简介：在进行高中化学复习教学的过程中，常常遇到关于氢氧化钡的图像题，这类题目忽深忽浅，给学生的学习带来一定的困难，现把对这类题目总结如下。

简介：在高一化学教材必修（2）第二章第一节＂化学能与热能＂里有一个这样的演示实验：将约20gBa（OH）2·8H2O晶体研细后与约10gNH4Cl晶体一起放入烧杯中,并将烧杯放入滴有几滴水的玻璃片或小木块上,用玻璃棒快速搅拌闻气味,用手触摸杯壁下部,试着用手拿起烧杯,观察现象。一、实验存在的问题1.实验成功的关键是小烧杯与下面的玻璃片要粘结在一起,否则会被认为不成功。

简介：Fe（OH）2是一种白色难溶于水的固体，在空气中或含O2的水溶液中极易被氧化而变色，难以观察到它的本来颜色．对此，人们开动脑筋，设计了多种方法来解决Fe（OH）2被氧化的问题．

简介：现行教材中有关Fe(OH)2的制备装置由于是一个开放的反应体系，故实际上只能观察到瞬间的Fe(OH)2白色沉淀(几乎分辨不出)．要较长时间观察到白色沉淀的生成，关键是怎样降低反应体系中氧气的存在量和操作过程中氧气的引入量．笔者在此将几种典型的改进方法作一介绍．

简介：

简介：

简介：

简介：

简介：Takingadvantageofthelargeγ-detectorarrayGammasphereandtherecoilmassseparatorFMA,highspinstatesin117Bawereinvestigatedthroughtherecoil-β-delayedprotondecaytaggingtechniqueviatheheavy-ioninducedfusion-evaporationreaction64Zn(58Ni,2p3n)117Ba,atabeamenergyof305MeV.Promptγraysbelongingto117Bahavebeenidentifiedfurthermore,arotationalbandhasbeenidentifiedforthefirsttimeandpresentedasbandAinFig.1.

简介：

简介：

简介：TheinfluenceofNa2SO4ontheformationofZnOwhiskerswasinvestigatedinthispaper.ZnOwhiskerswithaspectratiosofupto50weresynthesizedbydissolvingε-Zn（OH）2precursorinNaOH/Na2SO4solutionatroomtemperature,followedbyagingoftheresultingsolutionat140℃for6h.Fouriertransforminfraredspectroscopy,Ramanspectroscopy,andX-rayphotoelectronspectroscopyanalysesrevealedthatSO42-ionswereprimarilyadsorbedonthe（100）planeoftheZnOwhiskersviaanouter-spherecomplexconfiguration（O-H…O）,therebypromotingtheone-dimensionalgrowthofZnOwhiskersalongthec-axis.

简介：ThephaseandmorphologytransformationduringthehydrothermaltreatingprocessofY2O3wasevaluatedwithX-raydiffcrcnce(XRD),scanningelectronmicroscopy(SEM),transmissionelectronmicroscopy(TEM),particlesizeandspecificsurfaceareadetermination.TheresultsshowedthatthecubicY2O3didnottransferintohexagonalY(OH)3inpurewater.Therefore,purehexagonalY(OH)3withnanotubeandmicrorodmorphologieswereobtainedbyhydrothermaltreatingY2O3at150℃for12hin15mlof2mol/LNaOHsolutionwithandwith-outPVAorPEGItwassuggestedthatthecharacteristicpreferentialgrowthofY(OH)3wasattributedtothestructureanisotropyofhexahedronY(OH)3.TheadditionofPVAorPEGcouldpromotetheformingprocessofnanotubesbyselectiveadsorptionondifferentcrystalplanes,whichalteredthegrowthratealongdifferentdirectionsandresultedinthediffusionlimitofconstructingionsinthecentertopofrods.Finally,Y(OH)3:EuandY2O3:Eunanotubeswerealsosynthesizedbyusingthismethod,andtheirphotoluminescencepropertieswereevaluated.

简介：Thedevelopmentofthehydrogenelectrodeisvitalfortheapplicationofalkalinepolymerelectrolytefuelcells(APEFCs).Inthisstudy,aseriesofNi(OH)2decoratedNi/Ccatalysts(Ni(OH)2-Ni/C)werepreparedbyathree-stepelectrochemicaltreatmentofNi/C.TheexistenceofNi(OH)2wasdemonstratedbyX-rayphotoelectronspectroscopy(XPS),andthesurfacemolarratioofNi(OH)2/Niofthesampleswasestimatedviaanelectrochemicalmethod.TheHORcatalyticactivityofthecatalystswasevaluatedbyarotationdiskelectrode(RDE)method,anda'volcanoplot'wasestablishedbetweentheHORexchangecurrent(j0)andthesurfacemolarratioofNi(OH)2/Ni.Ontopofthe'volcano',thesurfacemolarratioofNi(OH)2/Niis1.1:1,thej0ofwhichwas6.8timesofthatofNi/C.ThestabilityofthesamplestowardHORwasevaluatedtobegood.OurstudyaddedasystematicexperimentalevidencetotheHORresearch,showingthattheHORcatalyticactivityofNicanbedeliberatelycontrolledviadecorationofNi(OH)2,whichmayhelpunderstandingtheHORmechanismonNi.

简介：氯化铵溶液能溶解Mg（OH）2,实为沉淀溶解平衡、氨水的电解质平衡以及水的电离平衡综合作用的结果,其本质为离子反应,是NH4＋还是H3O＋首先作用于Mg（OH）2的沉淀溶解平衡,对此学术界无统一的观点。复分解反应的活化能几乎为0,但各种离子的扩散速率不尽相同,多种离子参加反应时,到底哪种离子首先碰撞先发生反应,实难判断,事实上也不重要,但我们可以通过计算、实验得出铵盐溶解Mg（OH）2的＂功劳＂主要是NH4＋,而不是H3O＋,同时指出低浓度的铵盐难以溶解氢氧化镁的事实。

简介：Anisotropicstructures,nanoneedles,andnanospindlesofrareearthhydroxychloride(RE(OH)2Cl)andoxychloride(REOCl)(rareearth=EuandTb)weresynthesized.Therareearthhydroxychloridenanostructureswereformedviaathermallyassistedhydrolysisoftherare-earthsesquioxidenanocrystals.Themorphologicalevolutionofthenanostructureswasstudiedusinghigh-resolutiontransmissionelec-tronmicroscopyandscanningelectronmicroscopy,whilethestructuralevolutionwasinvestigatedusingX-raydiffractiontechniques.Thethermalstabilityoftherareearthhydroxychlorideswasinvestigatedusingthermogravimetricanalysis.Therareearthoxychloridenanospin-dlesweresynthesizedviaasimpleheat-treatmentofrareearthhydroxychloridenanospindles.

简介：

简介：

简介：

简介：AnewlayeredCu-basedoxychalcogenideBa3Fe2O5Cu2S2hasbeensynthesizedanditsmagneticandelectronicpropertieswererevealed.Ba3Fe2O5Cu2S2isbuiltupbyalternativelystacking[Cu2S2]2-layersandironperovskiteoxide[（FeO2）（BaO）（FeO2）]2-layersalongthecaxisthatareseparatedbybariumionswithFe3+fivefoldcoordinatedbyasquare-pyramidalarrangementofoxygen.Fromthebondvalencearguments,weinferredthatinlayeredCuCh-based（Ch=S,Se,Te）compoundsthe+3cationinperovskiteoxidesheetprefersasquarepyramidalsite,whilethelowervalencecationprefersthesquareplanarsites.Thestudiesonsusceptibility,transport,andopticalreflectivityindicatethatBa3Fe2O5Cu2S2isanantiferromagneticsemiconductorwithaNe′eltemperatureof121Kandanopticalbandgapof1.03eV.Themeasurementofheatcapacityfrom10Ktoroomtemperatureshowsnoanomalyat121K.TheDebyetemperatureisdeterminedtobe113K.TheoreticalcalculationsindicatethattheconductionbandminimumispredominantlycontributedbyO2pand3dstatesofFeionsthatantiferromagneticallyarrangedinFeO2layers.TheFe3dstatesarelocatedatlowerenergyandresultinanarrowbandgapincomparisonwiththatoftheisostructuralSr3Sc2O5Cu2S2.