简介:本文采用磁粉、X射线、CT和超声等无损检测和金相分析等方法对40CrNi2Si2,MoVA钢制零件的磁痕显示进行了系统分析。研究认为,40CrNi2Si2MoVA钢制零件的磁痕显示为显微成分沿变形方向偏析导致的马氏体转变点Ms差异所致。显微成分偏析是钢锭结晶过程中不可避免的,但可通过优化熔炼工艺参数降低显微偏析的程度。本文还分析了四种磁痕显示的类型及其判别方法。
简介:Themetal-organicchemicalvapordeposition(MOCVD)techniqueisapromisingprocessforhigh-temperaturesuperconductorYBa2Cu3O7-δ(YBCO)preparation.Inthistechnique,itisachallengetoobtainbariumprecursorswithhighvolatility.Inaddition,thepurity,evaporationcharacteristics,andthermostabilityofadoptedprecursorsinwholeprocesswilldecidethequalityandreproducibleresultsofYBCOfilm.Inthepresentreport,bis(2,2,6,6-tetramethyl-3,5-heptanedionato)barium(Ⅱ)(Ba(TMHD)2)wassynthesized,anditsstructurewasidentifiedbyFTIR,1HNMR,13CNMR,andESI-MSspectroscopy.Subsequently,thethermalpropertiesandthekineticsofdecompositionweresystematicallyinvestigatedbynonisothermalthermogravimetricanalysismethods.BasedontheaverageapparentactivationenergyevaluatedbytheOzawa,Kissinger,andFriedmanmethods,thevolatilizationprocesswasdiscussed,andallresultsshowthatBa(TMHD)2isunstableandhighlysensitivetothechangeoftemperatureduringthewholeevaporationprocess.Therefore,itisveryimportanttochoosesuitablevolatilizationtechnologyandconditionsforavoidingBa(TMHD)2break-down(orthermalaging)duringMOCVDprocess.Subsequently,thepossibleconversionfunctionisestimatedthroughtheCoats-Redfernmethodtocharacterizetheevaporationpatternsandfollowsaphaseboundaryreactionmechanismbythecontractingsurfaceequationwithaverageactivationenergyof118.7kJ.mol-1.
简介:起落架40CrNi2Si2MoVA钢螺桩在安装一段时间后发生了断裂。为确定螺桩断裂的原因,对断裂螺桩断口宏微观形貌、断裂螺桩及对比件的氢含量、材料的性能以及表面损伤等因素进行了检查,并对电镀工艺进行了评定。结果表明,裂纹主要起源于第一螺纹根部的机械损伤部位,源区以沿晶断裂特征为主,断裂件含氢量较高。综合分析认为。螺桩断裂性质为氢致延迟断裂,表面机械损伤对氢吸收和扩散的促进作用和40CrNi2Si2MoVA钢材料高强度所致的高氢脆敏感性是导致断裂的主要原因。
简介:研究VC/Cr3C2对Ti(C,N)基金属陶瓷微观组织和力学性能的影响。利用光学显微镜、X射线衍射仪和扫描电镜结合能谱仪研究微观组织。测试横向断裂强度、硬度和断裂韧性等力学性能。结果表明:微观组织中存在"黑芯-灰壳"和"白芯-灰壳"结构;由于添加VC/Cr3C2,硬质相晶粒变细,添加0.75VC/0.25Cr3C2的金属陶瓷晶粒细化最明显;黑芯随着VC添加量的增加而变细,壳随着Cr3C2添加量的减少而变厚;孔隙率随着VC/Cr3C2中VC的量增加而增大;横向断裂强度和硬度均升高,并且均在添加0.25VC/0.75Cr3C2时达到最大值;按适当的VC和Cr3C2添加量比例添加VC/Cr3C2可以有效地使断裂韧性升高,并在添加0.5VC/0.5Cr3C2时取得最大值。
简介:ItiswellknownthatthephotocatalyticactivityofTiO2thinfilmsstronglydependsonthepreparingmethodsandpost-treatmentconditions,sincetheyhaveadecisiveinfluenceonthechemicalandphysicalpropertiesofTiO2thinfilms.Therefore,itisnecessarytoelucidatetheinfluenceofthepreparationprocessandpost-treatmentconditionsonthephotocatalyticactivityandsurfacemicrostructuresofthefilms.ThisreviewdealswiththepreparationofTiO2thinfilmphotocatalystsbywet-chemicalmethods(suchassol-gel,reversemicellarandliquidphasedeposition)andthecomparisonofvariouspreparationmethodsaswellastheiradvantageanddisadvantage.Furthermore,itisdiscussedthattheadvancementofphotocatalyticactivity,super-hydrophilicityandbactericidalactivityofTiO2thinfilmphotocatalystinrecentyears.
简介:本文对TB6钛合金锻件弦向和径向两种取样方向分别进行了室温和200℃下旋转弯曲高周疲劳、轴向低周疲劳和疲劳裂纹扩展性能试验研究。试验结果表明,弦向(C)和径向(R)两种取样方向对该合金锻件的旋转弯曲高周疲劳、轴向低周疲劳性能和疲劳裂纹扩展性能没有影响;温度升高可加速该合金锻件的疲劳裂纹萌生,但在裂纹扩展阶段,该合金高温下的韧性优势与屈服强度降低的劣势平衡的结果使其在室温~200℃温度范围内的疲劳性能基本不受温度的影响;在10—20mm的厚度范围内,厚度对该合金的疲劳裂纹扩展性能没有影响;在3.5%NaCl盐雾环境中。腐蚀介质对TB6钛合金的疲劳裂纹扩展速率在初始阶段有迟滞作用,但在应力强度因子范围大于14MPam后有加速作用。
简介:Thesegregationanddiffusionofboronduringheattreatmentswerestudied.Theinfluenceofboroncontents,agingtimeandappliedstressonFeMo2B2formationwasalsostudied.Finally,theeffectsofboroncontentsandFeMo2B2formationonthehightemperaturestrengthwerestudied.Boronatomsweresegregatedtoprioraustenitegrainboundaryduringnormalizingtreatment.Andtheseboronatomswereslowlydiffusedintothegraininteriorduringtemperingandagingat700℃.TheFeMo2B2phasewasonlyformedafter1,000hagingat700℃inalloycontaining196ppmboron.TheformationofFeMo2B2phaseisacceleratedbytheappliedstress.ItwasexpectedthattheformationofFeMo2B2iscloselyrelatedtotheredistributionofboronatoms.Thetensilestrengthsat700℃areincreasedwiththeincreaseofboroncontents.However,theformationofFeMo2B2phaseresultsinlowertensilestrength.
简介:TheeffectofyttriaonthesolidreactionmechanismofaCaHPO4·2H2O+CaCO3systematdifferenttemperatureswasexperimentallystud-ied.Thesampleswithandwithoutyttriaweresubjectedtothermogravimetric/differentialscanningcalorimetrymeasurement.ThesampleswereheattreatedatthetemperaturescorrespondingtothepeaksontheDSCspectra,andtheresultedphasecompositionswereidentifiedbyX-raydiffraction.Thetransformationmechanismwasdeducedbycomparingthephasesobtainedatdifferenttemperatures.Theresultsshowthatthetransformationsatbelow1073Karenotaffectedbyyttria,butallthoseatabove1073Karecompletelyaltered.Theformationtem-peratureofhydroxyapatitedecreasesby134K,andthedecompositiontemperatureincreasesby38K.ThepolymorphoustransformationofCa3(PO4)2fromβphasetoαphaseincreasesby47K.Thethermodynamicpropertiesofthetransformationsatabove1073Karealsomodi-fiedbytheadditionofyttria;thatis,theendothermalpeaksaresubstitutedbyexothermalpeaks.