简介:Pureandneodymium-dopedgadoliniumcalciumoxoboratecrystalsofhighqualityweregrownbytheCzochralskimethod.Theorientationofcrystalwaspreciselydetermined,andthesamplesformeasurementswereprepared.Throughsynchrotronx-raytopographyandhigh-resolutionx-raydiffractometry,thetwinstructurewasdiscovered.Somepropertiessuchasthefigureofmeritvalue,anddielectric,piezoelectric,andelasticconstantsweremeausuredalongwithadiscussionoftheanisotropyofthelaserproperties.
简介:ConsideringthatKBe2BO3F2(KBBF)isanoutstandingdeepultravioletcrystalwhichcangeneratetheshortestwavelengthsinsecondharmonicgenerationandsum-frequencygeneration,wereportthedeterminationofthenonlinearopticalcoefficientsoftheKBBFcrystal.Thed11coefficientwasdeterminedtobe0.49pm/VbytheMakerfringesmethodatthewavelength1064nm,whichisinagreementwellwiththetheoreticalvalue.
简介:YbxY1-xAl3(BO3)4(x=0.1,0.07and0)crystalshavebeengrownbythefluxmethod.ThegrowthdefectsofYbxY1-xAl3(BO3)4crystalsweredetectedbyX-raytopography.ItisfoundthattheperfcetionofYbYABcrystalwithlowYbdopantisbetterthanthatwithhighYbdopant.InYb0.1Y0.9Al3(BO3)4crystal,growhtbands,growthboundaries,grown-indislocationsandinclusionswereobserved.Howver,thedensitiesofgrowthdefectsforYb0.07Y0.93Al3(BO3)4andYAl3(BO3)4arelowandnoobviousinclusionsareobservedinthesecrytals.Inaddition,growthtwinswrerdetectedinYbxY1-xAl3(BO3)4crystalbyusingthechemicaletchingmethod.ItisfoundthatthegrowthtwinsoccurfrequentlyinYb0.01Y0.9Al3(BO3)4crystalwhereasnogrowthtwinappearsinYAl3(BO3)4crystal.Basedontheexperimentalobservations,theformationmechanismofgrowthtwinsisdiscussed.Inthemeantime,theeffectivemeasuresforreducingthegrowthtwinsanddefectsareproposed.2001ElsevierScienceB.V.Allrightsreserved.
简介:LargeGdCa4O(BO3)3crystalhasbeengrownbytheCzochralskimethod.ThequalityofGdCa4(BO3)3crystalwasassessedbywhite-beamsynchrotronradiationtopography.Ithasbeenfoundthatthereisasub-grainboundaryintheGdCa4O(BO3)3crystal.TheboundarydividesthelargeGdCa4O(BO3)3crystalintotwoindividuals.Duetothemisorientationbetweenthetwoindividuals,theimageshiftscanbeobservedinthesynchrotrontopopraphs.BasedonthemisorientationdeterminedbyhighresolutionX-raydiffractometer,theimageshiftswerecalculatedforseveralreflections.ThecalculationsareinagreementwiththemeasurementsfromthetopogrphsveryWell.Inaddition,theformationmechanismofsub-grainboundaryisdiscussed.2001ElsevierscienceB.V.Allrightsreserved.
简介:Ca3Y2(BO3)(4):Eu3+黄磷被高温度solid-statereaction方法综合,并且光特征被调查。排放光谱在相应于电的dipoleD-5(0)的613和621nm展出二强壮的红排出物在365nm刺激下面的Eu3+的-F-7(2)转变,原因是Eu3+代替forY3+在Ca3Y2(BO3)(4)的水晶结构占据非中心对称的位置。为613nm的Theexcitation光谱显示黄磷能是有效地激动的由紫外(紫外)(254nm,365nm和400nm)并且蓝色(470nm)光。Ca3Y2(BO3)(4)的排放紧张上的Eu3+集中的效果:Eu3+黄磷被测量,排放紧张与增加Eu3+集中增加的结果表演,然后减少。Ca3Y2(BO3)(4)的CIE颜色坐标:Eu3+黄磷是(0.639,0.357)在15mol%Eu3+。
简介:以化学沉淀法制备单相的铕离子掺杂硼铝酸盐红色荧光粉YAl3(BO3)4:Eu3+,考察了焙烧温度、掺铕量等因素对材料性能的影响,用X射线衍射、扫描电镜、激发光谱和发射光谱对荧光粉的结构、形貌和发光性能进行了表征.以尿素为沉淀剂,900℃焙烧沉淀前驱体可得到单相荧光粉YAl3(BO3)4:Eu3+,反应温度比传统高温固相法降低了300℃;沉淀法制备的荧光粉粒径分布范围小,无团聚现象,粒径约300nm.掺铕量为10%(物质的量比)时发光强度最大.在260nIn的紫外光激发下,Eu3+的5D0→F72的电偶极跃迁最强,发射光为618nm的红光.
简介:Inthispaper,wereportedamultiwavelengthpassivelyQ-switchedYb3+:GdAl3(BO3)4solid-statelaserwithtopologicalinsulatorBi2Te3asasaturableabsorber(SA)forthefirsttime,tothebestofourknowledge.Bi2Te3nanosheetswerepreparedbythefacilesolvothermalmethod.TheinfluenceofthreeBi2Te3densitiesonthelaseroperationwascompared.Themaximumaverageoutputpowerwasupto57mWwithapulseenergyof511.7nJ.Theshortestpulsewidthwasmeasuredtobe370nswith110kHzpulserepetitionrateand40mWaveragepower.Thelaseroperatedatthreewavelengthssimultaneouslyat1043.7,1045.3,and1046.2nm,ofwhichthefrequencydifferenceswerewithintheterahertzwaveband.OurworksuggeststhatsolvothermalsynthesizedBi2Te3isapromisingSAforsimultaneouslymultiwavelengthlaseroperation.