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  • 简介:Thispaperreportstheexperimentsofevaporationstudyin6mminnercopperdiametertubesusingHFC-134a,HCFC-22andCFC-12asworkingfluid.Theresultsshowthattheevaporationheattransfercofeeicientincreasesewiththedecreasingofinnerdiameteroftubes,AnewconceptofnondimensionaltubediameterUisproposedinthispaperforcorrectionoftheinfluenceofthetubediameterontheevaporationheattransfercoefficient.Andfurther,aconveinentempiricalcorrectionmethodispreseted.

  • 标签: 热传导 管径影响 结冰 蒸发器
  • 简介:ThispaperpresentsaclosedformsolutionandnumericalanalysisforEshelby’sellipticinclusioninaninfiniteplate.Thecomplexvariablemethodandtheconformalmappingtechniqueareused.Thecontinuityconditionsforthetractionanddisplacementalongtheinterfaceinthephysicalplanearereducedtothesimilarconditionsalongtheunitcircleofthemappingplane.Thepropertiesofthecomplexpotentialsdefinedinthefiniteellipticregionareanalyzed.Fromthecontinuityconditions,onecanseparateandobtaintherelevantcomplexpotentialsdefinedintheinclusionandthematrix.Fromtheobtainedcomplexpotentials,thedependenceoftherealstrainsandstressesintheinclusionfromtheassumedeigenstrainsisevaluated.Inaddition,thestressdistributionontheinterfacealongthematrixsideisevaluated.Theresultsareobtainedinthepaperforthefirsttime.

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  • 简介:一系列新包含硅(p-arylenevinylene)poly,有在主要的链的蒽单位的s(PAV)被hydrosilylation反应综合。有机硅单位的介绍改进了聚合物的溶解度,并且-聚合的链的变化形式被打断。这些聚合物在答案在0.280.30的范围在447499nm和量收益与他们的荧光最大值作为蓝绿色的轻emitters表现了。

  • 标签: 反应合成 硅氢化 乙炔 光物理 高分子链 光发射器
  • 简介:TheauthorsconsiderthescatteringphenomenaofthedefocusingH~s-criticalNLS.ItisshownthatifasolutionofthedefocusingNLSremainsboundedinthecriticalhomogeneousSobolevnormonitsmaximalintervalofexistence,thenthesolutionisglobalandscatters.

  • 标签: 整体适定性 散焦 散射 SOBOLEV 时间间隔 NLS
  • 简介:Thechaoticbehaviorofone-dimensional,2-segmentand3-segmentpiecewise-linearmapsisexaminedbyusingtheconceptofsnap-backrepellersintroducedbyMarottoandtheparametersconditionsofexistenceforsnap-backrepellerareobtained.Simulationresultsarepresentedtoshowthesnap-backrepeller,someperiodicpointsandattractingintervalcycleswithchaoticintervals.

  • 标签: 混沌性质 双峰映射 时滞循环 分段线性连续 反射级反驳说 不动点
  • 简介:Generalizedcase-cohortdesignhasbeenprovedtobeacost-effectivewaytoenhancetheefficiencyoflargeepidemiologicalcohort.Inthisarticle,weproposeaninferenceprocedureforestimatingtheunknownparametersinCox’sproportionalhazardsmodelingeneralizedcase-cohortdesignandestablishanoptimalsamplesizeallocationtoachievethemaximumpoweratagivenbudget.Thefinitesampleperformanceoftheproposedmethodisevaluatedthroughsimulationstudies.TheproposedmethodisappliedtoarealdatasetfromtheNationalWilm’sTumorStudyGroup.

  • 标签: 队列分析 风险模型 COX 比例 病例 广义
  • 简介:采用密度泛函理论的B3LYP方法、从头算的MP2方法和自洽反应场极化连续模型(PCM),在6-311++G(2d,2p)基组水平上研究了N,N’-二甲基-S-异苯并呋喃在气相和溶液中发生S→N烷基重排反应的机理、溶剂效应和取代基效应.结果表明:该反应通过四元环机理和双位迁移机理生成产物,在气相和溶剂水中,双位迁移途径的能垒均比四元环途径低,反应主要通过双位迁移途径生成产物.在气相,苯环上发生-Cl,-NO2和-OCH3取代时,双位迁移途径的能垒在MP2/6-311++G(2d,2p)水平上比没有取代时分别低4.18,7.61,4.96kJ/mol,反应的取代基效应不明显.而在溶剂水中,苯环上发生-Cl,-NO2和-OCH3取代时,双位迁移途径的能垒在PCM-MP2/6-311++G(2d,2p)水平上比气相时分别低37.73,39.96和37.17kJ/mol,反应的溶剂化效应非常明显.理论研究结果与实验观察结果一致.

  • 标签: N N’-二甲基-S-异苯并呋喃 S→N烷基重排 溶剂化效应 反应机理 密度泛函理论
  • 简介:Lithiumsulfurbattery(LSB)offersseveraladvantagessuchasveryhighenergydensity,low-cost,andenvironmental-friendliness.However,itsuffersfromseriousdegradationofitsreversiblecapacitybecauseofthedissolutionofreactionintermediates,lithiumpolysulfides,intotheelectrolyte.Tosolvethislimitation,therearemanystudiesusinggraphene-basedmaterialsduetotheirexcellentmechanicalstrengthandhighconductivity.Comparedwithgraphene,grapheneoxide(GO)containsvariousoxygenfunctionalgroups,whichenhancethereactionwithlithiumpolysulfides.Here,weinvestigatedthepositiveeffectofusingGOmixedwithcarbonblackontheperformanceofcathodeinLSB.WehaveobservedasmallerdropofcapacityinGOmixedsulfurcathode.Wefurtherdemonstratethatthemechanisticoriginofreversibilityimprovement,asconfirmedthroughCVandRamanspectra,canbeexplainedbythestabilizationofsulfurinlithiumpolysulfideintermediatesbyoxygenfunctionalgroupsofGOtopreventdissolution.Ourfindingssuggestthattheuseofgrapheneoxide-basedcathodeisapromisingroutetosignificantlyimprovethereversibilityofcurrentLSB.

  • 标签: 多硫化物 氧化石墨 可逆容量 阴极 电池 反应中间体
  • 简介:Inthispaper,wederivetwogeneralparameterizedboundariesoffinitedifferenceschemeforVee’sPDEwhichisusedtopricebothfixedandfloatingstrikeAsianoptions.Usingthesetwoboundaries,wecandealwithallkindsofsituations,especially,someextremecases,likeoverhighvolatility,verysmallvolatility,etc,underwhichtheAsianoptionisusuallymispricedinmanyexistingnumericalmethods.Numericalresultsshowthatourboundariesareprettyefficient.

  • 标签: 期权定价 PDE 边界 胶合板 有限差分方法 数值方法
  • 简介:WestudythestructureofBernstein’sfirstsummableoperatorsandshowthattheycon-vergeuniformlytocontinuonsfunctionsonthespecialrealorthogonalgroupSO(n)inthispaper.Inaddition,wehavealsodiscussedtheapproximationdegreetoaclassoffunctionLipα(0<α≤1)onSO(n).

  • 标签: OPERATORS verge FIRST REAL UNIFORMLY kernel
  • 简介:ForagiventriangulationΔofaregionRofinterest,letS82(Δ):={s∈C2(R):s|1∈P8,l∈Δ}bethespaceofallsplinesofdegree8andsmoothness2,wheretdenotesanytriangleofΔandP8thespaceofpolynomialsoftotaldegree≤8.Furthermore,letS82(Δ):={sS83(Δ):s∈C3atv,v∈Δ}beasupersplinesubspaceofS82(Δ).WeconstruelacollectionoflocallysupportedsplinesinS82(Δ)whichcanbeusedtoachievelhefullapproximationorderofS82(Δ)anditscardinalilyislessthanthedi-mensionofsupersplinespacespaceS82(Δ).

  • 标签: spline TRIANGULATION triangle collection SMOOTHNESS vertex
  • 简介:我们在场这里周期的oligo(乙烯adipate)的第一合成经由有乙烯乙二醇的adipoyl氯化物的伪高度冲淡冷凝作用反应的s(COEA),和合成相应poly(乙烯adipate)(豌豆)经由COEA的melt聚合。COEA的结构被1H-NMR和MALDI-TOF团大小。器官的底,反应温度和到COEA的收益上的乙烯乙二醇的adipoyl氯化物的比率的效果被学习,并且最佳反应条件被揭示。豌豆,二酸和diol基于半水晶的绿脂肪族的聚酯,被COEA的melt聚合用Ti综合(n-C4H9O)是的4是的催化剂和1,10-decanediol在200点的开始者在上到葡萄牙的语言的BPI在巴西说瞄准它的以后的用法在癌症病人生活测量疼痛的紧张和干扰。方法:BPI-B从原来的位/英寸被开发,用背翻译和委员会评论。背Translatio?

  • 标签: 二酸乙二醇酯 聚合合成 熔融聚合 POLY 环状 脂肪族聚酯
  • 简介:Thecombustionperformanceoftheboilerlargelydependsonthecoaltype.Lotsofexperimentalresearchshowsthatdifferentfuelshavedifferentcombustioncharacteristics.ItisobviousthatfuelwillchangethewholeoperatingperformanceofCirculatingFluidizedBedCombustion(CFBC).Weknoweveninapilot-scalerunningboiler,themeasurementofsomeparametersisdifficultandcostly.Therefore,wedevelopedthewayofsimulationtoevaluatethecombustionperformanceofChinesecoalsinCFB,Thesimulationresultsshowthat,differentcoalswillresultindifferentcoalparticlediameterandcominutiondependingontheirmineralcomponentandthechangewillaffectthedistributionofashinCFBCsystem.Inaword.thecomputationalresultsareinaccordancewithexperimentalresultsqualitativelybuttherearesomedifferencesquantitatively.

  • 标签: 锅炉 燃烧 CFB 循环流化床 模拟