简介:Self-emissionx-rayshadowgraphyprovidesamethodtomeasuretheablation-fronttrajectoryandlow-modenonuniformityofatargetimplodedbydirectlyilluminatingafusioncapsulewithlaserbeams.Thetechniqueusestime-resolvedimagesofsoftx-rays(>1keV)emittedfromthecoronalplasmaofthetargetimagedontoanx-rayframingcameratodeterminethepositionoftheablationfront.Methodsusedtoaccuratelymeasuretheablation-frontradius(δR=±1.15μm),image-to-imagetiming(δ(t)=±2.5ps)andabsolutetiming(δt=±10ps)arepresented.Angularaveragingoftheimagesprovidesanaverageradiusmeasurementofδ(Rav)=±0.15μmandanerrorinvelocityofδV/V=±3%.ThistechniquewasappliedontheOmegaLaserFacility[Boehlyetal.,Opt.Commun.133,495(1997)]andtheNationalIgnitionFacility[CampbellandHogan,PlasmaPhys.Control.Fusion41,B39(1999)].
简介:LiMn2O4andLiNixAlyMn2-x-yO4(x=0.50;y=0.05-0.50)powdershavebeensynthesizedviafacilesolgelmethodusingBehenicacidasactivecheiatingagent.Thesynthesizedsamplesaresubjectedtophysicalcharacterizationssuchasthermogravimetricanalysis(TG/DTA),X-raydiffraction(XRD),Fouriertransforminfraredspectroscopy(FT-IR),field-emissionscanningelectronmicroscopy(FESEM),transmissionelectronmicroscopy(TEM)andelectrochemicalstudiesviz.,galvanostaticcyclingproperties,electrochemicalimpedancespectroscopy(EIS)anddifferentialcapacitycurves(dQ/dE).FingerprintXRDpatternsofLiMn2O4andLiNixAlyMn2-x-yO4fortifythehighdegreeofcrystallinitywithbetterphasepurity.FESEMimagesoftheundopedpristinespinelillustrateuniformsphericalgrainssurfacemorphologywithanaverageparticlesizeof0.5μmwhileNidopedparticlesdepictthesphericalgrainsgrowth(50nm)withice-cubesurfacemorphology.TEMimagesofthespinelLiMn2O4showstheuniformsphericalmorphologywithparticlesizeof(100nm)whilelowlevelofAl-dopingspinel(LiNio.5Alo.05Mn1.45O4)displayingcloudyparticleswithagglomeratedparticlesof(50nm).TheLiMn2O4samplescalcinedat850℃deliverthedischargecapacityof130mAh/ginthefirstcyclecorrespondsto94%coiumbicefficiencywithcapacityfadeof1.5mAh/g/cycleovertheinvestigated10cycles.Amongallfourdopantcompositionsinvestigated,LiNi0.5Al0.05Mn1.45O4deliversthemaximumdischargecapacityof126mAh/gduringthefirstcycleandshowsthestablecyclingperformancewithlowcapacityfadeof1mAh/g/cycle(capacityretentionof92%)overtheinvestigated10cycles.ElectrochemicalimpedancestudiesofspinelLiMn2O4andLiNi0.5Al0.05Mn1.45O4depictthehighandlowrealpolarizationof1562and1100Ω.
简介:我们在Mn50Ni40SnSbx(x=1,2,3,和4)合金。所有准备样品在房间温度与空间组一起展出B2类型结构。Sb的替换增加原子价电子集中并且减少联合起来的房间体积。作为结果,当x增加,magnetostructural转变向更高的温度很快变。在在不同磁场变化下面的磁性的熵的变化在这转变附近被探索。等温的磁化曲线展出典型metamagnetic行为,显示magnetostructural转变能被一个磁场导致。悦耳的martensitic转变和磁性的熵变化建议那Mn50Ni40SnSbx合金是应用在的吸引人的候选人固态制冷。