简介:IntroductionInGuixiSmelter,copperanodeslimewastreatedbymeansoftechnologicalprocesofvolatilizingSeinarotarykiln,pickingcoppe...
简介:Thecreepmechanismofas-castMg-6Al-6Ndalloywasstudied.Thestressexponentforcreepis5.8undertheappliedstressesof50-70MPaat175°C.Theactivationenergyforcreepis189kJ·mol-1undertheappliedstressof70MPaintherangeof150-200°C.Thetruestressexponentandthresholdstressforcreeparecalculatedas4.96and10.2MPa,respectively.Thetruestressexponentindicatesthatitscreepmechanismbelongstothedislocationclimb-controlledcreep,whichisinagreementwiththemicrostructurechangesbeforeandaftercreep.ThehighvalueforstressexponentisattributedtotheinteractionofAl11Nd3phasewithdislocations.Theactivationenergyismorethantheself-diffusionactivationenergyofMg,whichisattributedtotheloadtransfertakingplacefromthematrixtoAl11Nd3phaseduringcreep.
简介:Pt(Ⅱ)andPd(Ⅱ)complexeswith2',3',4',5,7-pentahydroxy-flavoneweresynthesizedandcharacterizedbyelementalanalysis,molarconductance,IR,1HNMR,TG-DTA,UV-Visspectroscopictechniques,andfluorescenceanalysis.Thescavengingeffectonthesuperoxideradical(O-2)andtheinhibitoryeffectonlipidperoxideswerealsoinvestigated.Boththeligandandthecomplexesexhibitscavengingeffectonsuperoxideradicals,andtheeffectofthecomplexesisgreaterthanthatoftheligand.ThePt(Ⅱ)complexexhibitsthestrongestscavengingefficiency.BothPt(Ⅱ)andPd(Ⅱ)complexeshavetheinhibitoryeffectonlipidperoxides,andtheeffectofthecomplexesisgreaterthanthatoftheligand,butthePt(Ⅱ)complexhasahigheffectofpromotinglipidperoxides.
简介:采用吸附饱和EDTA的活性炭作为三维电极反应器中的粒子电极,多次使用后采用电化学方法对其再生。通过对吸附饱和EDTA的活性炭和多次电解使用后的活性炭的红外光谱谱图的分析得出,EDTA被活性炭吸附后产生甘氨酸H2NCH2COOH,通过N—H键生成一种永久性占据活性炭活性点的非催化活性缔合物,导致其催化活性消失,降解效率下降。采用电解方法使活性炭再生,得出活性炭的最佳活化条件为:电流100~300mA,溶液电导率1.39mS/cm,pH值6.0~8.0,电解1h可以使活性炭恢复活性,电解后有机物的残余TOC浓度低于10mg/L(初始浓度为200mg/L)。