简介:四lanthanide协作建筑群,也就是[行(2,3-DClBA)3(5,5-dmebipy)(H2O)]2(Ln=Sm(1),Eu(2),Dy(3),惊讶(4));2,3-DClBA=2,3-dichlorobenzoate;5,5-dmebipy=5,5-dmethylbipyridine)被元素的分析,红外线的光谱学和单个水晶X光检查衍射综合并且描绘。调查结果显示建筑群3是一个dinuclear分子,并且中心Dy3+是八坐标的。每个dinuclear单位能被H债券和卤素卤素相互作用连接。建筑群2的光性质建议了Eu3+离子的典型强烈排出物。热分析证明建筑群在三分解了步:协作水然后第一被失去中立ligand5,5dmebipy被失去,最后,2,3-DClBAligand被失去。
简介:Duetotheremarkablemagnetoresistance(MR)effectonperovskite-typemanganite,magnetoelectronicsandspintronicshavebecomeattractivesubjectsofexperimentalandtheoreticalinvestigationsfortheapplicationpurpose.(La0.9Nd0.1)2/3Ca1/3Mn1-xFexO3(x=0,x=0.05)werepreparedsuccessfullybysol-gelmethod.Thestructure,magneticproperties,andtransportpropertiesofthecompoundswereinvestigated.Themagnetoresistanceeffectdependsonthecompositionandthetemperature.XRDpatternsshowthatthecompoundisasinglephasepolycrystalwithpseudocubicstructure.Alargenegativeisotropicmagnetoresistanceeffectinthesampleswereobservedatlowtemperatureregion.ThemaximumMRofthesampleswas77%and97%,respectively.Itwasmostlikelyduetothescatteringorthetunnelingtransportofspin-polarizedcarriersinlatticeunderstrongmagneticfield.
简介:EffectofLa-richrareearthoneutecticmicrostructureinA1-2%Fealloywasstudied.WhentheadditionofREissmall,a-A1phaseisintheformofcellulardendrite.WiththeincreaseoftheadditionofRE,thenucleationandgrowthofa-A1dendritearesuppressed,andeutecticAl3Fephaseisrefined.WhentheadditionofREgetsto0.6%(massfrac-tion),thesizeofeutecticAl3Feincreases.Inaddi-tion,mechanismoftheeffectofmixedREoneutecticmorphologyofA1-2%Fealloyisexplored.
简介:EffectofMnsubstitutionforFeincubicLavesZr0.1Tb0.9(Fe1-xMnx)2andY0.1Tb0.9(Fe1-xMnx)2com-poundsispresented.Similarresultsinbothsystemsareobtained:ThestructureandthemagnetismofTbFe2arebothinfluencedslightlybyasmallamountofYorZrsubstitutionforTb;Withincreasingxvalue,thelatticeconstantincreasesmonotonously;theCurietemperaturedecreaseslinearly;whilesaturationmagnetizationincreaseslinearly.ForthesmallamountofMnsubstitutionforFeinbothsystems,magnetostrictionissignificantlylargerthanthatinthepureironalloys.Thelargestmagnetostrictionof|γ‖-|γ|=2200×10-6atmagneticfieldof2×107/4πA/misobtainedforY0.1Tb0.9(Fe0.95Mn0.052.
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简介:ThemeasurementsoftemperaturedependenceofthemagneticsusceptibilityofLa1-xSrxCoO3perovskiteoxidesatdifferentSrdoping(0≤x≤0.5)andannealingtemperaturewerepresented.Forthesamplewithx=0.1,ashoulderwasobservedaround150K,andapeakwhichisonefeatureofspinglassappearedaround50Kinthecurveofsusceptibilityversustemperature.Thehigh-temperature(250~420K)susceptibilityfitswellwithCurie-Weisslawforallsamples.WeissconstantandeffectivemagneticmomentweredeterminedandtheirvariationswithSrdopingandoxygenannealingconditionwereobtained.TheWeissconstantincreasesmonotonouslywithSrcontentforx>0.2.Thevaluesofeffectivemomentswereinterpretedwiththespinstateofcobaltions.Studiesonthesusceptibilitiesofthesampleswithx=0.2underdifferentpreparationtemperaturesandannealingtemperaturesshowthattherisingofsinteringtemperatureandannealingtemperaturewillincreasethepara-ferromagnetictransitiontemperature,andreducetheeffectivemomenttonormalvalue.OurresultshowsthatbothCo3+andCo4+ionsshouldbeinISstateafterannealingandtheoxygenannealingcausesthetransitionofCo3+spinstatefromHStoIS.