简介:ThecrystalstructureofN-(2,3,4,6-tetra-O-acetyl-β-D-gly-cosyl)-thiocarbamicbenzoylhydrazine(C22H27N3O9S)wasdeterminedbyX-raydiffractonmethod.Thehexopyranosylringadoptsachairconformation.Alltheringsubstituentsareintheequatorialpositions.Theacetoxyl-methylgroupisinsynclinalconformation.TheSatomisinsynperiplanarconformationwhilethebenzoylhydrazinemoietyisanti-periplanar.Thethiocarbamicmoietyisalmostcompanarwiththebenzoylhydrazinegroup.Therearetwointramolecularhydrogenbondsandoneintermolecularhydrogenbondforeachmoleculeinthecrystalstructure.Themoleculesformanetworkstructurethroughintermolecularhydrogenbonds.
简介:Anewanalyticalmodelwasdevelopedtopredictthegravitywavedrag(GWD)inducedbyanisolated3-dimensionalmountain,overwhichastratified,non-rotatingnon-Boussinesqshearedflowisimpinged.Themodelisconfinedtosmallamplitudemotionandassumestheambientvelocityvaryingslowlywithheight.ThemodifiedTaylor-GoldsteinequationwithvariablecoefficientsissolvedwithaWentzel-Kramers-Brillouin(WKB)approximation,formallyvalidathighRichardsonnumbers.WiththisWKBsolution,genericformulaeofsecondorderaccuracy,fortheGWDandsurfacepressureperturbation(bothforhydrostaticandnon-hydrostaticflow)arepresented,enablingarigoroustreatmentontheeffectsbyverticalvariationsinwindprofiles.Inanidealtesttothecircularbell-shapedmountain,itwasfoundthatwhenthewindislinearlysheared,thattheGWDdecreasesastheRichardsonnumberdecreases.However,theGWDforaforwardshearedwind(windincreaseswithheight)decreasesalwaysfasterthanthatforthebackwardshearedwind(winddeceaseswithheight).Thisdifferenceisevidentwheneverthemodelishydrostaticornot.
简介:Anadaptivemulti-scaleconjugategradientmethodfordistributedparameterestimations(orinverseproblems)ofwaveequationispresented.Theidentificationofthecoefficientsofwaveequationsintwodimensionsisconsidered.First,theconjugategradientmethodforoptimizationisadoptedtosolvetheinverseproblems.Second,theideaofmulti-scaleinversionandthenecessaryconditionsthattheoptimalsolutionshouldbethefixedpointofmulti-scaleinversionmethodisconsidered.Anadaptivemulti-scaleinversionmethodfortheinverseproblemisdevelopedinconjunctionwiththeconjugategradientmethod.Finally,somenumericalresultsareshowntoindicatetherobustnessandeffectivenessofourmethod.
简介:Thepresentworkisconcernedwithapenny-shapedDugdalecrackembeddedinaninfinitespaceofone-dimensional(1D)hexagonalquasicrystalsandsubjectedtotwoidenticalaxisymmetrictemperatureloadingsontheupperandlowercracksurfaces.ApplyingDugdalehypothesistothermo-elasticresults,theextentoftheplasticzoneatthecracktipisdetermined.Thenormalstressoutsidetheplasticzoneandcracksurfacedisplacementarederivedintermsofspecialfunctions.Forauniformloadingcase,thecorrespondingresultsarepresentedbysimplifyingtheprecedingresults.Numericalcalculationsarecarriedouttoshowtheinfluenceofsomeparameters.
简介:ItwasgenerallyconsideredthatcontaminationofthegeltypepolystyrenestrongbasicanionexchangeresinbyorganicmatterinnaturalwateristheresultofionexchangeandVanderwaal′sadsorptiononit.Onthebasisoflaboratoryandindustrialexperiments,thispaperconfirmedthattheinterreactionbetweenorganicmatterandresinpolymermatrixisprimarilycontroledbyaVanderwaal′sadsorption.
简介:适用的一本有限投出的杂志的短暂流动上的杂志错误排列的效果在这研究被介绍。新3D计算液体动力学(CFD)分析方法被使用。另外,在杂志适用和转子动力学的油电影的短暂液体动力学的联合伪的计算在分析被考虑。基于结构化的网孔,当杂志在一部油电影的液体动力学模拟期间移动时,为网孔运动的一条新途径被建议更新网孔体积。存在动态网孔模型提供了由流畅不对在杂志轴承的短暂的油流动合适。杂志的运动被作为负担的边界条件与计算电影压力解决忍受转子的系统的动人的方程获得。在液体动力学和转子动力学之间的数据交换被数据文件认识到。从CFD模型获得的结果与没有对齐的杂志轴承上的以前的试验性的结果一致。电影压力,油电影力量,磨擦转矩,错误排列时刻和态度角度为没有对齐并且排列的杂志轴承计算、比较。结果显示适用的表演被被失衡的刺激,和CFD方法基于技术能有效地预言的液体结构相互作用(FSI)引起的错误排列极大地影响在一个忍受转子的系统适用的一本没有对齐的杂志的短暂流动域。
简介:三维(3D)排干的triaxial压缩和飞机的模拟拉紧的DEM(分离元素方法)测试用一个周期的房间为polydisperse范围的稠密、松开的集会被介绍。在工作,报导、排干的测试被在经常的吝啬的压力条件下面使样品变形建模。排干的行为被显示是类似于出版物理试验性的结果的品质上。主教为中间的主要压力的评价的公式被评估。批评密度的存在被显示独立于起始的收拾行李的密度和紧张条件。不同失败标准基于DEM模拟结果被比较了,并且Lade标准被发现是最适当的。一个新显微镜的织物参数被介绍在一般3D织物条件下面把卓见给结构的anisotropy。二个参数描绘压力和分别地独立于种类条件的织物的进化,这被发现。
简介:Inthepresentpaper,amultifluidmodeloftwo-phaseflowswithpulverized-coalcombustion,basedonacontinuum-trajectorymodelwithreactingparticlephase,isdevelopedandemployedtosimulatethe3-Dturbulenttwo-phaseflowsandcombustioninanewtypeofpulverized-coalcombustorwithoneprimary-airjetplacedalongthewallofthecombustor.Theresultsshowthat:(1)thiscontinuum-trajectorymodelwithreactingparticlephasecanbeusedinpracticalengineeringtoqualitativelypredicttheflamestability,concentrationsofgasspecies,possibilitiesofslagformationandsootdeposition,etc.;(2)largerecirculationzonescanbecreatedinthecombustor,whichisfavorabletotheignitionandflamestabilization.
简介:这研究向动人的表面为三维的麦克斯韦液体集中于热和集体流动的Cattaneo-Christov理论。有可变热电导率的不可压缩的laminar流动被考虑。流动产生由于表的双向拉长。热和集体运输的联合现象被说明。热和集体散开的Cattaneo-Christov模型被用来开发精力和集体种类的表情。在集体种类方程的一阶的化学反应术语被考虑。边界层假设导致管理数学模型。homotopic模拟被采用设想无尺寸的流动方程的结果。速度,温度,和集中的图显示出不同产生参数的效果。一个数字基准被介绍设想计算结果的会聚的价值。结果证明集中和温度地为热和集体散开的Cattaneo-Christov理论被腐烂。
简介:Four1,2,3-trisubstitutedimidazoliniumiodideswhichwereusedas5,10-+CPh-THFmodel(7-10)atformicacidoxidationlevelweresynthesized.Thebenzylidynegroup(phenyl-substitutedonecarbonunit)transferreactionsfromthesecompoundstoGrignardreagentwerein-vestigated,andthereactionsofthesecompoundswithKBH4andNaOHwerealsostudied.
简介:利用蒙特卡罗模拟程序MCNP研究了NaI(Tl)探测器对海水中137Cs、131I的比计数率响应情况;计算了NaI(Tl)探测器对不同半径海水球体源中137Cs与131I的比计数率响应曲线;分析了探测器防水套筒、NaI(Tl)晶体尺寸与结构、射线能量等因素对比计数率响应的影响;拟合了3R3型、5R5型NaI(Tl)探测器最大比计数率ymax及有效探测距离D。防水套筒模型与裸晶体简化模型的计算结果对比表明,裸晶体模型会给计算带来明显的偏差,应在模型设计时,考虑探测器结构,构建更精确的模型。