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简介:THE SUPPORTED GOLD CATALYSTS FOR CLOSED CYCLE CO2 LASERTHESUPPORTEDGOLDCATALYSTSFORCLOSEDCYCLECO2LASER¥ZhengPingHAO;LiDunAN;...
简介:Ni/Mo2NasaHighlyActiveHydrodenitrogenationCatalystNi/Mo2NasaHighlyActiveHydrodenitrogenationCatalyst¥WenYuZHANG;XinPingWANG;...
简介:Anovelquaternarymetalselenide,K_2CdSnSe_4,wassynthesizedviaamolten-saltreactionat550℃.Thecompoundhasaone-dimensionalstructurecontainingachainof_∞~1[CdSnSe_4]~(2-)anionsseparatedbyK~+cations.ThecrystalbelongstothespacegroupI-42m,withtheunitcellparametersa=0.80298(11)nm,b=0.80298(11)nm,c=0.69217(14)nm,α=β=γ=90°.Areflectancespectroscopystudyrevealsthenatureofthesemiconductorwithanenergygapof1.7eVforthecompoundandithasastrongopticalabsorptioninarangeof2—5eV.
简介:Thenovelcomplex[K(18-C-6)]2[Cd(mnt)2][18-C-6-18-crown-6,nmt=1,2-dicyanoethene-1,2-dithiolate,C2S2-(CN)2^2-]wassynthesizedandcharacterizedbyelementalanalysis,IRspectrumandX-raydiffractionanalysis.Thecomplexdisplaystwo-dimensionalnetworkstructureof[K(18-C-6)]complexsegmentsand[Cd(nmt)2]complexsegmentbridgedbyS-K-S,S-K-NandN-K-Ninteractionsbetweenadjacent[K(18-C-6)]and[Cd(mnt)2]units.
简介:AsimpleandefficientcascadeMichael/cyclizationreactionof3-aminoindolin-2-oneswithenones/enalswasidentifiedforthesynthesisofpotentiallybiologicallyactive3’,4’-dihydrospiro[pyrrol-3,2’-oxindoles],usingDBUasanefficientcatalystandethyleneglycolasanenvironmentallybenignsolvent.Morediverse3’,4’-dihydrospiro[pyrrol-3,2’-oxindoles]analoglibrarieswerepreparedingoodyields(upto97%).Thestructureof3’,4’-dihydrospiro[pyrrol-3,2’-oxindoles]wasconfirmedbymassspectrometryanalysis,NMRanalysisandsinglecrystalX-raydiffraction.Themainadvantagesofthismethodincludetheavailabilityofstartingmaterials,simpleexperimentaloperation,shortreactiontime,aswellashighyieldsobserved.
简介:SYNTHESIS AND 183W NMR CHARACTERIZATION OF P4W30Al4(H2O)2O11220- HETEROPOLYANIONSYNTHESISAND183WNMRCHARACTERIZ?..
简介:合成了通式为K10H5[Ln(PMo7W2VO39)2].nH2O(Ln-La^3+,Ce^3+,Pr^3+,Nd^3+,Sm^3+,Eu^3+,Gd^3+,Dy^3+,Yb^3)的9种五元新型杂多配合物,并用元素化学分析,TG,ICP,IR,UV,31^1P,51V-NMR,ESR,XPS,XRD进行了表征,结果表明新配合物仍保持Keggin结构,稀土元素处于配合物的内界。借助TG-DTA,不同温度下的IR,XRD的水溶性实验考察了新配合物的热解性质,得出了热稳定的温度范围为400℃-500℃,为催化研究提供了依据。
简介:Theadsorptioncapabilityofloamsoilfornano-TiO2affectedbytheamountandintensityofleachedwaterhasbeeninvestigatedbysimulatingthenaturalrainfallprocessundertheleachingcondition.Theresultsshowthattheamountandtheintensityofleachedwateraretwoimportantfactorsaffectingtheadsorptioncapabilityofloamsoilfornano-TiO2.Theresultsindicatethatthedepthoftheloamsoilcontainingamaximalamountofnano-TiO2isproportionaltotheamountofleachedwater,whileitisinverselyproportionaltotheintensityofleachedwater,ataconstantamountoftheleachedwater.Itwasalsofoundthattheadsorptioncapabilityofsoilsfornano-TiO2canbeimprovedbyaddingothermaterials,suchasdissolvedorganicmatter(DOM),bentoniteandstraw.ItwasfoundthatDOMisthebestsorbentforimprovingtheadsorptioncapabilityofloamsoilfornano-TiO2,followedbybentonite,whilestrawisnotsuitableforthemodificationofloamsoil.Theimprovementofadsorptioncapabilityofloamsoildependsontheamountoftheseadditives.Nano-TiO2canbeeffectivelyadsorbedonthesurfacelayerofloamsoilcontaininganappropriateamountofadditive.
简介:忍受2,6二度(imino)的一系列钴建筑群含苯氧基的ligands,LCoCl2[L=2,6-(ArNCH)2CH3C6H2OH]被ligand2,6二度(imino)的反应综合有钴二氯化物的相等的鼹鼠的酚,和这些建筑群被元素的分析描绘,1HNMR,MS和红外系列。一建筑群的结构被单个水晶X光检查衍射分析决定。
简介:InT12SO4+Na2SO4+di(2-ethylhexyl)dithiophosphoricacid+n-CsH18+watersystem,theT1^+equilibriummolalitiesweremeasuredationicstrengthfrom0.1to2.0mol·kg^-1containingNa2SO4assupportingelectrolyteinaqueousphaseandatconstantmolalityofextractantattemperaturesfrom278.15to303.15Kinorganicphase.ThestandardextractionconstantsK^0atvarioustemperatureswereobtainedbymethodsofextrapolationandpolynomialapproximation.Thermodynamicquantitiesfortheextractionprocesswerecalculated.