学科分类
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40 个结果
  • 简介:Thecatalyticwetairoxidation(CWAO)ofHacidandphenolwasinvestigatedinthepresenceofCuorFedopedCeO2solidsolutions,whichwereobtainedbysol-gelmethod.TheexperimentresultsshowedthattheincorporationofCuorFeintothefluoritelatticeofCeO2stronglyenhancedtheoxidationactivityofthecatalyst.At90℃and0.1MPa,Hacidconversionwas70%fortheCe0.9Fe0.1O2-δand60%fortheCe0.9Cu0.1O2-δcatalyst.Forphenolremoval,theconversionwas70%fortheCe0.9Cu0.1O2-δcatalyst,whilefortheCe0.9Fe0.1O2-δtheconversionwas30%.TheresultsindicatedthatCe0.9Cu0.1O2-δwassuitableforthetreatmentoforganicwastewaterswhileCe0.9Fe0.1O2-δwassuitablefortheremovalofHacid.The70%phenolremovalratewithCe0.9Cu0.1O2-δcatalystwasmarkedlyincreasedto90%withCe0.8Cu0.2O2-δcatalyst.However,thephenolremovalreducedfrom30%to15%withFecontentincreasingfrom10%to20%.FortheHacid,theincreaseofthecontentofCuorFetendedtoobviouslyincreasetheoriginalreactionratewhiletheCODremovalchangedlittle.

  • 标签: H acid PHENOL COD removal rate
  • 简介:Thetreatmentoftheindustrialwastewater,inwhichtheconcentrationoftriethylamine(TEN)andCODcrwasaround3450mg/Land22400mg/Lrespectively,wasstudiedbyadsorptionofmacroporousresins,ResultsdemonstratethatthepolymericadsorbentCHA-111hasexcellenteffectontheadsorptionanddesorptionofTEN.TheconcentrationofTENintheeffluentislessthan30mg/L,andtheremovalefficiencyofTENandtotalCODcrexceed99%and95%respectively.TheaccumulationandresourcereuseofTENcanberealizedinthisprocess.

  • 标签: 工业废水处理 三乙胺 聚合吸附剂
  • 简介:凝结絮凝过程在diosgenin废水的预告的处理被使用。当主要凝结剂和cationicpolyacrylamide(CPAM)被用作凝结剂帮助,Polyferric硫酸盐被使用。用罐测试过程,主要操作参数的影响,例如在凝结的自河pH和凝结剂剂量,性能被调查。有效pH被发现在6.58.0的范围,凝结剂剂量是100mg/L。在最佳的条件下面,15%化学的氧需求(货到付款)移动效率被完成,剩余混浊是不到20NTU。CPAM的存在实质地在25mg/L的范围与适当CPAM剂量支持了剩余混浊的减小。

  • 标签: 阳离子聚丙烯酰胺 聚合硫酸铁 皂素废水 酸预处理 薯蓣 有效剂量
  • 简介:Systematicstudiesonthetreatmentandreuseoftheacidindustrialwatewatercontainingsodium2-Naphthylsulfonate(β-salt)from2-NaphthanolproductionprocessbyND-910resin(madebyself)isreportedinthispaper.Undertheoperationconditionsofinitialβ-saltconcentrationof10000-25000mg/LandinitialCODCrof20000-40000mg/L,theremovalratesofSodium2-NaphthylsulfonateandCODCrareover95%andover89%,respectively.Theeffluentcanbedischargeddirectlyafterbiologicaldegradation.TheworkingsorptioncapacityofND-910Resinforβ-saltisover230g/kg.Analkali-waterwashprocedureisutilizedtoregenerateresinandthereclaimingrateofβ-saltisover98%.

  • 标签: 2-萘并吡咯生产 废水处理 废水再用
  • 简介:Thelimestone-gypsumfluegasdesulfurization(FGD)processhasbecomethemostwidespreadprocessintheworldforsulfurremoval.Theswirl-et-absorbingwetlimestone-gypsumsinteringFGDtechnologywasdevelopedforsinteringfluegasdesulfurization,andthisprocessproducesvolumesofwastewaterwithvariouscontaminantsthatrequirestreatmentbeforedisposalorreuse.Inthisstudy,thewastewaterqualityfromthreedifferentsinteringFGDsystemsatBaosteelGroupwasinvestigatedandcomparedwithwastewaterfrompowerplantFGD.AtreatmentprocesswasproposedwhichissuitableforsinteringFGDwastewater.Aftertreatmentwithaneutralization,coagulationandsedimentationprocess,heavymetalsinthesinteringFGDwastewaterwerereducedtoalevelmeetingtherelevantemissionstandards,butthepHandammoniaconcentrationweretoohigh,andafurthertreatmentprocesswasneeded.DuetocertainsimilaritiesandcomplementaritiesbetweensinteringFGDwastewaterandcokingwastewater,itisentirelyfeasibletomixthepretreatedsinteringFGDwastewaterintoabiologicalcokingwastewatertreatmentsystem.ThisstudyindicatesthatitisentirelyfeasibletomixpretreatedsinteringFGDwastewaterintothebiologicaltreatmentsystemsusedforcokingwastewaterfromtheironandsteelindustries.

  • 标签: 废水处理系统 烧结烟气 脱硫过程 烟气脱硫装置 生物处理系统 脱硫废水
  • 简介:4,4'-diaminostilbene-2,2'-disulfonicacid(DSDacid)manufacturingwastewaterwastreatedbyamacroporousresininafixed-bedcolumn.Theresultsshowedthatthismethodwassuitableforremovalofchemicaloxygendemands(COD)andcolorAbout91%CODand99.5%colorremovalwereobtainedundertheoptimumadsorptionconditions,i.e.temperature20℃,flowrate1bedvolume/hour(BV/hr)andpH1-2.Theresinwasefficientlyregeneratedwithaqueoussodiumhydroxideandwater.Furthermore,65.5%of4,4'-dinitrostilbene-2,2'-disulfonicacid(DNS)couldberecoveredfromwastewaterforpossiblerecyclingtothemanufacturingprocess.Theadsorptioncapacityofresinremainedconstantduringtherepetitionprocessofadsorptionanddesorption.

  • 标签: 大孔树脂 废水 吸附 解吸
  • 简介:Inthispaper,thetwoeffluentsfromPBA(3-phenoxy-benzaldehyde)productionprocessweretreatedbypolymericadsorbentCHA-111.PBAorPBC(3-phenoxy-benzoicacid)wasrecoveredfromthewastewaterintheprocessofneutralization.Asasecondarytreatmentmethod,adsorptionwithCHA-111showedbetterefficiencythanphotocatolyticdecompositionandsolventextraction.Theoptimaltechnologicalparameterswere:adsorption:currentvelocity:2.0BV/hr(bedvolumeperhour),roomtemperature;desorption:currentvelocity:2.0BV/hr(bedvolumeperhour),roomtemperature;desorption:currentvelocity:1.0BV/hr,80℃,8%sodiumhydroxideaqueoussolutions.Inconclusion,99.9%CODintheneutralizingwastewaterand98.4%CODinthehydrolysiswastewaterareremovedsuccessfully.

  • 标签: 聚合吸附剂 3-苯氧基苯甲醛 废水处理
  • 简介:Wastewaterfromproductionprocessof2,3-acidwastreatedbyadsorptionusingmacroporousresinNDA-708.Afteronlyone-steptreatmentbyresinadsorption,removalefficiencyofthreekindsofnaphthalenechemicalswasabove99%;removaleficiencyofCODcrwasabove96%.Underproperoperatingcondition,desorptionefficiencywasaround100%.Therunningrecordsoftheindustrialfacilityshowedthatthenaphthlenechemicalsindesorptioneffluentcouldbereusedwithoutobviousinfluenceonthequalityoftheproduct.

  • 标签: 2 3-酸 生产过程 废水处理
  • 简介:Thepowderedactivatedcarbontreatment(PACT)processhasbeenwidelyusedinmanyindustrialfields,however,veryfewPACTprocessesarebuiltforpetrochemicalwastewatertreatmentinChina.AnindustrialPACTunitlaunchedinapetrochemicalplantwasintroducedandevaluatedfromboththepracticeandmechanismstudy.Practically,thePACTprocessshowedexcellentcapabilityinpollutantsremoval,shockresistance,toxicitytolerance,andtheCODandammonium-NineffluentofPACTunitassistedbyPACwasequalto15.5mg/Land0.7mg/LlowerthanthatwithoutPACaddition,respectively.ThewetoxidationregenerationunitwasquiteefficientinsupplyingregeneratedPAC,and,however,thehardcalciumsulphatescaleandthehighpollutantconcentrationsolutionneededtobecarefullycontrolled.Moreover,althoughthecarbonbalanceshowedthattheadsorptioncapabilityofregeneratedPACwasnegligible,thebiologicaltestsprovedthattheregeneratedPACincreasedmicrobeactivityupto17%morethanpureactivatedsludgesystem,whichwasalmostcompatiblewiththefreshactivatedcarbon.

  • 标签: powdered ACTIVATED carbon treatment PETROCHEMICAL WASTEWATER
  • 简介:ThewastewaterfromnaphtholAs-EproductionprocesswastreatedwithmacroporouspolymericadsorbentNDA-222.NaphtholAs-Eand2,3-acidinthewastewatercouldberemovedcompletelyandtheTotalOrganicCarbon(TOC)ofthewastewaterwasdecreasedmorethan98%from1655mg/Ltolessthan30mg/L.TheadsorbatescouldbedesorbedcompletelywithNaOHaqueoussolution.

  • 标签: 废水处理 资源 再利用
  • 简介:Thesolid-phasemicroextraction(SPME)combinedwithgaschromatography/massspectrometry(GC/MS)wasusedtodetermineandanalyzeorganicpollutantsincokingwastewater.Basedonthefactthatthemaincompoundsinthewastewaterwereorganics,somekeyparametersoftheSPMEwereoptimized.Themethodhasgoodlinearity(itscorrelationcoefficients>0.99)intherangedetermined,itsrelativestandarddeviations(RSD)arelessthan15%,anditsrecoveryisfrom87.9%to128.1%withthelowestquantificationlimitof5μg/L.Thismethodhasbeenusedtomeasure15organicpollutantsinwastewaterfromacertaincokingplant.Theresultsshowthatcomparedwiththeconventionalmethod,itcansaveanhourinpretreatmenttime.Itisafast,low-cost,accurate,simpleandefficientanalyticalmethodindeed.

  • 标签: 焦化废水 有机物 气相色谱 质谱 固相微萃取 有机污染物
  • 简介:Anilineisatoxicwaterpollutantdetectedindrinkingwaterandsurfacewater,andthischemicalisharmfultobothhumanandaquaticlife.Adielectricbarrierdischarge(DBD)reactorwasdesignedinthisstudytoinvestigatethetreatmentofanilineinaqueoussolution.Dischargecharacteristicswereassessedbymeasuringvoltageandcurrentwaveforms,capturinglightemissionimages,andobtainingopticalemissionspectra.Theeffectsofseveralparameterswereanalyzed,includingtreatmentdistance,dischargepower,DBDtreatmenttime,initialpHofanilinesolutions,andadditionofsodiumcarbonateandhydrogenperoxidetothetreatment.Anilinedegradationincreasedwithincreasingdischargepower.Underthesameconditions,higherdegradationwasobtainedatatreatmentdistanceof0mmthanatothertreatmentdistances.Atadischargepowerof21.5W,84.32%ofanilinewasremovedafter10minofDBDtreatment.InitialpHsignificantlyinfluencedanilinedegradation.Addingacertaindosageofsodiumcarbonateandhydrogenperoxidetothewastewatercanacceleratethedegradationrateofaniline.PossibledegradationpathwaysofanilinebyDBDplasmaswereproposedbasedontheanalyticaldataofGC/MSandTOC.

  • 标签: 介质阻挡放电 苯胺溶液 降解速率 废水利用 初始PH值 常压
  • 简介:Water-insolublebagassexanthateswerepreparedbyxanthationofalkalifiedcellulosesbytreatingbagassewithchromiumhydroxidereactioneffluent.TheremovelofnickelfrombothtestsolutionsandelectroplatingindustrialwastewatersampleswithBXwasinvestigated.TheprocesswasstudiedtakingintoaccountsuchparametersaspHofwater,precipitationtime,xanthatedosageandstoragetimeofBX.Theseproductswrerfoundtobehighlyefficientinremovingnickel.Theresidualconcentrationofnickelaftertreatmentcanbereducedtoavalueoftheordorof0.01mg·l^-1.

  • 标签: 制备 甘蔗渣 黄原酸盐 废水
  • 简介:在在废水处理过程的雌激素的活动和DOC/UV260比率之间的关联被调查为雌激素的物质的存在建议简单、可靠、全面的指示物。与这相反,当象你屏幕,受体绑定和记者基因表达式试金那样的短期的生物鉴定被用于在废水样品检测雌激素的活动时,他们要求很长时间,至少一些天。贡献雌激素的活动的主要因素被发现是17β-estradiol(E2)和雌素酉同(E1)。在DOC/UV260比率和在活性污泥过程的自河的雌激素(E1和E2)的集中之间的Agood关系被发现:当DOC/UV260ratio增加了,当E1集中减少了时,E2集中增加了。相对雌激素的活动andDOC/UV260比率显示出好关联(R~2=0.84)为除了在污水处理工厂的ozonized样品的所有污水样品。这研究证明雌激素的混合物是难的被常规生物过程使矿物化。先进氧化过程被要求进一步在第二等的自河移开雌激素的物质。由文档和UV260的分析,在废水的雌激素的活动能很快被估计。

  • 标签: 污水处理厂 活性污泥 EDCS 雌激素活性
  • 简介:ThetreatmentofsalicylicacidmanufacturingwastewaterbyNDA-100resinwasinvestigated.ThesorptionintensityofphenolwasfoundtobestronglydependentonpHoftheaqueousphase.EquilibriumadsorptiondatafittobothLangmuirandFreundlichmodels.ThecolumnadsorptionshowedthatthisprocesswassuitableforthetreatmentofsalicylicacidmanufacturingwastewaterAbout99.9%CODcrremovalwasobtainedundertheoptimaloperatingconditions.Theresincouldbecompletelyregeneratedwith1BV8%(w/w)NaOH+2BVH2O,therecoveryof98.9%ofthesubstancewasreached.Thisprocessmakesitpossibletorecoverthevaluablematerialfromthewastewaterandtoimprovetheeffluentwaterquality.

  • 标签: 水杨酸 制造业 废水处理 高交联聚合吸附剂(NDA-100)