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43 个结果
  • 简介:Thesimplemodelfor4f-5dtransitionsoflanthanideionsincrystalswasextendedtodealwiththecaseoftheoctahedralcrystalfield,whereforthet2componentof5dorbitalsthespin-orbitinteractioncouldnotbeneglectedduetoincompletequenchingofthe5dorbitalangularmomentum.Theenergylevelsforthe4fN-15dconfigurationandtherelativelinestrengthsforthe4fN4fN-15dtransitionwerecalculatedindetail.Theresultwasappliedtotheinterpretationofthelow-temperature4f-5dexcitationspectrumofCs2NaYCl6∶Tb3+.

  • 标签: SIMPLE model f-d TRANSITION 5d SPIN-ORBIT
  • 简介:2013年4月1日,湖南省政府下发的《关于铅锌矿石和石墨资源税从价计征改革试点的通知》明确,自2013年1月1日起,对湖南省铅锌矿石和石墨资源税实行从价定率征收,税率为5%。

  • 标签: 铅锌矿石 资源税 湖南省 石墨 征收 省政府
  • 简介:总结了临钢5号高炉炉缸、炉底破损的情况,找出了影响5号高炉寿命的主要原因,并提出了今后高炉设计中应采取的措施。

  • 标签: 高炉 破损 设计 对策
  • 简介:IBISWorld工业机构分析预测,在未来5年,有色金属回收行业将保持强劲增长趋势,以2014年计,每年将有12.1%的增长速度,190亿美元的回收业务收入。同时,随着研究的不断深入,能源效率和工业生产中使用的金属回收成本效益已逐渐取代原材料的加工和投入。这种趋势已经加速产生新的环保标准,鼓励使用再生材料以减少工业废物和二氧化碳的排放量。商品价格的飙升,致使经济衰退后对再生金属的需求日益增加,这比购买和处理原生金属要经济,如从报废汽车中提取金属物件。

  • 标签: 有色金属 回收行业 大发 工业生产 经济衰退 机构分析
  • 简介:2013年6月28日,发改委发布1—5月有色金属行业运行情况。1~5月,全国十种有色金属产量1604万t,同比增长10.9%。据悉,电解铝生产增速放缓,其他主要有色金属产量保持较快增长。5月份,全国十种有色金属产量同比增长7.5%,增速同比加快0.9%。其中,电解铝产量增长2.3%,减缓6.8%;铜、铅、锌产量分别增长18.4%、7.1%和13.6%。

  • 标签: 有色金属行业 锌产量 电解铝生产 同比增长 运行情况
  • 简介:LuminescencelifetimeofCe(Ⅲ)forCe0.9RE0.1P5O14,whereREdenotesrareearthionsotherthanCe(Ⅲ),wasmeasuredbymeansofthetime-correlatedsinglephotoncountingtechnique.Ithasbeenfoundthatthelifetimedataarecapableofelucidatingtheenhancementorquenchingofcerium(Ⅲ)luminescencebyalienREions(otherthanCe)indoublydopedceriumpentaphosphatecrystal.

  • 标签: REP5O14crystal Luminescence LIFETIME CE
  • 简介:SpectralParameterStudyonTm3+inNaTm(WO4)4CrystalYaoLianzeng(姚连增)(DepartmentofMaterialsScienceandEnginering,UniversityofScienc...

  • 标签: Rare earths NA 5Tm(WO 4) 4
  • 简介:Loadedonthecordierite,therareearthdopedcompositecatalystwaspreparedbysol-gelmethodcombinedwithdippingtechnique.TakingOrthodichlorobenzeneasmodel,thecatalystwasusedtoremovethedioxinsofthewastegas.Theresultsshowedthatat280℃andgasspacevelocitybeing8000h-1,theorthodichlorobenzenecouldberemovedeffectivilybythepreparedCeO2-TiO2-V2O5compositecatalystwhoseactivitywasremarkablyenhancedbythedopingofCe,whiletheindustrialside-streamtestofdioxinsfromrefuseincinerationsmokeindicatedthatthedecompositionratecouldreachabove93%underthesameconditions.

  • 标签: orthodichlorobenzene DIOXINS CATALYTIC oxidation REFUSE INCINERATION
  • 简介:TheeffectofrapidsolidificationonstructureandelectrochemicalperformanceoftheLaNi4.5Co0.25Al0.25hydrogenstoragealloywasinvestigatedbyX-raypowderdiffractionandasimulatedbatterytest,includingmaximumcapacity,cyclingstability,self-discharge,andhigh-ratedischargeability(HRD).Allthemelt-spunalloysweresingle-phasewiththeCaCu5-typestructure(spacegroupP6/mmm).Incomparisontotheas-castalloy,therapidlyquenchedalloysmanifestedanimprovedhomogeneityofcompositionandexpandedlatticeparameters.Theelectrochemicalmeasurementsshowedthattheactivationproperty,cyclingstabilityandself-dischargeofthealloyelectrodeswerealsoimprovedfortherapidsolidifiedalloys.TheHRDoftheas-castalloywasbetterthanthoseofalltherapidlysolidifiedalloys.Asthequenchingrateincreased,theHRDandexchangecurrentdensityfirstdecreasedandthenincreased.

  • 标签: AB5型贮氢合金 电化学性能 快速凝固 结构 X射线粉末衍射 循环稳定性
  • 简介:Thephasesandmagnetocaloriceffectinthealloys(Gd1-xErx)5Si1.8Ge2.2withx=0,0.1,0.2and0.3wereinvestigatedbyX-raydiffractionanalysisandmagnetizationmeasurement.ThesamplesweresinglephasewiththemonoclinicGd5Si2Ge2-typestructure.WiththeincreaseofErcontent,theCurietemperature(Tc)decreasedobviouslyfrom253Kofthealloywithx=0to114Kwithx=0.3.Themaximummagneticentropychangedinthesamplesof(Gd1-xErx)5Si1.8Ge2.2withx=0.0,0.1,0.2and0.3were6.88,8.32,9.59and10.24J·kg-1·K-1respectivelyintheappliedfieldchangeof0~2.0T.

  • 标签: (Gd1-xErx)5Si1.8Ge2.2 compounds MAGNETOCALORIC effects magnetic entropy
  • 简介:Er3+/Yb3+codopedzincateBaGd2ZnO5phosphorsweresynthesizedviaatraditionalsolidstatereaction.ThecrystalstructureandphasepuritywerecheckedbymeansofX-raydiffraction(XRD),andtheresultsshowedthatpurephaseBaGd2ZnO5phosphorswithvariousEr3+,Yb3+concentrationswereobtained.TheinfluenceofEr3+andYb3+dopingconcentrationsonthegreenandredupconversionemissionswasstudied.Itwasfoundthatbothgreenandredupconversionemissionsunder980nmexcitationweretwo-photonprocessesindependentfromtherareearthdopingconcentrations.However,theupconversionluminescenceintensitiesgreatlydependedontherareearthdopingconcentration.Furthermore,thepopulationprocessesofupconversionluminescenceandthequenchingmechanismswereanalyzed.Thetemperature-dependentgreenupconversionluminescencewasstudied,andthetemperaturequenchingprocessoftwogreenupconversionemissionswasmodeled.Thethermalquenchingprocessesofthegreenupconversionemissionscouldbewellexplainedbythemodelweproposed.

  • 标签: 上转换发光 温度依赖性 浓度效应 荧光粉 淬火 固相反应合成
  • 简介:8月29日,包头国家稀土高新区对外发布消息称,稀土高新区根据包头市建设稀土新材料基地的战略目标,拟用5~10年的时间,将包头建成全国最重要的稀土新材料基地。

  • 标签: 包头市 稀土 产业基地 时间 新材料 中国
  • 简介:ThesurfaceofacommercialY3Al5O12:Ce3+phosphorwasmodifiedby99%NH4F+CH3COOHsolutioninasupersonicbathwithwatertemperatureof80oCfor4h.Thescanningelectronmicroscopy(SEM)resultsshowedthattheedgeangleswerenotassharpastheunmodifiedparticlesandtheflatsurfacesturnedroughwithmanymicro-structurescovered.Positronlifetimemeasurementsquantitativelyshowedthatsurfacedefectswereremovedawaybymorethan50%.Asaresult,thephotoluminescencedeterminationsshowedthatthebackscatterlosswasreducedby4.2%andtheemissionpowerwasenhancedby5.6%afterthesurfacemodification.Theconversionefficiencywasgreatlyimprovedfrom47.3%to51.1%,aspresentedbythefluorescenceimages.Therefore,itwouldbegreatlyhelpfulfortheimprovementofefficiency,transparencyandstabilityofpc-LED.Moreover,thismethodwassignificantlysuitableformassproductionduetoitseasyoperationandlowcost.

  • 标签: 表面特征 表面缺陷 溶胶-凝胶法 荧光粉 选择性腐蚀 CE
  • 简介:Thesinglecrystalofthecomplex[Sc(NO3)3(H2O)2]·(15C5)hasbeenpreparedinacetonitrile.Thenewcomplexhasbeencharacterizedbyelementalanalysis,IRspectra,solubilityandmolarconductancemeasurements.ThestructureofthecomplexisdeterminedbysinglecrystalX-raydiffractionanalysis.

  • 标签: solubility acetonitrile Crown molar H2O NO3