简介:Inordertofurtherreducethesulfurcontentingasoline,anewdesulfurizationprocesswasproposedbyusingcatalyticoxidationandextractionrealizedinanelectrochemicalfluidizedreactor.Thefluidizedlayerofloadedcatalystparticlesconsistedofleaddioxide(PbO2)supportedonactivatedcarbonparticles(PbO2/C)andtheelectrolytewasaqueousNaOHsolution.ThePbO2/Cparticleanodescouldremarkablyacceleratetheelectrochemicalreactionrateandpromotetheelectrochemicalcatalysisofsulfurcompounds.Thesulfurcompoundswereatfirstoxidizedtosulfonesorsulfoxides,whichwerethenremovedafterextraction.Theexperimentalresultsindicatedthattheoptimaldesulfurizationconditionswereasfollows:Thecellvoltagewas3.2V,theconcentrationofhydroxylionsinelectrolytewas0.12mol/L,andthefeedratewas300mL/min.Undertheseconditionstheconcentrationofsulfuringasolinewasreducedfrom310ppmto70ppm.Basedontheseexperimentalresults,amechanismofindirectelectrochemicallycatalyticoxidationwasproposed.
简介:Thefirstdomesticstyreneextractionunit,a30kt/aunitforextractionofstyrenefrompyrolysisgasoline(pyro-gas),intheconstructionofwhichtheGuangdongNewHua’aoPetrochemicalCompany,arestructuredenterpriseaffiliatedtotheMaomingPetrochemicalCompany,hasinvested160millionRMB,hasbeencontinuouslyandsafelyoperatingfor430dayssinceMay2011.
简介:Recentlytheproject'Developmentofpackagetechnologyforregenerationofstyrenethroughextractivedistillationofpyrolysisgasoline(STED)'undertakenjointlybytheSINOPECResearchInstituteofPetroleumProcessing(RIPP)andotherinstitutionshaspassedtheappraisalheldinBeijing.Theexpertgroupattendingtheappraisal