简介:Inordertodeepentheunderstandingoftherelationshipbetweenfundamentalproperties(including:microstructureandcomposition)andphotocatalyticperformance,fourbismuthatecompounds,including:LiBiO3,NaBiO3,KBiO3,andAgBiO3,areregardedasresearchexamplesinthepresentwork,becausetheyhaveparticularcrystalstructuresandsimilarcompositions.Usingdensityfunctionaltheorycalculations,theirstructural,electronic,andopticalpropertiesareinvestigatedandcomparedsystematically.Firstofall,thecalculatedresultsofcrystalstructuresandopticalpropertiesareinagreementwithavailablepublishedexperimentaldata.Basedonthecalculatedresults,itisfoundthatthetunneledorlayeredmicro-structuralpropertiesleadtothestrongerinteractionbetweenbismuthandoxygen,andtheweakerinteractionbetweenalkaline-earthmetaland[BiO6]octahedron,resultinginthefeatureofmulti-bandgapsinthecasesofLiBiO3,NaBiO3,andKBiO3.ThisconclusionissupportedbythecaseofAgBiO3,inwhichthefeatureofmulti-bandgapsdisappears,duetothestrongerinteractionbetweenthenoblemetaland[BiO6]octahedron.Thesepropertieshavesignificantadvantagesinthephotocatalyticperformance:absorbinglowenergyphotons,rapidlytransferringenergycarriers.Furthermore,thefeaturesofelectronicstructuresofbismuthatecompoundsarewellreflectedbytheabsorptionspectra,whichcouldbeconfirmedbyexperimentalmeasurementsinpractice.Combinedwiththecalculatedresults,itcouldbeconsideredthatthecrystalstructuresandcompositionsofthephotocatalystdeterminetheelectronicstructuresandopticalproperties,andsubsequentlydeterminethecorrespondingphotocatalyticperformance.Thus,anovelBi-basedphotocatalystdrivenbyvisible-lightcouldbedesignedbyutilizingspecificcompositionstoformfavorableelectronicstructuresorspecificmicro-structurestoformabeneficialchannelforenergycarriers.
简介:Multilayerblackphosphorus(BP)nanoplateletsofdifferentthicknesseswerepreparedbytheliquidphaseexfoliationmethodanddepositedontoyttriumaluminumgarnetsubstratestoformsaturableabsorbers(SAs).Thesewerecharacterizedwithrespecttotheirthickness-dependentsaturableabsorptionpropertiesat3μm.TheBP-SAswereemployedinapassivelyQ-switchedEr:Lu2O3laserat2.84μm.ByusingBPexfoliatedindifferentsolvents,stablepulsesasshortas359nsweregeneratedatanaverageoutputpowerofupto755mW.Therepetitionrateintheexperimentwas107kHz,correspondingtoapulseenergyof7.1μJ.TheseresultsprovethatBP-SAshaveagreatpotentialforopticalmodulationinthemid-infraredrange.
简介:Inthispaper,wepresenttheluminescentpropertiesofTm3+∕Ho3+co-dopednewglass.Aseriesofsilicategermanateglasswaspreparedbytheconventionalmelt-quenchingmethod.IntheTm3+∕Ho3+co-dopedsilicategermanateglass,astrongemissionof2μmoriginatingfromtheHo3+:5I7→5I8transitioncanbeobservedunderconventional808nmpumping.Thecharacteristictemperatures,structure,andabsorptionspectrahavebeenmeasured.TheradiativepropertiesofHo3+inthepreparedglasswerecalculated.TheemissioncrosssectionofHo3+ionstransitioncanreach4.78×10-21cm2around2μm,andtheFWHMisashighas153nm.TheenergytransferefficiencybetweenHo3+andTm3+hasalargevalue(52%),whichindicatestheTm3+∕Ho3+co-dopedsilicategermanateglassisasuitablecandidateforthe2μmlaser.Moreover,theenergytransfermechanismbetweenTm3+andHo3+ionswasinvestigated.
简介:基于Sigma-deltaModulator(Σ△M)原理的数字闭环微机械加速度计不仅实现了力反馈闭环控制,同时直接完成信号的模数转换。基于全差分式电容微加速度设计了一种2-2级联式(MASH)高阶Σ△M闭环系统——MASH_(2-2),并与传统的单环路二阶、四阶Σ△M闭环系统(SD2、SD4)进行了仿真分析比较,研制了原理样机。微加速度计是基于结构层厚度50mm的SOI硅片通过DRIE刻蚀、气态HF释放等一系列微加工工艺得到,系统电路以数字化方式集成在FPGA中。常压下测试结果表明,样机的灵敏度为0.876V/g,噪声基底为-110dB,零偏不稳定性为20mg,静态温漂为40.8mg/℃,量程为±20g。