简介：Inordertodeepentheunderstandingoftherelationshipbetweenfundamentalproperties（including:microstructureandcomposition）andphotocatalyticperformance,fourbismuthatecompounds,including:LiBiO3,NaBiO3,KBiO3,andAgBiO3,areregardedasresearchexamplesinthepresentwork,becausetheyhaveparticularcrystalstructuresandsimilarcompositions.Usingdensityfunctionaltheorycalculations,theirstructural,electronic,andopticalpropertiesareinvestigatedandcomparedsystematically.Firstofall,thecalculatedresultsofcrystalstructuresandopticalpropertiesareinagreementwithavailablepublishedexperimentaldata.Basedonthecalculatedresults,itisfoundthatthetunneledorlayeredmicro-structuralpropertiesleadtothestrongerinteractionbetweenbismuthandoxygen,andtheweakerinteractionbetweenalkaline-earthmetaland[BiO6]octahedron,resultinginthefeatureofmulti-bandgapsinthecasesofLiBiO3,NaBiO3,andKBiO3.ThisconclusionissupportedbythecaseofAgBiO3,inwhichthefeatureofmulti-bandgapsdisappears,duetothestrongerinteractionbetweenthenoblemetaland[BiO6]octahedron.Thesepropertieshavesignificantadvantagesinthephotocatalyticperformance:absorbinglowenergyphotons,rapidlytransferringenergycarriers.Furthermore,thefeaturesofelectronicstructuresofbismuthatecompoundsarewellreflectedbytheabsorptionspectra,whichcouldbeconfirmedbyexperimentalmeasurementsinpractice.Combinedwiththecalculatedresults,itcouldbeconsideredthatthecrystalstructuresandcompositionsofthephotocatalystdeterminetheelectronicstructuresandopticalproperties,andsubsequentlydeterminethecorrespondingphotocatalyticperformance.Thus,anovelBi-basedphotocatalystdrivenbyvisible-lightcouldbedesignedbyutilizingspecificcompositionstoformfavorableelectronicstructuresorspecificmicro-structurestoformabeneficialchannelforenergycarriers.

简介：采用UMP2/6-311＋G（3df）方法研究了一系列化合物M_（n＋1）F_n（n=1,2;M=Na,K）体系的几何构型及非线性光学性质（NLO）.结果表明：这些体系均为超价化合物,均拥有较大的第一超极化率（β_0）.尤其是Na_3F_2体系中结构2c的β_0值为29.16×10~（-49）C~3·m~3·J~（-2）,是已知超价化合物Li_3F_2的2c结构的β_0值2.22×10~（-49）C~3·m~3·J~（-2）的13.1倍.

简介：Multilayerblackphosphorus（BP）nanoplateletsofdifferentthicknesseswerepreparedbytheliquidphaseexfoliationmethodanddepositedontoyttriumaluminumgarnetsubstratestoformsaturableabsorbers（SAs）.Thesewerecharacterizedwithrespecttotheirthickness-dependentsaturableabsorptionpropertiesat3μm.TheBP-SAswereemployedinapassivelyQ-switchedEr:Lu2O3laserat2.84μm.ByusingBPexfoliatedindifferentsolvents,stablepulsesasshortas359nsweregeneratedatanaverageoutputpowerofupto755mW.Therepetitionrateintheexperimentwas107kHz,correspondingtoapulseenergyof7.1μJ.TheseresultsprovethatBP-SAshaveagreatpotentialforopticalmodulationinthemid-infraredrange.

简介：一个图称为分数（g，f，m）一消去图若删除任意m条边后的剩余子图依然存在分数（g，f）一因子．本文证明若图G的阶为n，1≤n≤g（x）≤f（x）-△≤b-△对任意顶点x∈V（G）成立，δ（G）≥（b-△）（b＋1）/a＋2m,n≥（a＋b）（2（a＋b）＋2m-1）/a＋△且｜NG（x1）∪NG（x2）｜≥（b-△）n/a＋b对任意不相邻顶点x1和x2都成立，则G是分数（g，f，m）-消去图．这个领域并条件在一定程度上是最好的．

简介：Inthispaper,wepresenttheluminescentpropertiesofTm3+∕Ho3+co-dopednewglass.Aseriesofsilicategermanateglasswaspreparedbytheconventionalmelt-quenchingmethod.IntheTm3+∕Ho3+co-dopedsilicategermanateglass,astrongemissionof2μmoriginatingfromtheHo3+:5I7→5I8transitioncanbeobservedunderconventional808nmpumping.Thecharacteristictemperatures,structure,andabsorptionspectrahavebeenmeasured.TheradiativepropertiesofHo3+inthepreparedglasswerecalculated.TheemissioncrosssectionofHo3+ionstransitioncanreach4.78×10-21cm2around2μm,andtheFWHMisashighas153nm.TheenergytransferefficiencybetweenHo3+andTm3+hasalargevalue（52%）,whichindicatestheTm3+∕Ho3+co-dopedsilicategermanateglassisasuitablecandidateforthe2μmlaser.Moreover,theenergytransfermechanismbetweenTm3+andHo3+ionswasinvestigated.

简介：基于Sigma-deltaModulator（Σ△M）原理的数字闭环微机械加速度计不仅实现了力反馈闭环控制,同时直接完成信号的模数转换。基于全差分式电容微加速度设计了一种2-2级联式（MASH）高阶Σ△M闭环系统——MASH_（2-2）,并与传统的单环路二阶、四阶Σ△M闭环系统（SD2、SD4）进行了仿真分析比较,研制了原理样机。微加速度计是基于结构层厚度50mm的SOI硅片通过DRIE刻蚀、气态HF释放等一系列微加工工艺得到,系统电路以数字化方式集成在FPGA中。常压下测试结果表明,样机的灵敏度为0.876V/g,噪声基底为-110dB,零偏不稳定性为20mg,静态温漂为40.8mg/℃,量程为±20g。

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