简介:实验通过高温固相法合成了不同气氛条件下的BaZn2(BO3)2荧光粉.在空气气氛条件下制备的BaZn_2(BO_3)_2样品,发射黄色的荧光,峰位在543nm处,这是由颗粒中单个带负电荷的氧填隙离子O-i中心捕获价带上的光生空穴,与导带上落下的光生电子辐射复合产生的.在氮氢还原气氛条件下的BaZn_2(BO_3)_2样品,发射绿色的荧光,峰位在500nm处,这是由于在颗粒中光生电子经过无辐射跃迁,落入被单一电离的氧空位缺陷V*o,再由缺陷回到靠近价带,与光生空穴复合产生可见光的发射.BaZn_2(BO_3)_2荧光粉紫外波段有很强的吸收,并且荧光衰减寿命和稀土元素掺杂的荧光粉寿命相当.因此BaZn_2(BO_3)_2荧光粉在用于白光LED时,将会具有广泛的应用前景与潜在的商业价值.
简介:Weprovidethefirstdemonstrationofpureredemissioninthevisiblelightregionviathree-photonexcitationinmonodisperseNa_3ZrF_7:Ernanoparticles(NPs)byusingalaseroperatinginthetelecommunicationband.NPsof~22nmindiameteraresynthesizedat260°Cbythethermaldecompositionmethod.TheexperimentalresultsrevealthattheNa_3ZrF_7:ErNPsexhibitpureredemissioninthevisibleregionunder1480nmlaserexcitation,andtheemissionintensityissignificantlyinfluencedbytheEr~(3+)ionconcentration.Thedecaytimesofthe~4S_(3∕2)→~4F_(15∕2)and~4F_(9∕2)→~4F_(15∕2)transitionsoftheEr~(3+)ionsat540and655nm,respectively,arereducedbyincreasingtheEr~(3+)ionconcentrationintheNa_3ZrF_7:ErNPs.Thesuppressedemissionintensityresultfromthedefect-relatedquenchingeffect:whentrivalentEr~(3+)ionsreplactetravalentZr~(4+)ions,extraNationsandFvacanciesareformedtore-balancethechargeintheNa_3ZrF_7matrix.TheemissioncoloroftheNa_3ZrF_7:ErNPsisrelatedtothecrossrelaxationbetweenEr~(3+)ions.Theseresultsprovideanimportantsteptowardmoreeffectivebiologicalimagingandphotodynamictherapybyminimizingthescatteringoftheexcitationlightandincreasingthepenetrationdepth.
简介:Wedemonstrateadiode-pumpTm3+t-dopedall-fiberlaseroperatingat1908nmbasedonamasteroscillatorpoweramplifier(MOPA)configuration.Inourwork,152Woflaseroutputpowerisgeneratedbyatotalincidentpumppowerof434Wat790nm,correspondingtothetotalopticalefficiencyof35%.Thelaserwavelengthis1908.29nm.Tothebestofourknowledge,itisthehighestoutputpowerreachedaround1908nmwithsuchanarrowlinewidthof0.18nmbasedonaMOPAconfiguration.
简介:Wereportonthecontinuous-wave(CW)andpassiveQ-switchingperformanceofaminiatureYb:Y3Ga5O12crystallaserendpumpedbya935-nmdiodelaser.AmaximumCWoutputpowerof12.03Wisproducedwithanoptical-to-opticalefficiencyof54.4%,whiletheslopeefficiencyis63%.InthepassivelyQ-switchedoperationachievedwithaCr4+:YAGsaturableabsorber,anaverageoutputpowerof2.12Wat1025.2nmisgeneratedwithaslopeefficiencyof46%atapulserepetitionrateof5.0kHz.Thepulse’senergy,duration,andpeakpowerare424μJ,2.3ns,and184.3kW,respectively.