简介:Monoammoniumphosphate(1molL^-1),monopotassiumphosphate(1molL^-1)andaluminumchloride(5×10^-3molL^-1)wereusedtoinvestigatetheinfluenceofpHontheformationofNH4-taranakiteandK-taranakiteinsystemswithahighNH4H2PO4orKH2PO4concentration.TheexperimentaldataindicatedthatthereactionproductsofaluminumwithNH4H2PO4orKH2PO4changedwiththepHinthesystems.InapHrangeof2.5to10.0,asthepHincreased,theproductsineitherammoniumorpotassiumsystemfollowedthesequence:taranakite,amorphous(NH4,K)2AIH(PO4)2.4H2O,andthencrystalline(NH4,K)AlPO4OH.2H2O.However,thepHrangesoftheformationoftheseproductsinammoniumsystemweredifferentfrompotassiumsystem.NH4-taranakiteformedfrompH2.75topH5.75,whereasK-taranakiteformedinthepHrangeof3.00to5.0,Fromthetheoreticalcalcuationbyacomputerprogram(GEOCHEMversion2.0),NH4-taranakteandK-taranakitecouldformatthepHfrom1.50to8.30andfrom1.25to8.45,respectively.ThesepHrangesweremuchwiderthantheexperimentalresults.Thedifferencebetweentheexperimentaldataandtheoreticaldatawasattributedtothelackofkineticdataand/ortheincompletenessandinaccuracyofthethermodynamicdatainthedatabaseoftheprogram.ThepHrangesoftheformationofthetaranakitesindicatedthatthetaranakitescouldexistintheimmediatevicinityofphosphateferilizerzoneasreactionproductsofphosphatefertilizerswithsoils,especiallyacideicsoils,resultinginthefixationofnotonlyphosphatebutalsonitrogenand/orpotassiuminsoils.
简介:TheimpactofpHchangesonmicrobialbiomasscarbon(Cmic)andmicrobialbiomassphosphorus(Pmic)wereexaminedfor3redsoilsundercitrusproductionwithdifferentlengthsofcultivation.SoilpHsignificantlyaffectedCmicandPmic.TheCmicandPmicchanges,asafunctionofsoilpH,appearedtofollowanormaldistributionwiththeoriginalsoilpHvalueattheapexandaspHincreasedordecreasedcomparedtotheoriginalsoilpH,CmicandPmicdeclined.Moreover,therewerecriticalpHvaluesatbothextremes(3.0ontheacidicsideand8.0to8.5onthealkalineside),beyondwhichmostofmicroorganismscouldneversurvive.TheeffectofpHonCmicandPmicwasalsorelatedtotheoriginalsoilpH.ThehighertheoriginalsoilpHwas,thelessCmicorPmicwereaffectedbypHchange.ItissuggestedthatsoilmicroorganismsthatgrowinasoilenvironmentwithamoreneutralsoilpHrange(I.e.pH5.5-7.5)mayhaveagreatertolerancetopHchangesthanthosegrowinginmoreacidicormorealkalinesoilpHconditions.
简介:在modulating植物生产率的土壤pH的潜在的角色根据干燥质量被估计,在0.25m2空铅形式收获了,在北希腊的二块低生产率的高地草地使遭到了到年度因素的氮(N)和磷(P)授精(15gNm−2year−1和10gPm−2year−1)在最小上3年的时期。在这些特别条件下面,一种积极关系将在土壤pH和植物生产率之间存在,进一步,营养素的那N或P化肥应用限制系统,这被假设,将导致一变弱这种积极关系。一种重要积极关系在其它在二个学习区域和一个积极趋势之一在土壤pH和植物生产率之间被证实。而且,植物生产率增加,后面的授精,看起来在土壤pH植物生产率关系上有有害效果。调查结果支持原来的假设并且加强想法种调停差异的土壤pH植物生产率关系是发生在更多的“typical”下面的更强烈的植物种形成的结果更高的pH在的土壤条件与热带区域对比适度。
简介:吸管法是测定颗粒组成的经典方法,激光法作为一种新兴的方法,近年被广泛应用于土壤和河流泥沙颗粒组成的分析中,并逐步应用到侵蚀泥沙粒径分析。为获取激光法与吸管法测定侵蚀泥沙特性指标和不同粒径的差异以及二者之间的转换关系,对18个黑土区侵蚀泥沙样品颗粒组成进行了测定和分析。采用中值粒径D50和平均质量直径MWD进行侵蚀泥沙样品特性分析,激光法比吸管法测定结果明显偏低;但2种方法测定D50和MWD具有很好的线性转换关系(R〉0.9,P〈0.001)。激光法测定的砂粒和黏粒质量分数低于吸管法测定值,测定粉粒质量分数明显高于吸管法测定值。测得砂粒、粉粒和黏粒含量在2种方法间,均具有很好的线性转换关系(R〉0.8,P〈0.001)。进一步细分泥沙颗粒为大于中砂、细砂、极细砂、粗粉和细粉这5个粒级时,2种方法间除极细砂(R=0.764,P〈0.001)外,其余粒级均具有很好的线性转换关系(R〉0.8,P〈0.001)。