简介:运用循环伏安法、线性电位扫描法研究木糖醇在碱性溶液(含锑)中的电化学稳定性及锑在木糖醇碱性溶液中的沉积动力学参数;采用计时电流法研究锑在不锈钢阴极上的电化学成核机理。循环伏安测试结果表明,木糖醇在碱性溶液中的稳定性较好,在-1.20V~+0.60V(vsHg/HgO)范围内无氧化还原反应发生,在电位负于-1.70V(vs.Hg/HgO)时木糖醇在锑电极上可能发生分解。在该体系中,锑在阴极上的沉积经历了不可逆电结晶过程。根据线性电势扫描结果,锑沉积的活化能、表观传递系数、交换电流密度等动力学参数分别为46.33kJ/mol、0.64和4.40×10-6A/m2。计时电流法实验结果表明,锑在碱性木糖醇溶液中的成核机理符合扩散控制下的三维连续成核模型,外加电位对晶体生长速率和恒定电位下的饱和晶核密度有显著影响。通过分析恒电位阶跃曲线,求出锑离子在该体系中的扩散系数为1.53×10-6cm2/s。
简介:本文介绍了低温(-50℃)乙烯球罐制造和焊接技术,制定了球罐制造工艺流程和球壳板成形工艺,通过试验确定了焊接预热温度、层间温度和后热温度,并正确选择了焊接材料。制定了乙烯球罐的焊接工艺规范,并成功地完成了低温(-50℃)乙烯球罐的制造和焊接。
简介:采用B50A789材料制备的压气机叶片产生的缺陷,主要是由于原材料内部夹杂、局部偏析、组织粗大,带状偏析和折叠引起的.本研究采用金相和能谱分析方法研究了锻造压气机叶片表面裂纹的形成机理,并对其锻造裂纹的形成过程进行有限元模拟.结果表明结合低倍及高倍形貌特征,可以得出叶片缺陷为锻造加工过程产生的折叠裂纹;通过有限元模拟分析认为锻造叶片表面裂纹是源于锻件在制坯过程中,在连接杆与安装圆盘的转接处形成啃伤台阶,导致终锻结束时在叶身形成折叠裂纹缺陷.同时通过对试验过程中锻造工艺调整,采用分料卡子对过渡区分料或进行打磨来保证转角半径圆滑过渡,可有效避免叶片表面折叠和裂纹缺陷的形成.
简介:Inthiswork,transformationbehaviorsandmechanicalpropertiesofcold-rolledshapememoryalloyTi50Ni49Fe1bysevereplasticdeformation(SPD)wereintensivelyinvestigated.Thephasetransformationbehaviors,phaseanalysis,andmicrostructureswerecharacterizedbydifferentialscanningcalorimetry(DSC),X-raydiffraction(XRD),andtransmissionelectronmicroscopy(TEM),respectively.TensiletestingwasperformedtoanalyzetheeffectofSPDonthemechanicalpropertiesandshapememoryofTi50Ni49Fe1alloy.Whenthethicknessreductionisbeyond30%,themartensitictransformationissuppressed.Aftercold-rolling,thealloyismainlycomposedofB2parentphaseswithsomestress-inducedmartensiticB190phases,andhighdensityofdislocationsaregeneratedandthegrainsareobviouslyrefined.Theyieldstressrbsignificantlyraisesfrom618MPaof0%coldrollingto1,338MPaof50%SPD.Shape-memoryeffectincreasesfrom6.5%withoutcoldrollingto8.5%after30%SPD,ascribedtotheinduceddefectsincoldrolling.ThoseresultsindicatethatTi50Ni49Fe1alloyhasimprovedmechanicalpropertiesandpotentialcommercialapplicationsafterSPD.
简介:ThemicrostructuresandcrystallizationbehaviorofTi–47at%Ni–3at%Feshapememoryalloywireundertheconditionofseverecolddrawingatroomtemperatureanddifferentpost-deformationannealingprocesseswereintensivelyinvestigatedusingtransmissionelectronmicroscope(TEM)anddifferentialscanningcalorimetry(DSC).ItisindicatedthattheamorphousphaseisdominantintheTi50Ni47Fe3wireafterthecolddrawingof78%arealreduction.Thecriticaltemperatureforrecrystalizationisdeterminedatabout300°C.Theaveragegrainsizegrowsfrom7upto125nmwhenannealingtemperaturerisesfrom300to500°C.Post-deformationannealingprocessexertssignificantinfluenceonthecrystallizationtemperaturewhichclimbsupwiththeincreaseofannealingtemperature.