学科分类
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326 个结果
  • 简介:一个非水的暂停polycondensation方法被建议继续为准备的p-phenylenediamine和terephthaloyl氯化物的反应poly(p苯撑terephthalamide)(PPTA)。系统与NMP-CaCl被操作<潜水艇class=“a-plus-plus”>是的2答案驱散的阶段和是的惰性的液体石蜡连续阶段。每NMP-CaCl<潜水艇class=“a-plus-plus”>在石蜡推迟的2答案microdroplet用作polycondensation发生了的microreactor。根据TGA,XRD,红外,SEM和EA的结果,有好质量的PPTA通过这个新奇方法被获得,并且影响这个过程的很多个主要因素被调查为PPTA的准备决定最佳条件。而且,这个二阶段的polycondensation系统与常规解决方案polycondensation方法相比带给许多唯一的优点,包括使反应物离开氧和水的封上的反应环境,HCl到的容易的移动支持更少的精力花费了工具的反应,控制得好的温度和低粘性。

  • 标签: 对苯二甲酰胺 液体石蜡 水悬浮 亚苯基 系统 制备
  • 简介:Ahigh-orderleap-frogbasednon-dissipativediscontinuousGalerkintime-domainmethodforsolvingMaxwell'sequationsisintroducedandanalyzed.Theproposedmethodcombinesacenteredapproximationfortheevaluationoffluxesattheinterfacebetweenneighboringelements,withaNth-orderleap-frogtimescheme.Moreover,theinterpolationdegreeisdefinedattheelementlevelandthemeshisrefinedlocallyinanon-conformingwayresultinginarbitrarylevelhangingnodes.ThemethodisprovedtobestableundersomeCFL-likeconditiononthetimestep.Theconvergenceofthesemi-discreteapproximationtoMaxwell'sequationsisestablishedrigorouslyandboundsontheglobaldivergenceerrorareprovided.Numericalexperimentswithhigh-orderelementsshowthepotentialofthemethod.

  • 标签: GALERKIN法 麦克斯韦方程组 时间步长 跨越式 高阶 网格
  • 简介:Thispaperestablishesanon-linearfiniteelementmodel(NFEM)ofL4-L5lumbarspinalsegmentwithaccuratethree-dimensionalsolidligamentsandintervertebraldisc.Forthepurpose,theintervertebraldiscandsurroundingligamentsaremodeledwithfour-nodalthree-dimensionaltetrahedralelementswithhyper-elasticmaterialproperties.Puremomentof10N·mwithoutpreloadisappliedtotheuppervertebralbodyundertheloadingconditionsoflateralbending,backwardextension,torsion,andforwardfle...

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  • 简介:BasedontheHolsteinmodelHamiltonianofone-dimensionalmolecularcrystals,bymakinguseoftheexpansionapproachofthecorrelatedsqueezed-coherentstatesofphononinsteadofthetwo-phononcoherentstateexpansionscheme,thepropertiesofthegroundstateandtheanomalousquantumfluctuationsareinvestigatedinastronglycoupledelectron-phononsystemwithspecialconsiderationoftheelectron-two-phononinteraction.Theeffectiverenormalization(αi)ofthedisplacementofthesqueezedphononswiththeeffectofthesqueezed-coherentstatesofphononandboththeelectron-displacedphononandthepolaron-squeezedphononcorrelationshavebeencombinedtoobtaintheanomalousquantumfluctuationsforthecorrectionsofthecoherentstate.Duetothesenon-adiabaticcorrelations,theeffectivedisplacementparameterαiislargerthantheordinaryparameterα(0)i.Incomparisonwiththeelectron-one-phononinteraction(g)correctedasαig,wehavefoundtheelectron-two-phononinteraction(g1)correctedasαi2g1isenhancedsignificantly.Forthisreason,thegroundstateenergy(E(2)0)contributedbytheelectron-two-phononinteractionismorenegativethanthesingle-phononcase(E(1)0)andthesolitonsolutionismorestable.Atthesametime,theeffectsoftheelectron-two-phononinteractiongreatlyincreasethepolaronenergyandthequantumfluctuations.Furthermore,inadeeperlevel,wehaveconsideredtheeffectofthepolaron-squeezedphononcorrelation(f-correlation).Sincethiscorrelationparameterf>1,thiseffectwillstrengthentheelectron-oneandtwo-phononinteractionsbyfαigandf2αi2g1,respectively.Thefinalresultsshowthatthegroundstateenergyandthepolaronenergywillappearmorenegativefurtherandthequantumfluctuationswillgainfurtherimprovement.

  • 标签: 一维分子晶体 极化声子 相互作用 量子波动 电子流 非绝热