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  • 简介:Two-dimensionalmaterialsaregeneratinggreatinterestduetotheiruniqueelectricalandopticalproperties.Inparticular,transitionmetaldichalcogenidessuchasmolybdenumdisulfide(MoS2)areattractivematerialsduetotheexistenceofadirectbandgapinthemonolayerlimitthatcanbeusedtoenhancenonlinearopticalphenomena,suchasRamanspectroscopy.Here,wehaveinvestigatedfour-wavemixingprocessesinbulkMoS2usingamultiplexcoherentanti-StokesRamanspectroscopysetup.Theobservedfour-wavemixingsignalhasaresonanceatapproximately680nm,correspondingtotheenergyoftheAexcitonictransitionofMoS2.Thisresonancecanbeattributedtotheincreasedthird-ordernonlinearsusceptibilityatwavelengthsneartheexcitonictransition.ThisphenomenoncouldopenthepathtousingMoS2asasubstrateforenhancingfour-wavemixingprocessessuchascoherentanti-StokesRamanspectroscopy.

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