学科分类
/ 25
500 个结果
  • 简介:Thispaperreportsthatpolarizedfar-infraredreflectivitymeasurementshavebeendoneonLiGaO2singlecrystalalongtwocrystallineaxesatdifferenttemperatures.Thetemperaturedependentfrequenciesofthelongitudinalandtransverseopticalphononhavebeenobtainedfromtherealpartofopticalconductivityandthelossfunctionrespectively.AsmallDrudecomponentisobservedatfrequencybelow300cm-1whichcouldarisefromLiionsoroxygendeficiencies.TheionicityofLiGaO2hasbeenstudiedfromtheanalysisoftheBorneffectivechargeofdifferentions.

  • 标签: 温度 声子 红外线 光学传导性
  • 简介:Wesynthesizedonequaternaryammoniumpolymericionicliquids(PILs)P[VBTHEA]ClandthreeimidazoliumPILsofP[VEIm]Br,P[VEIm]BF4,P[VEIm]PF6byfree-radicalpolymerizationinsolution.ThesePILswerecharacterizedbyFT-IR,1H-NMR,13C-NMR,TGA,XRDandSEM.TheirCO2adsorptioncapacitiesweremeasuredunderdifferentpressuresandtemperaturesbyconstant-volumetechnique.ItwasobservedthatquaternaryammoniumPILsofP[VBTHEA]ClhavehigheradsorptioncapacityforCO2thanthoseimidazoliumPILs,followingP[VBTHEA]Cl>P[VEIm]PF6>P[VEIm]BF4>P[VEIm]Br,whichmaybeascribedtohigherpositivechargedensityonammoniumcationthanthatonimidazoliumcationandthusstrongerinteractionwithCO2,consistentwiththeresultsfromdual-modeadsorptionmodelthatammoniumPILshavemuchhigherCO2bulkabsorptionthanimidazoliumPILs.CO2adsorptioncapacityofP[VBTHEA]Clis9.02mg/gunder295Kand1bar,whichiscomparabletothatofsomeotherPILs,andismuchhigherthanthatofthecorrespondingILsmonomer.ThesePILshavegoodadsorptionselectivityforCO2overN2andregenerationefficiency.

  • 标签:
  • 简介:Formicacidphotodegradationisoneofthemostimportantreactionsinorganicpollutioncontrol,andhelpstoimprovethehydrogengenerationefficiencyintitaniumdioxidecatalyzedwaterphotodecomposition.BasedondensityfunctionaltheoryandReaxFFmoleculardynamics,theadsorption,diffusionandactivationofformicacidonthedifferentanataseTiO2(101),(001),(010)surfacesareinvestigated.TheresultshowsthattheadsorptionofCOOHonanataseTiO2surfaceshrinkstheenergygapbetweenthedehydrogenationintermediateCOOHandHCOO.OntheanataseTiO2(101)surface,theformicacidbreakstheO–Hbondatthefirststepwithactivationenergy0.24eV,andtheconsequentbreakofα-Hbecomemucheasierwithactivationenergy0.77eV.Thedissociationofα-HisthedeterminationstepoftheHCOOHdecomposition.

  • 标签:
  • 简介:WehaveexploitedagreenapproachtopreparelayeredtitanateNa2-xHxTi2O5·H2OnanosheetarraysonFTOsubstratebyhydrothermalhydrolysisoftitanium(IV)isopropoxide(TTIP)withaidsofNa2EDTAandTEOAasco-coordinationagents,whichwerethentreatedbyHNO3toreplaceNa+byH+,followedbyacalcinationat450℃totopotacticallytransformintoanataseTiO2nanosheetarrays.SEM,TEM,XRD,andRamanspectroscopyhavebeenemployedtocharacterizethenanosheetfilms.TheTiO2nanosheetarrayswerefurtherappliedaselectrontransportmaterialsofCH3NH3PbI3perovskitesolarcells,achievingpowerconversionefficiencyof6.99%.

  • 标签: TIO2纳米 锐钛矿型 阵列 FTO 合成 基板
  • 简介:TheNd2O3nanoparticleswhichmodifiedbyAOTwaspreparedusingmicrioemulsionmethodinthesystemofwater/xylene.L3edgeXAFSwasusedtodeterminethedifferenceofthelocalstructurearundNd^3+ionandtheelectricalstructurebetweenthenanocystallineNd2O3andthecoarsebulkmicrocrystallineNd2O3.ItwasfoundthatNd-Odistanceincreasedwiththeformofnanocrystalliteandtheintensityofabsorptionedgealsoenhancedatthesametime.

  • 标签: EXAFS研究 ND2O3 毫微米粒子
  • 简介:Tungstendisulfide(WS2)isatypeofanisotropic-layeredcompoundandhasbroadbandsaturableabsorptionfeaturesassaturableabsorbers(SAs).WithWS2-basedSAs,darksolitonsinerbium-dopedfiber(EDF)lasersarefirstobtained.Forthegenerateddarksolitons,thecenterwavelengthismeasuredtobe1530nm,andtherepetitionrateisabout116.5MHz.Aseriesofopticalspectraisexhibited.Theelectricalsignal-to-noiseratioisbetterthan94dB.ResultsinthispaperdemonstratethatWS2-basedSAsarethepromisingSAsforgeneratingdarksolitonsinEDFlasers.

  • 标签:
  • 简介:TheCasimireffecthasbeenstudiedforvariousquantumfieldsinbothfiatandcurvedspacetimes.Asafurtherstepalongthisline,weprovideanexplicitderivationofCasimireffectformasslessspin-3/2fieldwithperiodicboundaryconditionimposedinfour-dimensionalMinkowskispacetime.ThecorrespondingresultswithDirichletandNeurnannboundaryconditionsarealsodiscussed.

  • 标签: CASIMIR效应 无质量自旋 MINKOWSKI空间 边界条件
  • 简介:TheHL-2ANBIdesignparametersarehydrogenbeamenergy60keY,thepulsedurationof2s,consistoftwobeamlinesandinjectedalongtangentialdirection.Theneutralbeampowerwillarrive4MWinthefuture.Thefirststepisonebeamlineandtwoionsources.Thevacuumvesselconsistsofmajorchamber,minorchamberandionsourcechamberanddriftduct.Weneedavacuumsystem,whichcapacityissufficientandtherelativelylowcostsofit.

  • 标签: 中性束注入器 钛吸附泵 HL-2A 等离子体 设计思路
  • 简介:Amine-silicacompositematerialsforpost-combustionCO2capturehaveattractedconsiderableattentionbecauseoftheirhighCO2uptakeatlowCO2concentrations,excellentCO2captureselectivityinthepresenceofmoisture,andlowerenergyrequirementsforsorbentregeneration.Thisreviewdiscussestherecentadvancesinamine-silicacompositesforCO2capture,includingadsorbentpreparationandcharacterization,CO2captureunderdryandmoistureconditionsatdifferentCO2partialpressures,sorbentregeneration,andstabilityaftermanycyclicsorption-desorptionruns.

  • 标签: