简介:Treatmentof4-amino-3-(1-aryl-5-methyl-1,2,3-triazol-4-yl)-5-mercapto-1,2,4-triazoles/2-amino-5-(1-aryl-5-methyl-1,2,3-triazole-4-yl)-1,3,4-thiadiazoleswithbenzaldehyde,acetoneandω-bromoacetophenonewastestedandcompared.ThetitlecompoundsSchiffbases,amides,imidazolo[2,1-b]-1,3,4-thiadiazolesand7H-s-triazolo[3,4-b]-1,3,4-thiadiazineshavebeenconfirmedbyelementalanalyses,^1HNMR,IRandMSspectra.AllthecompoundshavealsobeenscreenedfortheirantibacterialactivitiesagainstB.subtilis,S.aureusandE.coli.
简介:Thestructureofpolyimidefrom1,4-bis(3’,4’-dicarboxyphenoxy)benzeneand4,4’-oxydianilinefilmspecimensbeforeandafterhotstretchinghasbeeninvestigatedbyWAXD,DSCandFTIR.AsevidencedbyboththeWAXDandDSCresults,itcouldbebelievedthatstraininducedcrystallizationdidtakeplaceafterhotstretching.Meanwhile,shiftingpositionandsplittingofsomebandpeaksexistedontheFTIRspectrogramswereexplainedintermsoftheclosepackingofchainsandthechangesofinter-molecularcharge-transferinteractionbetweenimidegroupsandaromaticgroupsuponcrystallization.
简介:LetMbeapositivequaternionicKhlermanifoldofdimension4m.Wealreadyshowedthatifthesymmetryrankisgreaterthanorequalto[m/2]+2andthefourthBettinumberb_4isequaltoone,thenMisisometrictoHP~(m).Thegoalofthispaperistoreportthatwecanimprovethelowerboundofthesymmetryrankbyoneforhighereven-dimensionalpositivequaternionicKahlermanifolds.Namely,itisshowninthispaperthatifthesymmetryrankofMwithb_4(M)=1isgreaterthanorequaltom/2+1form≥10,thenMisisometrictoHP~m.OneofthemainstrategiesofthispaperistoapplyamoredelicateargumentofFrankeltypetopositivequaternionicKhlermanifoldswithcertainsymmetryrank.
简介:Morelocalizedenergydepositionisabletobeproducedinantiproton-nucleuscollisionsincomparisonwithheavy-ioncollisionsduetoannihilationreactions.Searchingforthecoldquark-gluonplasma(QGP)withantiprotonbeamshasbeenconsideredasahottopicbothinexperimentsandinthereticalcalculationsoverthepastseveraldecades.Strangenessproductionandhypernucleusformationinantiproton-inducednuclearreactionsareimportanceinexploringthehyperon(antihyperon)-nucleon(HN)potentialandtheantinucleon-nucleoninteraction,whichhavebeenhottopicsintheforthcomingexperimentsatPANDAinGermany.
简介:Thehydrolysisreactionof(±)-2-acetamido-3-hydroxy-1-(4-nitrophenyl)-1-propanone[(±)-1],anintermediateofchloramphenicol,wasstudiedandthreedifferentproductswereobtainedrespectivelyunderdifferentreactionconditions.Theresolutionofhydrolysisproduct(±)-2-amino-3-hydroxy-1-(4-nitrophenyl)-1-propanone[(±)-3]wascarriedout.Aprocessofcrystallization-inducedasymmetrictransformationwasobservedandupto76%oftheopticallypureenantiomerwasobtainedintheresolutionof(±)-3.
简介:Refluxingcalix[4]-1,3-substitutedbenzaldehydederivative(4)withglycinehydrazidederivative,weobtainedanovelcalix[4]arenehydrazonederivative(5)via'1+2'condensationinayieldof78%.Inthereactionofcompound4withL-leucinehydrazidederivativeatroomtemperature,lariatcalix[4]-1,3-aza-crown(6)withchiralaminoacidgroupasbranchedchainwassynthesizedvia'1+1'additioninayieldof70%.Thepreliminaryextractionexperimentssuggestedthathostingcompounds5and6possessedgoodcomplexationabilitiesforα-aminoacids.
简介:Newmodelcompound1H,1′H-Bis(benz-Δ^4-imidazoline)2,2′-spiro-titaniumdichloridewaspreparedandthestructureofthecompoundwasdeterminedby1R,MSandelementaryanalysis.
简介:Thereactionof1-phenyl-3-methyl-4-benzoyl-2,5-dihydro-1H-pyrazol-5-one(PMBP)andmethyldithiocarbazate(mdtc)inmethanolresultsinformationofayellowcrystallinesolid,adductof1-phenyl-3-methyl-4benzoyl-2,5-dihydro-lH-pyrazol-5-oneandmethyldithiocarbazate.Whentheyellowsolidsweredissolvedinamixtureofmethanolandether(1:4),aredcrystal,whichisanoxidationproductoftheformer,wasobtainedbyallowingsolventtoevaporateforafewdaysatroomtemperature.TheX-rayanalysisoftheredcrystalindicatesthatitisanoveldisulfidewithaspecialstructurelikea“U”conformationinthesolidstate.
简介:ThepossiblegeometricalstructuresandrelativestabilitiesofsemiconductormicroclustersGa.P.(n=1-4)werestudiedbyvirtueofdensityfunctionalcalculationswithgeneralizedgradientapproximation(B3LYP).ForthemoststableisomersofGa,,P.(n=1-4)clusters,theelectronicstructure,vibrationalproperties.dipolemoment,polarizabilityandionizationpotentialwereanalyzedbymeansofHF.MP2.CISDandB3LYPmethodswithdifferentbasissets.
简介:InallthearticlesinActaMechanicaSolidaSinica,Volume31,Issues1-4thecopyrightisincorrectlydisplayedas"TheChineseSocietyofTheoreticalandAppliedMechanicsandTechnology"whereitshouldbe"TheChineseSocietyofTheoreticalandAppliedMechanics".
简介:Thetitlecomplex,[La(baec)1/2(H2btec)1/2(H2O)]n(H4btec=1,2,4,5-benzenetetracarboxylicacid)(1)wassynthesizedbythehydrothermalreactionof1,2,4,5-benzenetetracarboxylicdianhydridewithLa(NO3)3·6H2OinH2O,andcrystallizesinthetriclinicsystem,spacegroupP-1withα=0.64403(3)nm,b=0.94500(4)nm,c=0.96380(5)nm,α=88.535(2)°,β=100.314(2)°,γ=76.6470(10)°,V=1.69968(10)nm^3,Z=2,andfinalR=0.0274,Rw=0.0735.In1,eachLa(Ⅲ)ioniscoordinatedbyeightoxygenatomsfromsixcarboxylategroupsandonecoordinatedwatermolecule.TwodifferentcoordinstionmodesofH4btecwerePresentinthestructure,oneofwhichcontainstwoprotonatedcarboxylategrougpstobalancethecharge.