简介：K2Ti2O5andLixK2-xTi2O5sampleswithvaryingKcontents(x=0.125,0.15,0.3),targetedonremovaloftwomainenvironmentalpollutants:PMandNOx,weresynthesizedbythesolidstatemethodusingTiO2,KNO3andLiOH·H2OasstartingmaterialsandwerecharacterizedbyX-raydiffractometry,scanningelectronmicroscopy,andBET.ThecatalyticactivityoftitanatecatalystsonPMoxidationwasevaluatedusingthetemperatureprogrammedoxidation(TPO)method.ThetestresultsshowedthattheperovskitestructureofK2Ti2O5wasstillretainedafterdopingasmallamountofLi,andthecatalyticperformanceofLixK2-xTi2O5hadbeenimprovedsignificantlycomparedwiththatofK2Ti2O5.Li0.15K1.85Ti2O5catalysthadthehighestcatalyticactivitywithanignitiontemperatureof210℃andapeaktemperatureof290℃.ThecatalyticactivityofbothK2Ti2O5andLixK2-xTi2O5underintimatecontactwashigherthanthatunderloosecontact.Whentheexhaustgasflowratewasaround100mL/min,thecatalystsamplesshowedahighestactivity.TheLidopedK2Ti2O5couldbeanexcellentcandidateforPMoxidationduetoitshighoxidationactivity,waterstability,resistancetosulfurpoisoningandeconomicaladvantages.

简介：ThesinteringofPtnanoparticlesisoneofthemainreasonsforcatalystdeactivationduringthehigh-temperaturepropanedehydrogenation(PDH)reaction.Promotersandsupportshavebeenintroducedtoprolongthecatalystlife.However,itisstillnecessarytodevelopnovelcatalystswithrobuststability.Herein,thephosphorus-modifiedcarbonnanotube-supportedPtnanoparticleswereemployedforthePDHprocess.PhosphorusmodificationimprovesthePtdispersion,effectivelypromotingtheactivityofPt/P-CNTs.Additionally,thephosphorus-modifiedCNTscaninteractstronglywithPtnanoparticlesbyimprovingtheelectrontransferorhybridization,stabilizingPtnanoparticlesfromagglomeration,andsignificantlyenhancingthecatalyststability.