简介:今年二季度初,核工业95质量工作会隆重召开。来自中核总70多个单位的质量总工程师、质量处长及肩负着军工企业质量工作重任的专家们汇聚北京,共商质量工作大计。在短短的几天时间里,会议代表围绕搞好核工业企事业、产品(工程)质量,交流了经验,总结了教训,研究了对策。1质量工作成绩斐然核工业从诞生之日起,就一直遵循着“万无一失,一次成功”的方针。全方位地保证军品质量,从而造就出了一支人员高素质,技术高水准,产品高质量的三高队伍。随着改革开放,核工业的光荣传统依旧在发扬。总公司注重抓质量工作,近年来军工产品质量一直处在稳定阶段,军品合格率始终保持100%。民品质
简介:SpectroscopicmethodsareusedtoinvestigatecoordinationstructureofN-picolylpolyurethanetransitionmetalcomplexes(PUPYM,M=Co^2+andNi^2+).Geometricalarrangementofligandsinfirst-shellcoordinationsphereofmetalionsispostulatedtobetetrahedralCoL2Cl2andoctahedralNiL2-Cl2Z2.whereListhepicolylgroupandZisahydrate.FromextendedX-rayabsorptionfinestructure(EXAFS)analysis,bondlengthsformetal-chlorineandmetal-ligandofPUPYMaresimilartothoseofsmallmolecularweighttransitionmetalcomplexes.Atwo-phasemodelofPUPYMwhichbestdescribestheexperimentaldataofDMTAandSAXS.isproposed.Onemicrophaseistheharddomainofselfsegregatedhaedsegmentsbroughtaboutbymetal-ligandinteraction.andtheotherphaseisthematrixofsoftsegments.Transitionmetalion-ligandmoietiesandtheirinteractionsdominatethemacroscopicthermalbehaviorofPUPYM.Theligandfieldstabilizationenergydifference(ΔLFSE)betweenmteald-electronsincomplexeswithtwopicolylligandsinthecoordinationsphereofmetalionsandcomplexesmaintainingonepicolylligandascoordinationpendentgroupiscalculatedonthebasisofobservedcoordinationstructure,anditrepresentstheenergysuppliedtosplitcoordinationcross-links.ΔLFSEofpolyurethanenickel(II)complexislargerthanthatofthecobalt(II)complex,Sincethemobilityofhardsegmentsisininverseproportiontothestrengthofcoordinationcross-links.ahigherα-transitiontemperatureofPUPYNi^2+withrespecttoPUPYCo^2+isfoundasexpected.
简介:Wehavedevelopedalargenumberofexocrineglandsonliquoriceleavesandfacilitatedpolysaccharidesecretion.Liquoricepolysaccharidepossessesstrongerboundwateraffinitytogaseouswatercomparedwithsucroseandglucose.Ourresultsshowthattheboundwateraffinityofliquoricepolysaccharidetogaseouswateris49.75%higherthanglucose(p<0.01).WithN~+implantation(totaldosageof4.68×10~(16)ions/cm~2andenergyof20keV)intodryliquoriceseeds,boththeboundwateraffinitytogaseouswaterandtheboundwatercontentofdryliquoriceleafcanbesignificantlyincreased30.24%(p<0.01)and36.51%(p<0.01)respectivelycomparedwiththesham-irradiatedseeds.Meanwhile,withtheseparameterschosenforN~+implantationintodryliquoriceseeds,theleafpolysaccharidecontentunderwaterstress(ψ_w=-1.5MPa)canincreasesignificantly(p<0.05)andtheplantgrowthcanalsoimprovesignificantly(p<0.05).
简介:用磁控溅射方法制备了一系列[C(t)/Cu(2.04nm))In(n=20,30)周期多层膜,利用四端点法、振动样品磁强计研究了多层膜的电磁性质,样品的磁电阻随钴亚层厚度的增大有一最佳值t=1.2nm。利用同步辐射掠入射X射线散射(衍射)技术在不同的X射线能量下研究了耦合多层腹的界面结构,探索了耦合多层膜中磁电阻增强的可能原因。
简介:采用程序升温氮化的方法制备了钼氮化物催化剂,并用EXAFS方法研究了氮化前后Mo原子的局域配位情况。负载MoO3样品的径向结构函数中有三个峰其中前两个峰对应着最近的Mo-O配位壳层,但是第一个峰与第二个峰的比例比晶体MoO3中的比例大很多,表明分子筛负载的MoO3具有更紧密的结构。氮化以后,Mo2N样品的径向结构函数中有三个峰,对应于一个Mo-N和两个Mo-Mo配位壳层,与面心立方模型符合的很好。根据X射线衍射和EXAFS谱的计算表明,Mo2N中的N原子使Mo-Mo键拉长并削弱。分子筛负载的Mo2N样品具有与非负载Mo2N样品相似的径向结构函数,只是对应于Mo-N壳层的峰较弱,表明负载的MoO3更难氮化。