简介:Witharapidincreaseinvolumeofve-hiclesintheworld,thepolutioncausedbytheautomobileexhaustedgashasbe-comemoreandmoreserious.Thisproblemhasbroughttoourgovernment’satten-tion.InBeijing,regulationsregardingthesupervisionoftheexhausthavebeenissued.AttheFifthNationalMeetingonRECatalyticpurificationofAutomobileEx-haustheldinBeijing1989,thepartici-pantsfrominstitutes,universities,andfactoriesalloverthecountryreportedanddiscussedthemethodsofpurifica-
简介:AnewtypeofcomplexsolidsuperacidcatalystWO3-ZrO2-SO42-withanacidstrengthH0≤-16.04waspreparedbykneadingZr(OH)4oramorphousZrO2withtungsticacid(H2WO4)(W/Zr=0.15),followedbyexposingthiscomplexhydroxidesto0.5tool/LH2SO4,calcininginairat700~800℃for3h.ThiscatalystpossessesbothstrongBronstedacidityandstrongLewisacidityexperimentallyshowedbyIRobservationofpyridineabsorbedonit.XPSandAEStechniqueswereemployedtoexaminethevalencestatesoftungsten,zirconium,sulfurandtheirinteractions.Thestructureofsulfurspecieswasstudiedbyinfraredspectroscopyandastructuremodelofactivesitewasproposedupontheseresults.
简介:ThevanadiumspecieswerecontaminatedonFCCcatalystsbyusingtheMitchellmethod.AfterthehydrothermaldeactivationoftheFCCcatalysts,thecrackingreactionwasperformedonthesecatalystsamples.ThetestresultsrevealedthattheconversionoffeedstockandthegasolineyieldobtainedovertheFCCcatalystswithvanadiumtrappingcomponentswereobviouslyhigherthanthosewithoutadditionofvanadiumtrappingcomponents.TheresultsalsoshowedthatthedrygasandcokeselectivityontheFCCcatalystscontainingvanadiumtrappingcomponentswasimproved.TheX-Raydiffractionresultsprovedthatthezeolitecrystalstructurewaswellprotectedbythevanadiumtrappingcomponentsduringitshydrothermaldeactivationstep.TheresultsofSEM-EDXmappingdisclosedthatthevanadiumwasenrichedonthevanadiumtrappingcomponentswhichverifiedthepositivefunctionofvanadiumtrappingcomponents.
简介:ThestrontiummodifiedwasteFCCcatalystwaspreparedbymagneticstirringmethodandcharacterizedbyXraydiffractometry(XRD),UV-Visdiffusereflectancespectrometry(DRS),X-rayphotoelectronspectroscopy(XPS)andscanningelectronmicroscopy(SEM).Meanwhile,itsphotocatalyticdenitrogenationperformancewasevaluatedintermsofitsabilitytodegradetheN-containingsimulationoilundervisiblelight.Amixtureofstrontiumnitratesolution(withaconcentrationof0.5mol/L)andwasteFCCcatalystwascalcinedat400℃for5hpriortotakingpartinthephotocatalyticdenitrogenationreaction.ThetestresultsshowedthatthephotocatalyticdegradationrateofpyridinecontainedinsimulationoilinthepresenceofthestrontiummodifiedFCCcatalystcouldreach92.0%undervisiblelightirradiationfor2.5h.
简介:降低polyketone合成的费用,稀土元素坐标催化剂被介绍给一氧化碳(公司)和苯乙烯(圣)的共聚化合物综合aliphaticpolyketoneSTCO。催化系统由稀土元素钕醋酸盐,乙酸钇,2,2''-bipyridine,p-toluensulfonic酸,含铜的p-toluensulfonate,和1,4-benzoquinone组成。Thecatalyst和共聚物被红外线的光谱和X光检查photoelectronspectrosco-py分别地描绘。催化系统的每个部件和共聚化合物的催化活性上的稀土元素醋酸盐的类型的效果被调查。结果证明建议稀土元素在公司和圣的copoiymerization有不同催化活性,最大的活动能到达303.3gSTCO/(摩尔中心点h)。