简介:StableoperatingregionintheHL-1Mtokamakhasbeenextendedbymeansofwallconditioning,corefuellingandcurrentcontroltechniques.Themechanismsoftheextensionareanalyzedinthispaper.Lithiumizationdiminishestheimpuritiesandhydrogenrecyclingtothelowestlevel.Afterlithiumizationahighdensityupto7×1019m-3wasobtainedeasilybystronggaspuffingwithordinaryohmicdischargealone.MoreattractivelywefoundthatmetalLi-coatingexhibitedtheeffectsofwallstabilization.Thelowqalimitwithhigherdensitywasextendedbyafactorof1.5~2incomparisonwiththatforboronization,and1.2forsiliconization.Siliconizationnotonlyextendedstableoperatingregionsignificantlybyitself,butalsoprovidedagoodtargetplasmaforotherexperimentsofraisingdensitylimit.Corefuellingschemesarefavourableespeciallyforsiliconizedwallwithahigherlevelofmedium-Zimpurity(Z=14).Aftersiliconizationthemaximumdensitynearto1020m-3wasachievedbyacombinationofsupersonicmoleculebeaminjectionandmultipelletinjection.ThenewdefinedslopeofHugilllimitillustratingmoreclearlythesituationunderlowqaandhighnedischargeswascreatedtoindicatethenewregionextendedbycombiningIpramp-upwithcorefuelling.TheslopewithalargeMurakamicoefficientincreasedbyafactorof50~60%.
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简介:利用角分辨紫外光电子谱对乙烯和乙炔气体在Ru(1010)表面的吸附及与K的共吸附的研究结果表明:当衬底温度超过200K,乙烯即发生脱氢反应,σCH和σCC能级均向高结合能方向移动。在室温下,σCH和σCC能级位置与乙炔在Ru(1010)表面的吸附时的分子能级完全一致。乙烯发生脱氢反应后的主要产物为乙炔。衬底温度从120K到室温,Ru(1010)表面上乙炔的σCH和σCC能级均未发现变化。室温下乙炔仍然可以在Ru(1010)表面以分子状态稳定吸附。在有K的Ru(1010)表面上,室温时σCC谱峰几乎。碱金属K的存在促进了乙炔的分解。
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简介:用EXAFS方法研究了重金属Zn(Ⅱ)在δ-MnO2上吸附的微观结构及吸附机制。在pH5.50,0.1M硝酸钠介质中,吸附-解吸实验表明Zn(Ⅱ)在δ-MnO2上的吸附可逆性很高.EXAFS结果表明,δ-MnO2表面上吸附态Zn2+以六配位的水合离子八面体形式存在。八面体的水合Zn^2+离子与δ-MnO2的结构单元MnO6八面体通过共用O原子结合,形成角-角结合的弱吸附.Zn-O平均原子间距为2.071A,Zn-Mn平均原子间距为3.528A。同一条等温线上随着吸附量增加,角-角结合的弱吸附形式基本上没有变化。Zn(Ⅱ)在δ-MnO2上较高的吸附可逆性是由于吸附态Zn(Ⅱ)与δ-MnO2以弱吸附的角-角形式结合所导致的。
简介:Vacuumtreatmentandion-beambombardmentaretwomajorprocessesinthelowenergyion-beamimplantation.Toaccuratelystudythecontributionsofthesetwomajorfactorstothebioeffectsseparately,theM_1generationvariationofArabidopsisthalianawithion-beamimplantationandvacuumtreatmentwerecomparedthroughaseriesofkeyplantdevelopmentparametersincludingmorphologicalobservation,biochemicalassayandRAPD(randomamplifiedpolymorphicDNA)analysis.Theresultsshowedthation-beamimplantationhadobviouseffectonalmostalloftheseparameters,andthevacuumtreatmenthadsomeimpactsonseveralmorphologicalparameterssuchastheboltingtimeandthelengthoftheprimarystem.Takingtheresultstogether,theindicationisthatvacuumtreatmenthassomeslightcontributionstothebioeffectsofion-beamimplantationwhileion-beambombardmentitselfisthemajorcreatorofthebioeffects.