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  • 简介:ThisworkstudiedthecharacteristicsofSiO2distributionandstructureofsilicatephasesinMgO-ZrO2compositessynthesizedbyrawmaterialsoflightfiredmagnesitendzircon,Theresultsindicatethat30wt%-40wt%SiO2contentinthesystemisexistedintheformofcrystallineofforsterite(M2S),theremainderingofSiOcontent(60wt%0-70wt%)isexistedintheglassphase,Thechemicalcompositionofglassphaseiswellagreedwiththechemicalcompositionofmonticellite(CMS).

  • 标签: 二氧化硅 氧化镁 氧化锆 复合耐火材料 硅酸盐
  • 简介:将竹纤维加入到环氧树脂中以形成增强环氧复合材料,研究了竹纤维竹粉和纳米二氧化硅(SiO2)对环氧树脂力学性能和耐溶剂浸蚀性能影响。竹纤维含量为15%时,竹纤维/环氧树脂冲击强度比纯环氧树脂提高50%。纳米SiO2能同时增强和增韧竹纤维/环氧树脂,并提高其耐溶剂浸蚀性能,纳米SiO2含量为4%时,纳米SiO2/竹纤维/环氧树脂三元复合材料冲击和拉伸强度分别比未添加纳米SiO2竹纤维/环氧树脂提高40%和30%。当纳米SiO2/竹纤维/环氧树脂质量比为4/15/85时,三元复合材料综合性能较好。

  • 标签: 环氧树脂 竹纤维 纳米二氧化硅 增强塑料 复合材料
  • 简介:β-sialon/alumina/silicamixturesweresinteredinflowingnitrogenat1500℃and1600℃respectively.ThesinteringpropertiesandmorphologyofsampleswereinvestigatedbySEM,EDSandXRD.Resultsshowthatsinteredpropertiesofthesamplesareinfluencedbysoakingtemperaturesandcompositions.Bulkdensitiesofsamplesareincreasedwiththeincreaseofthesoakingtemperature,whereastheapparentporositiesaredecreased.Masslossofthesinteredsamplesat1500℃islowerthanthatat1600℃,butallthemasslossremainsapproximatelyconstantwiththeincreaseofsialoncontent.Fromthepointofthermodynamicanalysis,ComplexchemicalreactionstakeplaceinsamplesduringsinteringprocessandthevolatileofSiO(g)isresponsibleforthemasslossofsamples.Comparedtocrosssectionmicrostructureofβ-sialon/Al2O3/SiO2mixturessinteredincokepowderbedconsistingofthedensecenterwithwell-developedcolumnofsialonphase,thetransitionalpartwithneedlelikegrainnitrogen-containingphaseandtheloosepartwithshortgranularAl2O3phase,thoseofmixturessinteredinflowingnitrogenisofwell-developedsialonindensecenterandslightlyloosepartwithsialondebris.

  • 标签: 硅铝氧氮聚合材料 氧化铝 硅石 高温条件 耐火材料
  • 简介:IntheprocessofsynthesisofnanometerSiCprecursorswithsol-gelofSiO2andlignin,theproductsofallsizesrequiredcanbecontrolledbytheconcentrationofreac-tants,pH,temperature,ractionandageingtime,andsoon.Thebestconditionsinthisreserchare:theconcentrationofNa2SiO3andorganicmattersare4.50%and26.4%respectively,pH=3.3,T=65℃,ageingtimeis30min,driedat150℃,thesizeofSiCprecursorsisabout2.0μm。

  • 标签: 木质素 耐火材料 合成 纳米材料 SIC SIO2
  • 简介:LowcementAl2O3-SiO2castableswaspreparedusingsupergradebauxite(w(Al2O3)>85%)asaggregate,brownfusedcorundum,siliconcarbide,Secar71CAcement,α-Al2O3micropowderandmicrosilicaasfinepowders.TheinfluenceofSiC(0,5wt%,10wt%,and15wt%)onresistancetoPbO-richslagwasinvestigatedbystaticcrucibleslagtest(1300℃for5h,inair).TheslagcorrosionmechanismofthecastableswasanalyzedbymeansofSEM,EDSandXRD.TheresultsshowthattheresistanceofAl2O3-SiO2castablestoPbO-richslagisimprovedobviouslybytheadditionofSiC.ThecorrosionmechanismofthePbO-richslagcanbediscribedasthatPbOintheslagreactswithSiO2andCaOinAl2O3-SiO2castables,forminglow-meltingcompounds(suchasPbO·SiO2and2PbO·SiO2).

  • 标签: 二氧化硅 氧化铝 硅含量 氧化铅 碳化 料渣
  • 简介:考察了SiO2纳米粒子改性ACR抗冲改性剂对R-PVC冲击性能、拉伸性能、耐候性、加工性能影响.结果表明,改性后ACR抗冲改性剂是一种综合性能优异抗冲改性剂.

  • 标签: SIO2纳米粒子 ACR抗冲改性剂 改性 性能
  • 简介:InordertoimprovethemechanicalpropertiesofSiO2aerogel-glassfibercomposites,effectsofdifferentsolvents(cyclohexane,n-hexane,ethanol,acetone)anddifferentdispersingmodes(planetaryballmilling,ultrasonicdispersionandmechanicalstirring)anddispersingduration(10-40min)onthedispersionofchoppedalkali-freeglassfiberbundleswerestudiedtodeterminethebestdispersionprocess.Onthisbasis,thematerialswerebatchedaccordingtothemassfractionofSiO2aerogelpowdertochoppedalkalifreeglassfiberbundlesof90:10,andacertainamountofzincoxidelight-screeningagentandphenolicresinbinderwereadded.SiO2aerogelglassfibercompositespecimenswerepreparedbydirectaddingchoppedalkalifreeglassfiberbundlesandpre-dispersedchoppedalkalifreeglassfiberbundles,respectively.Thecoldcrushingstrengthandthethermalconductivityatdifferentsurfacetemperatures(300,400,500and600℃,respectively)ofthespecimensweremeasured.Theresultsshowthat:(1)theoptimumdispersionprocessofchoppedalkali-freeglassfiberbundlesisusingethanolassolventandmechanicalstirringfor30min;(2)pre-dispersionofchoppedalkali-freeglassfiberbundleshaslittleeffectonthethermalconductivityofSiO2aerogel-glassfibercompositesbutcanimprovethecoldcrushingstrength.

  • 标签: silicon aerogel-glass insulating materials alkali-free GLASS
  • 简介:虽然纳米材料在表面技术方面应用报道屡见不鲜,但对于纳米材料在磷化中研究很少。减摩耐磨是磷化一个重要用途,SiO2修饰后沉积出Ni-P纳米SiO2复合镀层有更好硬度和耐磨性。在快速镀镍液中加入纳米SiC获得刷镀层耐磨性和硬度均有较大提高,摩擦系数减小,

  • 标签: 纳米SIO2 磷化处理 低碳钢 常温 基面 纳米材料
  • 简介:Thisworkinvestigatedthethermo-gravimetric(TG)changeandexplosionresistanceofultra-lowcementAl2O3-SiO2castablesaddedwith0,5%,10%,15%and20%of≤74μmrawbauxitepowderscontaining72.8%Al2O3,respectively.Thecastableswerepreparedusingwhitefusedaluminaasaggregate,powdersofwhitefusedalumina,fusedmullite,α-Al2O3ultrafines,3%CAcementand5%microsilicaasthematrixportion.TGchangeofthecastableswasinvestigatedbyathermo-gravimetricanalyzerforlargesizespecimen.Whentherawbauxiteadditionislessthan10%,themass-losingbehaviorofthecastablesissimilartothatwithoutrawbauxite,tendingtoreachaconstantmassaround400℃,beforewhichthemass-lossismildandproducinglittledestructiveinfluence.Withmorethan10%rawbauxiteaddition,however,themass-lossincreasessignificantly,andthetemperaturetoreachaconstantmassincreasesto600℃orhigher,unfavorabletostructuralstabilization.Withtherawbauxiteadditionupto20%,nonegativeinfluenceonexplosionresistanceisfound.

  • 标签: 氧化铝微粉 铝土矿石 超低水泥 二氧化硅 浇注料 热行为
  • 简介:AnO'-Sialon-Al2O3compositerefractorywaspreparedbyinsitureactionofSi3N4-ZrSiO4-Al2O3mixturewithfusedaluminaaggregates.Densification,insitureactionprocedureandmicrostructureofthematerialwereinvestigatedbymeansofX-raydiffraction,opticalandscanningelectronicmicroscopesandEDAX.

  • 标签: O′-硅铝氧氮聚合材料 氧化锆 三氧化二铝 AL2O3 SIO2 ZRO2
  • 简介:本文主要研究添加微量稀土La2O3对Li2O-Al2O3-SiO2微晶玻璃晶相组成,显微结构,抗折强度影响,研究结果表明:添加微量La2O3有利于Li2O-Al2O3-SiO2微晶玻璃中主晶相β-锂辉石发育成完整柱状,板状晶体,提高了微晶玻璃抗折强度。

  • 标签: 稀土La2O3 LI2O-AL2O3-SIO2 微晶玻璃 结构 性能 影响
  • 简介:介绍了化肥厂利用排空二氧化碳气体作为固定层煤气炉气化剂,他能够有效提高半水煤气中一氧化碳含量,为企业创造效益。

  • 标签: 二氧化碳 煤气炉 气化剂 一氧化碳