学科分类
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3 个结果
  • 简介:Inthispaper,wederivethebrightanddarkphotonnumberstatesforspatialinterferenceoftwoormorelightbeamsandsucceedintheexplanationofYoung'sinterferenceexperiment,andalsoachieveabettercomprehensionofthewellknowncommentofDirac"eachphotononlyinterferenceswithitself".Fromthefullyquantumpointofview,theoriginoftheinterferencefringesconsistsinthemodetransformationandthedetectionofdouble-slitstates.

  • 标签: 信息光学 亮光子数态 暗光子数态 相干实验
  • 简介:Wefocusonthefullrelativisticquantummechanicalcalculationsfromborontofluorineatomswithelectronicconfigurationof1s22s22pn(n=1,2,3,4,and5),where1s22s2istheclosedshelland2pnistheopenshell.Theiractiveelectronsintheopenshelloccupyallthesixspinorsasfaraspossible.Therefore,wesuggestanewrulecalled'maximumprobability'forthefullsymmetrygrouprelativistictheory.Furthermore,thespectralfinestructureoftheatomicgroundstatesbasedonthefullrelativistictheoryandtheirintervalsofL-Ssplittingareallreasonable.ItisimpossibletocalculatetheL-Ssplittingthroughnon-relativisticquantummechanics.Therelativisticeffectofatomicmassisincreasedsignificantlybyabout12foldsfromboronatomtofluorineatom.

  • 标签: 相对论理论 精细结构 原子光谱 非相对论量子力学 地基 相对论效应
  • 简介:Thepotentialenergycurves(PECs)ofBOmolecule,includingΣ+andΠsymmetrieswithdoubletspinmultiplicities,areobtainedemployingmulti-referenceconfigurationinteraction(MRCI)methodandDunning'scorrelationconsistentbasissets.Theanalyticalpotentialenergyfunctions(APEFs)arefittedusingtheMurrell-Sorbie(MS)functionandtheleastsquaremethod.BasedonthePECs,thespectroscopicconstantsofthestateshavebeendeterminedandcomparedwiththetheoreticalandexperimentalresultsavailabletoaffirmtheaccuracyandliabilityofthecalculations.Theroot-mean-square(RMS)errorsbetweenthefittedresultsandtheabinitiovaluesaretoolittleincomparisonwiththechemicalaccuracy(349.755cm-1).ItisshownthatthepresentAPEFsareaccurateandcandisplaytheinteractionbetweentheatomswell.ThepresentAPEFscanbeusedtoconstructmorecomplicatedAPEFordosomedynamicinvestigations.

  • 标签: 组态相互作用 分子势能函数 势能曲线 分析势能函数 最小二乘法 光谱常数