cl_2~+wasatypicalidentificationofthe3/2powerlaw.TherelationshipbetweentheionsignalintensityofC_6H_4~(35)Cl_2~+andthesampleconcentrationwasclosetoalinearoneintheppm(V/V)range,whichledtoadetectionlimitof125ppb(V/V)forp-dichlorobenzene.
简介:Theeffectofλ/2SiO2overcoatonthelaserdamagecharacteristicsofHfO2/SiO2high-reflector(HR)coatingsisinvestigatedwith1-on-1andN-on-1laserdamagetestmethods.Thelaserdamagesurfaceof1-on-1isanalyzedbyastepanalyzer.ThesurfacemorphologiesshowthatlaserdamagemakesthecoatingdamagedareaprotrudentandroughforHRcoatingwithoutλ/2silicaovercoat,butconcaveandsmoothforHRcoatingwithλ/2silicaovercoat.Theresultof10-on-1multi-pulseirradiationonthesamepointofthecoatingshowsthatthereisanenergydensitystageonthedamagecurve.Ifthelaserenergydensityiswithintherangeofthestage,HfO2/SiO2HRcoatingswithλ/2silicaovercoatwillnotbedamagedmorethan2timesformulti-shots,andthesurfacedamagesareveryslightsothatthereisnoimpactonthecoatingperformance.Anotherinterestingresultisthattheenergydensitystageextendsfromthedamagethresholdtothepointofabout3timesofthreshold,whichissimilartotheeffectofthelaserconditiononcoating.
简介:Thenonlinearswitchingcharacteristicsoffusedfiberdirectionalcouplerswerestudiedexperimentally.Byusingfemtosecondlaserpulseswithpulsewidthof100fsandwavelengthofabout1550nmfromasystemofTi:sapphirelaserandopticalparametricamplifier(OPA),thenonlinearswitchingpropertiesofanullcoupleranda100%couplerweremeasured.Theexperimentalresultswerecoincidentwiththesimulationsbasedonnonlinearpropagationequationsinfiberbyusingsuper-modetheory.Nonlinearlossinfiberwasalsomeasuredtogettheinjectedpoweratthecoupler.Afterdeductingthenonlinearlossandinputefficiency,thenonlinearswitchingcriticalpeakpowersfora100%andanullfusedcouplerswerecalculatedtobe9410and9440W,respectively.ThenonlinearlossparameterPNinanexpressionofαNL=αP/PNwasobtainedtobePN=0.23W.