简介:Thehighshearagitationdevicewasfirstadoptedforgasolinedesulfurizationbyionicliquids.Theeffectofbenzylimidazolfluoborateindesulfurizationofgasolineandtheinfluenceofmoistureondeuslfurizationratewereinvestigated.Theexperimentalresultsshowedthattheionicliquidcouldeffectivelydecreasethesulfurcontentofgasolineandtheoptimalconditionswereasfollows:Thereactioncouldbecarriedoutatroomtemperature,avolumetricratiobetweenoilandtheliquidof2∶1,avolumetricratiobetweenwaterandionicliquidof0.04∶1,arotationalspeedof5krad/s,andareactiontimeof1minute.Thedesulfurizationrateofgasolinereached53.6%,andthegasolineyieldwasupto97.3%.Theionicliquidcouldberecycledforrepeateduse,andtheuseofhighshearagitationforgasolinewouldhavegoodprospects.
简介:AnumberofdrybridgeshavebeenbuilttosubstitutefortheroadbedontheQinghai-TibetRailway,China.Theaimofthisstudywastoinvestigatetheexothermicprocessofcast-in-place(CIP)pilefoundationofadrybridgeanditsharmtothestabilityofnearbyfrozenground.Wepresent3Dheatconductionfunctionsofaconcretepileandoffrozengroundwithrelatedboundaries.Ouranalysisisbasedonthetheoryofheatconductionandtheexponentlawdescribingtheadiabatictemperaturerisecausedbyhydrationheat.ResultsundercontinuousandinitialconditionswerecombinedtoestablishafiniteelementmodelofaCIPpile-frozengroundsystemforadrybridgeunderactualfieldconditionsincoldregions.NumericalresultsindicatedthattheprocesscouldeffectivelysimulatetheexothermicprocessofCIPpilefoundation.ThermaldisturbancetofrozengroundunderalongdrybridgecausedbythecastingtemperatureandhydrationheatofCIPpileswassubstantialandlong-lasting.Thesimulatedthermalanalysisresultsagreedwithfieldmeasurementsandsomesignificantrulesrelatingtotheproblemwerededucedandconclusionsreached.