简介：Vanadiumnitridewassynthesizedbyone-stepmethodusingV2O5andcarbonblackasrawmaterialsinnitrogenatmosphere.ThephasesofdifferentreactionproductspreparedindifferentreactiontemperatureswereanalyzedbyX-raydiffraction(XRD),andthedynamicbehavioroftheprocessofsynthesizingvanadiumnitride(VN)byone-stepmethodwasstudiedwithnon-isothermalthermogravimetry.Themechanismfunctionandkineticparametersofreactionprocesswerecalculatedbythermalgravimetricanalyses(TGA),andthereactionrateequationwasestablished.TheXRDresultsshowthatforthesamplestestedwithminimalVNafterholdingfor4hat1273K,themainphaseofproductsisVNat1476K,whilesomevanadiumnitridestransformintovanadiumcarbidesagainover1573K.ItisfoundthatN2isbeneficialtostimulatereductionandproceedcarbonizationreaction,andthereductionandnitridationreactioncanoccursimultaneously.TheactivationenergyofpreparingVNbyone-stepmethodis104.005kJ·mol-1,andthefrequencyfactoris470.52at1280–1358K,and150.052kJ·mol-1and2.359104at1358–1426K,respectively.

简介：Thenon-isothermalleachingkineticsofprimarytitanium-richmaterialbymicrowaveheatingwasinvestigated,andthetemperature-pressurecurvesofleachingsystemandmicrowaveabsorptioncharacteristicsofmixturesolutionsbeforeandafterleachingweremeasured.Theresearchofnon-isothermalkineticswasevaluatedbytheleachingrateofFeandthetotalapparentvelocityequationofthenon-isothermalkineticsofleachingforprimarytitanium-richmaterialbymicrowaveheatingwasobtained.Itisshownfromthetemperature-pressurecurvesthatthehightemperatureandhighpressureofclosedleachingsystemarefavorabletotheenhancementoftheleachingrateofFe.Microwaveabsorptioncharacteristicsofmixturesolutionsbeforeandafterleachingshowthatthereareabruptchangesofmicrowaveabsorptioncharacteristicsfor15%HClsolutionandthemixturesolutionafterleachingby20%HCl.

简介：Mg-12Gd-2Er-1Zn-0.6Zr(wt%)合金的机械性质上的homogenization和等温的老化处理的效果被调查。猛抛的长时期的叠顺序(LPSO)结构和调节合金的变老的降水顺序分别地被观察并且分析。结果显示14H-LPSO结构在等温的老化过程以后发生在homogenization处理和阶段形式以后。这二个独立过程能被降水温度范围控制。在homogenization处理以后的当演员组合金的延伸的重要增加被归因于粗糙的主要Mg5(Gd,的消失嗯，Zn)阶段和14H-LPSO结构的存在。调查合金的降水顺序是-Mg(SSS)/(D019)/(cbco)/。而且，张力的力量(YTS)和最终的张力的力量(UTS)等温的老化合金珍视的收益有大改进，它能被归因于猛抛的阶段的高密度。图形的AbstractWith延长的变老的时间，阶段在合金被猛抛。14H-LPSO结构和阶段在498K为84h在老化以后在合金共存。14H-LPSO的层结构显然被观察[11\(\overline{2}\)0]Mg方向，它在高分辨率的传播电子显微镜学(HRTEM)被显示出图象。14H类型结构与c的一个时期显示一份叠的订单?=?3.67?nm，它不在等温的老化过程期间变化。

简介：TheCu/Sn-3.OAg-0.5Cu/Cubuttingsolderjointswerefabricatedtoinvestigatetheevolutionoftheinterfacialintermetalliccompound(IMC)andthedegradationofthetensilestrengthofsolderjointsundertheeffectofelectromigration(EM)andagingprocesses.Scanningelectronmicroscopy(SEM)resultsindicatedthattheCu_6Sn_5interfacialIMCpresentedobviousasymmetricalgrowthwiththeincreaseofEMtimeundercurrentdensityof1.78×10~4A/cm~2at100℃,andthegrowthofanodicIMCpresentedaparabolicrelationshipwithtimewhilethecathodicIMCgotthinnergradually.However,asforagingsamplesat100℃withoutcurrentstressing,theCu_6Sn_5IMCpresentedasymmetricalgrowthwithaslowerratethantheanodicIMCofEMsamples.Thetensileresultsindicatedthatthetensilestrengthofthesolderjointsundercurrentstressdeclinedmoredrasticwithtimethantheagingsamples,andthefracturemodetransformedfromductilefracturetobrittlefracturequicklywhilethefracturemodeofagingsamplestransformedfromcup-coneshapedfracturetomicroporousgatheringfractureinaslowway.

简介：Anewtypeofnon-preheatedhardfacingelectrodewasdevelopedusingH08Aasthecoreandthecoatcontentsincludingferrotitanium,ferrovanadium,graphite,rutileetc.Themicrostructuresandpropertiesofhardfacingmetalweresystematicallyresearched.Theresultsshowthehardnessofhardfacingmetalincreaseswithincreasingofferrotitanium,ferrovanadium,graphiteinthecoat,butthecrackresistanceandprocessingweldabilitybecomeworse.Thecarbidesformedbyarcmetallurgicreactionareuniformlydispersedinthematrixstructure.Thephasesofhardfacingmetalconsistofα-Fe,γ-Fe,VC,TiCandFe3C.ThecarbidesarecompressionaggregationofTiCandVC,andtheirappearancespresentirregularblock.Thematrixmicrostructureofhardfacingmetalislathmartensite.Thehardfacinglayerswithbettercrackresistanceandwearabilityareachievedandnovisiblecracksoccurwhenusingnon-preheatedelectrodeincontinuousweldingprocess.Hardnessofhardfacingmetalismorethan60HRC,anditsrelativewearabilityisfivetimesofwearabilityofD667electrodeinabrasiveweartest.

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简介：MagneticBarkhausennoise(MBN)isaphenomenonofelectromagneticenergyduetothemovementofmagneticdomainwallsinsideferromagneticmaterialswhentheyarelocallymagnetizedbyanalternatingmagneticfields.AccordingtoFaraday’slawofelectromagneticinduction,thenoisecanbereceivedbythecoilattachedtothesurfaceofthematerialbeingmagnetizedandthenoisecarriesthemessageofthecharacteristicsofthematerialsuchasstresses,hardness,phasecontent,etc.Basedonthecharacteristicofthenoise,researchingabouttherelationshipbetweentheresidualstressintheweldingassemblyandthenoisearecarriedout.Furthermore,dataprocessisperformedbyRMS(RootMeanSquare)equationandPowerSpectrumanalysis.

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简介：Anaxisymmetricfiniteelementmodelisdevelopedtosimulatethetemperaturefieldofresistantspotweldingaccordingtotheprocesscharactersofnuggetformationofnon-equalstainlesssteelsheets.Asimulationmethodoftheinteractionofelectricalandthermalfactorsispresented.Thespotweldingprocessofnuggetformationissimulatedusinghardandsoftweldingtechniquenorms.Theheatingcharactersofsoftandhardnormsdeterminethedifferencesintheprocessofnuggetformationanddeterminethefinallyshapeandoffsetofnugget.Experimentalverificationshowsthatthemodelpredictionagreeswellwiththepractical.

简介：Metallurgicalmodelingofsynergisticmicrocrackself-repairmenduringweldingsinglecrystalandpolycrystallinesuperalloysofhigh-temperatureaerospacematerialshasbeenproperlyestablished.Theideaofimprovementofnickel-basedsuperalloysweldabilitythroughnon-equilibriumsolidificationbehaviorofbackfilltoself-repairarterialcracknetworkisusefullyproposed.Crystallographiccontrolstrategyofcrackself-repairmenoffusionzoneinterdendriticsolidificationcrackingandheat-affectedzone(HAZ)intergranularliquationcrackingistechnicallyachievable,indicatingthatoptimalniobiumalloyingbeneficiallyrefinesweldmicrostructure,stabilizestheprimarysolidificationpath,increasesthesolidificationtemperatureandconcomitantlydecreasestheweldpoolgeometry.High-carbongrainboundaryismorethermalstableandlesscontributestoincipientintergranularliquidfilmthanthatoflow-carbongrainboundary.Thetheoreticalpredictionsofcrackingsusceptibilityareindirectlyverifiedinarathersatisfactorymanner.Additionally,themetallurgicalmodelingenhancespredicativecapabilitiesandtherebyisreadilyapplicableforotheralloysystems.